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41.
42.
Geraldo Magela da Costa Gabriel de Oliveira Polli Márcio A. Kahwage Eddy de Grave Antônio Claret Soares Sabioni Júlio Cesar Mendes 《Physics and Chemistry of Minerals》2006,33(3):161-166
Mössbauer spectra (MS) of blue, green and yellow beryl (ideally Be3Al2Si6O18) containing approximately 1% of iron were obtained at 295 and 500 K. Room temperature (RT) spectra of both blue and green samples showed the presence of an asymmetric Fe2+ doublet (ΔE
Q~2.7 mm/s, δ~1.1 mm/s), with a very broad low-velocity peak. There is no clear evidence for the presence of a ferric component. The MS of the yellow sample at RT consists of an intense central absorption with parameters typical for Fe3+ (ΔE
Q~0.4 mm/s, δ~0.29 mm/s), plus an apparently symmetrical Fe2+ doublet. This sample acquires a light-blue shade upon heating in air at about 620 K. Thermal treatments at high temperatures caused no significant changes in the MS, but the green and yellow beryl acquire a blue colour. All these results are interpreted in relation to the existence of channel water and the distribution of iron among the available crystallographic sites. 相似文献
43.
库车坳陷侏罗系煤成气动力学模拟研究 总被引:1,自引:0,他引:1
应用黄金管—高压釜封闭体系热模拟实验与GC、GC-IRMS分析技术,结合KINETICS专用软件,对库车坳陷侏罗系煤成气进行了动力学模拟研究。库车坳陷侏罗系煤具有高的产气性,在高演化阶段主要产甲烷气;侏罗系煤热解气甲烷碳同位素为-36‰~-25‰,乙烷碳同位素为-28‰~-16‰;甲烷、C2-C5气态烃的生成活化能分别为(47~64k)calm/ol、(55~72k)calm/ol,频率因子各为5.265×1013s-1、5.388×1018s-1。在此基础上,进一步探讨了克拉2气田天然气的成因。研究认为,克拉2气田天然气属阶段捕获的煤成气,主要聚集了5~1Ma时期的天然气,其成熟度Ro分布范围为1.3%~2.5%。 相似文献
44.
Yang Liu Alfred T. Anderson Colin J. N. Wilson Andrew M. Davis Ian M. Steele 《Contributions to Mineralogy and Petrology》2006,151(1):71-87
Large pyroclastic rhyolites are snapshots of evolving magma bodies, and preserved in their eruptive pyroclasts is a record
of evolution up to the time of eruption. Here we focus on the conditions and processes in the Oruanui magma that erupted at
26.5 ka from Taupo Volcano, New Zealand. The 530 km3 (void-free) of material erupted in the Oruanui event is comparable in size to the Bishop Tuff in California, but differs
in that rhyolitic pumice and glass compositions, although variable, did not change systematically with eruption order. We
measured the concentrations of H2O, CO2 and major and trace elements in zoned phenocrysts and melt inclusions from individual pumice clasts covering the range from
early to late erupted units. We also used cathodoluminescence imaging to infer growth histories of quartz phenocrysts. For
quartz-hosted inclusions, we studied both fully enclosed melt inclusions and reentrants (connecting to host melt through a
small opening). The textures and compositions of inclusions and phenocrysts reflect complex pre-eruptive processes of incomplete
assimilation/partial melting, crystallization differentiation, magma mixing and gas saturation. ‘Restitic’ quartz occurs in
seven of eight pumice clasts studied. Variations in dissolved H2O and CO2 in quartz-hosted melt inclusions reflect gas saturation in the Oruanui magma and crystallization depths of ∼3.5–7 km. Based
on variations of dissolved H2O and CO2 in reentrants, the amount of exsolved gas at the beginning of eruption increased with depth, corresponding to decreasing
density with depth. Pre-eruptive mixing of magma with varying gas content implies variations in magma bulk density that would
have driven convective mixing.
Electronic Supplementary Material Supplementary material is available for this article at and is accessible for authorized users. 相似文献
45.
Cyclicity in the Main and Upper Zones of the Bushveld Complex, South Africa: Crystallization from a Zoned Magma Sheet 总被引:9,自引:0,他引:9
The major element composition of plagioclase, pyroxene, olivine,and magnetite, and whole-rock 87Sr/86Sr data are presented forthe uppermost 2·1 km of the layered mafic rocks (upperMain Zone and Upper Zone) at Bierkraal in the western BushveldComplex. Initial 87Sr/86Sr ratios are near-constant (0·7073± 0·0001) for 24 samples and imply crystallizationfrom a homogeneous magma sheet without major magma rechargeor assimilation. The 2125 m thick section investigated in drillcore comprises 26 magnetitite and six nelsonite (magnetiteilmeniteapatite)layers and changes up-section from gabbronorite (An72 plagioclase;Mg# 74 clinopyroxene) to magnetiteilmeniteapatitefayaliteferrodiorite (An43; Mg# 5 clinopyroxene; Fo1 olivine). The overallfractionation trend is, however, interrupted by reversals characterizedby higher An% of plagioclase, higher Mg# of pyroxene and olivine,and higher V2O5 of magnetite. In the upper half of the successionthere is also the intermittent presence of cumulus olivine andapatite. These reversals in normal fractionation trends definethe bases of at least nine major cycles. We have calculateda plausible composition for the magma from which this entiresuccession formed. Forward fractional crystallization modelingof this composition predicts an initial increase in total iron,near-constant SiO2 and an increasing density of the residualmagma before magnetite crystallizes. After magnetite beginsto crystallize the residual magma shows a near-constant totaliron, an increase in SiO2 and decrease in density. We explainthe observed cyclicity by bottom crystallization. Initiallymagma stratification developed during crystallization of thebasal gabbronorites. Once magnetite began to crystallize, periodicdensity inversion led to mixing with the overlying magma layer,producing mineralogical breaks between fractionation cycles.The magnetitite and nelsonite layers mainly occur within fractionationcycles, not at their bases. In at least two cases, crystallizationof thick magnetitite layers may have lowered the density ofthe basal layer of melt dramatically, and triggered the proposeddensity inversion, resulting in close, but not perfect, coincidenceof mineralogical breaks and packages of magnetitite layers. KEY WORDS: layered intrusion; mineral chemistry; isotopes; magma; convection; differentiation 相似文献
46.
阿克库勒地区卡拉沙依组碎屑岩储层的成分成熟度和结构成熟度均较低.储层的次生溶蚀孔隙所占比例远高了:原生孔隙,次生孔隙是储层的主要储集空间.样品数据统计显示,卡拉沙依组储层属于低孔、低渗储层类型.根据岩石薄片、铸体薄片观察及储层样品的扫描电镜和阴极发光分析结果,本区石炭系储层主要经历的成岩作用有压实(压溶)作用、胶结作用、溶蚀作用和交代作用,其中碳酸盐矿物的沉淀和溶蚀作用是本区卡拉沙依组储层所经历的最重要的成岩作用.成岩作用已达到晚成岩B期,早期方解石交代石英颗粒并发生大量溶蚀,生成大量次生孔隙,晚期方解石没有发生溶蚀. 相似文献
47.
48.
利用由美国NOAA系列卫星观测的OLR资料研究了影响华东地区热带气旋年频数(记为ATC)与热带对流场的关系,结果表明两者存在密切的联系:(1)当华东地区热带气旋年频数ATC为异常偏多(少)时,ITCZ位置累积距平为正(负)值,即ITCZ位置异常偏北(南);(2)利用OLR设计了Walker综合指数WI,该指数的强弱可以反映ATC的异常情况,即当ATC为异常偏多(少)时,walker环流圈异常强(弱);(3)OLR距平累积量场能较好的表征ATC异常年份所对应的低纬度及中高纬地区大气环流的配置,其可以作为预测影响华东地区热带气旋年频数的强信号。 相似文献
49.
本文根据大量实测数据,首次系统地报道了中国西北地区塔里木盆地、准噶尔盆地和柴达木盆地内的岩石热导率、岩石放射性生热率数据及其分布特征.对600多个岩石热导率和100多个实测岩石生热率的统计分析表明,沉积盆地中岩石的热物理性质与其岩性、埋藏深度和地层时代密切相关.随深度和地层时代的加大,岩石热导率增大;塔里木盆地的岩石热导率的总体平均值最大,而柴达木盆地的最小.岩石生热率在上地壳的分布是随深度的增加而减小的,但在沉积盆地的深度范围内几乎不变,其分布是均匀的,仅不同岩性的生热率差别较大.估算的岩石放射性生热产生的热量可以占到盆地地表热流的25%~45%.因此,岩石热物理性质的参数不仅与盆地的地温分布和大地热流特征密切相关,还可以为该地区盆地热历史恢复及深部地球物理的研究提供有效的参数和边界条件. 相似文献
50.
车镇凹陷沙河街组的沉积体系受控于盆地内的构造、物源供给以及沉积时的气候环境。以岩石学特征为基础,描述了成岩过程中压实与压溶作用、胶结作用、溶解作用与次生孔隙的特征,以及次生孔隙带在本区的分布。论述了碳酸盐胶结物与粘土矿物胶结作用的特点。粘土矿物蒙脱石-伊利石转变具有明显的渐变与突变交替的演化程式,其演化经历了蒙脱石带、渐变带、迅速转化带和伊利石带以及蒙脱石向伊利石的转变带。沙河街组的成岩作用划分为早期成岩阶段(A期、B期)和晚期成岩阶段(A期、B期、C期),并提出了成岩阶段的划分标志。 相似文献