Growth mechanisms and geochemistry of carbonate concretions from the Cambrian Wheeler Formation (Utah,USA)          下载免费PDF全文

Robert R. Gaines  John S. Vorhies 《Sedimentology》2016,63(3):662-698

Carbonate concretions provide unique records of ancient biogeochemical processes in marine sediments. Typically, they form in organic‐rich mudstones, where a significant fraction of the bicarbonate required for carbonate precipitation is supplied from the decomposition of organic matter in the sediments. As a result, carbonates that comprise concretions are usually characterized by broad ranges in δ¹³C and include values that are significantly depleted relative to seawater. This article reports results from a physical, petrographic and geochemical analysis of 238 concretions from the Wheeler Formation (Cambrian Series 3), Utah, USA, which are unusual in several respects. Most prominently, they formed in organic‐poor mudstones (total organic carbon = 0·1 to 0·5%) and are characterized by a narrow range of δ¹³C that onlaps the range of contemporaneous seawater values. Subtle centre to edge trends in δ¹³C demonstrate that concretion precipitation was initiated by local chemical gradients set up by microbial activity in the sediments, but was sustained during growth by a large pool of inorganic bicarbonate probably derived from alkaline bottom waters. The large inorganic pool appears to have been important in facilitating rapid precipitation of the concretion matrix, which occurred via both displacive and replacive carbonate precipitation during early diagenesis. Stable isotope data from cogenetic pyrite (δ³⁴S) and silica (δ¹⁸O) phases provide insight into the evolution of biogeochemical processes during concretion growth, and suggest that concretions were formed almost entirely during sulphate reduction, with only minor modification thereafter. Concretions of the Wheeler Formation appear to represent an end‐member system of concretion formation in which rapid growth was promoted by ions supplied from sea‐water. As such, they offer insight into the spectrum of processes that may influence the growth of carbonate concretions in marine sediments.  相似文献   

Significance of shallow core transects for reef models and sea‐level curves,Heron Reef,Great Barrier Reef          下载免费PDF全文

Gregory E. Webb  Luke D. Nothdurft  Jian‐Xin Zhao  Bradley Opdyke  Gilbert Price 《Sedimentology》2016,63(6):1396-1424

A sequence of shallow reef cores from Heron Reef, Great Barrier Reef, provides new insights into Holocene reef growth models. Isochron analysis of a leeward core transect suggests that the north‐western end of Heron Reef reached current sea‐level by ca 6·5 kyr bp and then prograded leeward at a rate of ca 19·6 m/kyr between 5·1 kyr and 4·1 kyr bp (pre‐1950) to the present reef margin. A single short core on the opposing margin of the reef is consistent with greater and more recent progradation there. Further to the east, one windward core reached modern sea‐level by ca 6·3 kyr bp , suggesting near ‘keep‐up’ behaviour at that location, but the opposing leeward margin behind the lagoon reached sea‐level much more recently. Hence, Heron Reef exhibited significantly different reef growth behaviour on different parts of the same margin. Mean reef accretion rates calculated from within 20 m of one another in the leeward core transect varied between ca 2·9 m and 4·7 m/kyr depending on relative position in the prograding wedge. These cores serve as a warning regarding the use of isolated cores to inform reef growth rates because apparent aggradation at any given location on a reef varies depending on its location relative to a prograding margin. Only transects of closely spaced cores can document reef behaviour adequately so as to inform reef growth models and sea‐level curves. The cores also emphasize potential problems in U‐series dates for corals within a shallow (ca 1·5 m) zone beneath the reef flat. Apparent age inversions restricted to that active diagenetic zone may reflect remobilization and concentration of Th in irregularly distributed microbialites or biofilms that were missed during sample vetting. Importantly, the Th‐containing contaminant causes ages to appear too old, rather than too young, as would be expected from younger cement.  相似文献   

DEM simulations of methane hydrate exploitation by thermal recovery and depressurization methods     

《Computers and Geotechnics》2016

Methane hydrate (MH, also called fiery ice) exists in forms of pore filling, cementing and load-bearing skeleton in the methane hydrate bearing sediment (MHBS) and affects its mechanical behavior greatly. To study the changes of macro-scale and micro-scale mechanical behaviors of MHBS during exploitation by thermal recovery and depressurization methods, a novel 2D thermo-hydro-mechanical bonded contact model was proposed and implemented into a platform of distinct element method (DEM), PFC2D. MHBS samples were first biaxially compressed to different deviator stress levels to model different in-situ stress conditions. With the deviator stress maintained at constant, the temperature was then raised to simulate the thermal recovery process or the pore water pressure (i.e. confining pressure for MH bond) was decreased to simulate the depressurization process. DEM simulation results showed that: during exploitation, the axial strain increased with the increase of temperature (in the thermal recovery method) or decrease of pore water pressure (in the depressurization method); sample collapsed during MH dissociation if the deviator stress applied was larger than the compression strength of a pure host sand sample; sample experienced volume contraction but its void ratio was slightly larger than the pure host sand sample at the same axial strain throughout the test. By comparison with the laboratory test results, the new model was validated to be capable of reproducing the exploitation process by thermal recovery and depressurization methods. In addition, some micro-scale parameters, such as contact distribution, bond distribution, and averaged pure rotation rate, were also analyzed to investigate their relationships with the macroscopic responses.  相似文献   

The behavior of a multilayered porous thermo-elastic medium with anisotropic thermal diffusivity and permeability     

《Computers and Geotechnics》2016

With the aid of integral transform techniques, this paper presents an extended precise integration solution for thermal consolidation problems of a multilayered porous thermo-elastic medium with anisotropic thermal diffusivity and permeability due to a heat source. From the fundamental governing equations, ordinary differential equations are derived by employing Laplace–Hankel transforms. By applying the extended precise integration method, equations in the transformed domain can be solved, and the actual solutions are further obtained by adopting a numerical inverse transformation. The accuracy and feasibility of the proposed theory is demonstrated by contrastive analysis with existing studies. Finally, several examples are carried out to investigate the influence of heat source’s type, axial distance, burial depth of heat source, ratio of thermo-permeability, permeability anisotropy, thermal diffusivity anisotropy and stratification on the thermal consolidation process.  相似文献   

Characterisation of carbonate minerals from hyperspectral TIR scanning using features at 14 000 and 11 300 nm     

D. Green  M. Schodlok 《Australian Journal of Earth Sciences》2016,63(8):951-957

Rapid characterisation of carbonate phases in hyperspectral reflectance spectra acquired from drill core material has important implications for mineral exploration and resource modelling. Major infrared active features of carbonates lie in the thermal region around 6500 nm, 11 300 nm and 14 000 nm, with the latter two features being most useful for differentiating mineral species. A scatter diagram of the wavelength of the 14 000 nm feature vs that of the 11 300 nm feature, powerfully differentiates carbonates. Although the wavelength of the 11 300 nm peak is easily measured, the 14 000 nm trough and peak are commonly weak and their wavelengths can confidently be used only after filtering the spectra, e.g. selecting only those with the trough and peak separated by 175–230 nm, typical of common carbonates. The method is demonstrated with drillhole 120R from the Rosebery polymetallic VHMS deposit in western Tasmania, which has been scanned with the HyLogger-3 system. A 14 000–11 300 plot shows a high degree of clustering of the drillhole 120R data close to the library spectra of calcite, dolomite, Fe-dolomite, ankerite, kutnohorite, rhodochrosite, Fe-rhodochrosite and siderite. The interpreted compositions of the carbonate spectral populations strongly correlate with the chemical populations of 144 analysed carbonates and provide a highly resolved spatial framework for interpreting carbonate alteration.  相似文献   

Weak ENSO Asymmetry Due to Weak Nonlinear Air–Sea Interaction in CMIP5 Climate Models   总被引：1，自引：0，他引：1  

Yan Sun  Fan Wang  De-Zheng Sun 《大气科学进展》2016,33(3):352-364

State-of-the-art climate models have long-standing intrinsic biases that limit their simulation and projection capabilities.Significantly weak ENSO asymmetry and weakly nonlinear air–sea interaction over the tropical Pacific was found in CMIP5(Coupled Model Intercomparison Project, Phase 5) climate models compared with observation. The results suggest that a weak nonlinear air–sea interaction may play a role in the weak ENSO asymmetry. Moreover, a weak nonlinearity in air–sea interaction in the models may be associated with the biases in the mean climate—the cold biases in the equatorial central Pacific. The excessive cold tongue bias pushes the deep convection far west to the western Pacific warm pool region and suppresses its development in the central equatorial Pacific. The deep convection has difficulties in further moving to the eastern equatorial Pacific, especially during extreme El Ni o events, which confines the westerly wind anomaly to the western Pacific. This weakens the eastern Pacific El Ni o events, especially the extreme El Ni o events, and thus leads to the weakened ENSO asymmetry in climate models. An accurate mean state structure(especially a realistic cold tongue and deep convection) is critical to reproducing ENSO events in climate models. Our evaluation also revealed that ENSO statistics in CMIP5 climate models are slightly improved compared with those of CMIP3. The weak ENSO asymmetry in CMIP5 is closer to the observation. It is more evident in CMIP5 that strong ENSO activities are usually accompanied by strong ENSO asymmetry, and the diversity of ENSO amplitude is reduced.  相似文献   

Anomalous Western Pacific Subtropical High during Late Summer in Weak La Nia Years: Contrast between 1981 and 2013     

Feng Xue  Fangxing Fan 《大气科学进展》2016,33(12):1351-1360

Both 1981 and 2013 were weak La Niña years with a similar sea surface temperature (SST) anomaly in the tropical Pacific, yet the western Pacific subtropical high (WPSH) during August exhibited an opposite anomaly in the two years. A comparison indicates that, in the absence of a strong SST anomaly in the tropics, the cold advection from Eurasian high latitudes and the convection of the western Pacific warm pool play important roles in influencing the strength and position of the WPSH in August. In August 1981, the spatial pattern of 500 hPa geopotential height was characterized by a meridional circulation with a strong ridge in the Ural Mountains and a deep trough in Siberia, which provided favorable conditions for cold air invading into the lower latitudes. Accordingly, the geopotential height to the north of the WPSH was reduced by the cold advection anomaly from high latitudes, resulting in an eastward retreat of the WPSH. Moreover, an anomalous cyclonic circulation in the subtropical western Pacific, excited by enhanced warm pool convection, also contributed to the eastward retreat of the WPSH. By contrast, the influence from high latitudes was relatively weak in August 2013 due to a zonal circulation pattern over Eurasia, and the anomalous anticyclonic circulation induced by suppressed warm pool convection also facilitated the westward extension of the WPSH. Therefore, the combined effects of the high latitude and tropical circulations may contribute a persistent anomaly of the WPSH in late summer, despite the tropical SST anomaly being weak.  相似文献   

江苏一次锢囚状MCS和相关中涡旋MCV的观测分析   总被引：1，自引：1，他引：0  

陈永林  俞小鼎  杨引明  王慧  刘红亚 《气象》2016,42(2):166-173

利用常规地面和高空气象观测资料,结合气象卫星云图和雷达回波,分析了2009年6月14日15—23时(北京时,下同),造成江苏强对流天气的一个中尺度对流系统(MCS)的锢囚状特征的形成过程及其垂直结构。地面中尺度分析表明,雷暴高压东侧在飑前倒槽北端发展的闭合低压环流的东南气流将暖湿空气输送到冷性雷暴高压的北侧形成东南一西北向的暖舌,从而形成锢囚状的结构。长三角探空网资料的垂直结构分析表明,在对流层下部地面到850 hPa为冷性的雷暴高压,在对流层中部700 hPa为冷性的α中尺度涡旋(MCV),而500 hPa已转变为暖性的MCV。静力学关系可以说明MCV仅仅存在于700~500 hPa的原因和MCS下冷上暖的热力结构密切相关。  相似文献   

浙江盛夏一次强对流天气的特征及其成因分析   总被引：4，自引：2，他引：2  

沈杭锋  张红蕾  高天赤  勾亚彬  陈勇明 《气象》2016,42(9):1105-1113

利用常规气象观测资料、区域自动站加密观测资料、GFS 0.5°×0.5°逐6 h分析场数据,以及多普勒雷达、风廓线、微波辐射计探测资料,对2014年7月26日浙江盛夏一次强对流天气过程的特征及其成因进行了诊断分析,结果表明:此次过程发生在副热带高压边缘,由于高空槽东移过程中带来了弱冷空气的渗透,并有大量不稳定能量积聚,形成了午后"上干冷、下暖湿"这样有利于强对流发生的不稳定层结条件和环境背景场。当低层925 hPa的中尺度辐合线和对流层中层700 hPa的垂直上升运动区相重合时,中尺度辐合线附近在未来6 h内产生了强对流,这对强对流的发生发展具有一定的预报指示意义。宁波中尺度辐合线是由偏南风和东北风辐合而成,同时受沿海和喇叭口地形影响,该辐合线早已存在,之后触发了宁波地区的强对流天气。杭州中尺度辐合线是由于宁波雷暴的地面出流增强了偏东风气流,从而加强了偏东风与环境东北风的辐合,导致了杭州中尺度辐合线的形成,随后在辐合线附近出现了剧烈的对流天气。  相似文献   

海风雷暴的观测分析和数值模拟研究进展   总被引：4，自引：0，他引：4  

苏涛  苗峻峰  韩芙蓉 《气象科技》2016,44(1):47-54

沿海地区经济相对繁荣,城市化水平较高,对天气和气候的依赖性强,突发性强对流天气所造成的灾害也会更加严重;同时沿海地区的强对流天气又与海风环流密切相关,因此沿海地区海风雷暴的研究受到了日益广泛的关注,成为了气象学和大气科学中的重要研究对象。在过去的半个多世纪中,海风雷暴的观测和模拟研究取得了大量的研究成果。本文通过对这些研究工作进行回顾和总结,系统地分析了国内外的研究现状,重点讨论了海风雷暴的结构和特征、发展演变过程、触发机制及其预报预警。最后对海风雷暴未来的研究方向进行了探讨,提出了一些有待于研究或需深入研究的问题,以利于今后更好的开展有关海风雷暴的工作,加深对其发生发展规律的认识,提高预报预警水平。  相似文献