High-temperature X-ray investigation of natural columbites     

S. C.?Tarantino  M.?ZemaEmail author  M.?Pistorino  M. C.?Domeneghetti 《Physics and Chemistry of Minerals》2003,30(10):590-598

Structural investigations at high temperature were carried out on natural columbite samples across the join Fe(Nb_0.95Ta_0.05)₂O₆–Mn(Nb_0.95Ta_0.05)₂O₆. The samples were preliminarily annealed to attain the complete cation-ordered state and avoid the superimposition of the effects of cation ordering during high-temperature studies. Unit-cell parameters of three columbites with different X_Fe content were measured at regular intervals in the temperature range 25–900 °C using single-crystal X-ray diffraction techniques. The crystal structures of completely ordered ferrocolumbite and manganocolumbite were also refined from intensity data collected at room temperature, 300 and 600 °C. Structural thermal expansion coefficients show positive, linear expansion of a, b, c lattice constants and cell volume. In general, slightly higher expansion occurs along a and c directions. However, anisotropy decreases sharply with decreasing Fe content. Reversibility of thermal expansion in the investigated temperature range was checked by high-temperature diffraction studies under heating-up and cooling-down conditions. Impurities do not play an important role in thermal expansion of columbites; expansion coefficients measured on two crystals of the same sample characterized by different Ti content are in fact almost identical. Structural changes with temperature essentially affect bond lengths: volumes of both A and B octahedral sites increase linearly with temperature, whereas interpolyhedral geometrical parameters do not vary significantly.  相似文献   

绵竹三箭水S1井温泉补给源的同位素示踪研究   总被引：1，自引：0，他引：1  

徐进勇  王多义  尹观 《矿物岩石》2003,23(2):75-78

根据绵竹三箭水S1井相关地质区域内各水体的氢、氧同位素组成和放射性同位素氚浓度,结合该区的地质背景,利用同位素示踪手段,基本确定该井温泉地下水的成因为大气降水渗入补给主体含水层补给源在西北部1700m左右的“彭灌杂岩”高山区一带、补给量相对稳定,水温不会有大波动,有远期开发价值。  相似文献   

Characterization of beryl (aquamarine variety) from pegmatites of Minas Gerais,Brazil   总被引：2，自引：0，他引：2  

R. R. Viana  H. Jordt-Evangelista  G. Magela da Costa  W. B. Stern 《Physics and Chemistry of Minerals》2002,29(10):668-679

Eight samples of the beryl variety aquamarine were selected from four pegmatites in the Governador Valadares and Araçuaí regions in northeastern Minas Gerais State, Brazil. These samples were fully characterized by chemical analysis, infrared and UV-visible spectroscopy, thermal analyses, and high-temperature X-ray diffraction (from room temperature up to 800 °C). Several physical and chemical properties of beryl were found to depend on the amount of water and ions residing in the structural channels. The thermal expansion coefficients from room temperature to about 800 °C are temperature-independent, with αa ? ?3.2 × 10^?6 ° C^?1 and αc ? ?8.7 × 10^?6 ° C^?1. The contraction of both a and c unit-cell parameters with increasing temperature and the shift of the infrared band centered at about 1200 cm^?1 were tentatively ascribed to interactions between channel water and the silicate rings.The color of beryl seems to be dictated by the relative proportions of Fe³⁺ in the octahedralsites and of fe²⁺ in the channels. Thus, deep-blue samples have little Fe³⁺, whereas greener samples have more Fe³⁺ or less channel Fe²⁺.  相似文献   

Geochemistry of the thermal springs and fumaroles of Basse-Terre Island,Guadeloupe, Lesser Antilles     

Tatjana Brombach  Luigi Marini  Johannes C. Hunziker 《Bulletin of Volcanology》2000,61(7):477-490

 The purpose of this work was to study jointly the volcanic-hydrothermal system of the high-risk volcano La Soufrière, in the southern part of Basse-Terre, and the geothermal area of Bouillante, on its western coast, to derive an all-embracing and coherent conceptual geochemical model that provides the necessary basis for adequate volcanic surveillance and further geothermal exploration. The active andesitic dome of La Soufrière has erupted eight times since 1660, most recently in 1976–1977. All these historic eruptions have been phreatic. High-salinity, Na–Cl geothermal liquids circulate in the Bouillante geothermal reservoir, at temperatures close to 250  °C. These Na–Cl solutions rise toward the surface, undergo boiling and mixing with groundwater and/or seawater, and feed most Na–Cl thermal springs in the central Bouillante area. The Na–Cl thermal springs are surrounded by Na–HCO₃ thermal springs and by the Na–Cl thermal spring of Anse à la Barque (a groundwater slightly mixed with seawater), which are all heated through conductive transfer. The two main fumarolic fields of La Soufrière area discharge vapors formed through boiling of hydrothermal aqueous solutions at temperatures of 190–215  °C below the "Ty" fault area and close to 260  °C below the dome summit. The boiling liquid producing the vapors of the Ty fault area has δD and δ¹⁸O values relatively similar to those of the Na–Cl liquids of the Bouillante geothermal reservoir, whereas the liquid originating the vapors of the summit fumaroles is strongly enriched in ¹⁸O, due to input of magmatic fluids from below. This process is also responsible for the paucity of CH₄ in the fumaroles. The thermal features around La Soufrière dome include: (a) Ca–SO₄ springs, produced through absorption of hydrothermal vapors in shallow groundwaters; (b) conductively heated, Ca–Na–HCO₃ springs; and (c) two Ca–Na–Cl springs produced through mixing of shallow Ca–SO₄ waters and deep Na–Cl hydrothermal liquids. The geographical distribution of the different thermal features of La Soufrière area indicates the presence of: (a) a central zone dominated by the ascent of steam, which either discharges at the surface in the fumarolic fields or is absorbed in shallow groundwaters; and (b) an outer zone, where the shallow groundwaters are heated through conduction or addition of Na–Cl liquids coming from hydrothermal aquifer(s). Received: 9 November 1998 / Accepted: 15 July 1999  相似文献   

高精度热电离质谱(TIMS)铀系法洞穴沉积物(石笋)年龄的研究   总被引：5，自引：1，他引：4  

王兆荣  彭子成  孙卫东  仉守斌 《沉积学报》2000,18(1):162-164

用高精度热电离质谱技术测定石笋的年龄,初步建立了热电离质谱铀系年龄的方法。 4个样品的测定结果复现性较好,铀含量、同位素比值及年龄值与标准值吻合,数据的精度大大提高,显示了质谱铀系年龄方法具有样品量少、时间短、精度高的优点。  相似文献   

Manifestation and measurement of the fractal characteristics of karst hydrogeological formations     

Athanasios J. Maramathas  Andreas G. Boudouvis 《Advances in water resources》2006

A new method of estimating the fractal dimension of the percolation backbone of karst systems, which are discharged through karst springs, is presented. This method is based on the simulation of the spring by the MODKARST deterministic mathematical model. Application has been made to the Psiloritis karst formation in Crete, which feeds the periodically brackish karst spring “Almiros” in Crete. Furthermore, the estimated dimension justifies an independently determined power law that quantifies the sea intrusion into the karst system.  相似文献   

山东省春秋季暴雨天气的环流特征和形成机制初探   总被引：7，自引：2，他引：7       下载免费PDF全文

杨晓霞 万丰刘还珠  薛德强华岩 《应用气象学报》2006,17(2):183-191

对山东省春秋季暴雨的气候特征和影响系统进行了分析, 制作了春秋季暴雨的平均环流形势图。分析了2003年春秋季两次大范围暴雨的环流特征和影响系统及暴雨期间大气的热力特征和水汽输送特征, 应用k-螺旋度和倾斜涡度发展理论, 分析了暴雨的形成机制。结果表明:4月暴雨均受气旋影响, 10月暴雨以冷锋影响居多。2003年4月17—18日为气旋暴雨, 10月10—12日为切变线冷锋暴雨。两次暴雨前都有低空偏南风急流向暴雨区输送水汽, 大气强烈增温增湿, 对流不稳定度增大, 湿斜压性增强。强冷锋南下触发对流不稳定能量释放, 产生暴雨。暴雨期间低层正k-螺旋度猛烈发展。暴雨前期中低层MPV1 < 0且MPV2 > 0, 冷锋影响期间MPV1 > 0且MPV2 < 0, 都有利于倾斜涡度发展, 增强了上升运动。  相似文献   

东亚副热带西风急流季节变化特征及其热力影响机制探讨   总被引：19，自引：0，他引：19  

况雪源  张耀存 《气象学报》2006,64(5):564-575

利用1961—2000年NCEP/NCAR月平均再分析资料对东亚副热带西风急流强度和位置的季节变化进行了分析,指出急流位置季节变化不仅有明显的南北向移动,6—7月还存在东西方向的突变特征,同时急流轴在北进过程中具有东西向的不一致性,急流中心强度的变化超前于位置的南北移动。在此基础上,采用动态追随急流中心移动的方法,探讨东亚副热带西风急流季节变化的热力影响机制,发现东亚副热带西风急流强度变化及位置移动与对流层中上层气温南北差异的分布结构有很好的对应关系,这说明急流的季节演变是对辐射季节变化及由于东亚特殊的海陆分布和青藏高原大地形影响而造成纬向不均匀加热的响应。从各热量输送项与急流的关系来看,从冬半年到夏半年的增暖时段,急流中心南北温差减小,急流减弱北进;从夏半年到冬半年的降温时段,急流中心南北温差增大,急流加强南退。热量平流输送的经向差异是造成急流中心南北温差的主要原因,急流跟随热量平流输送最大经向梯度中心位置南北移动。非绝热加热对急流中心的东西移动有引导作用,青藏高原春夏季对对流层中上层强大的加热作用是导致6—7月急流中心位置西移突变的原因。  相似文献   

THE VARIATION OF THE SPRING PRECIPITATION IN GUANGZHOU AND ITS PRECURSORY SIGNALS     

谷德军  纪忠萍  林爱兰  郝立生 《热带气象学报(英文版)》2006,12(2):121-129

Guangzhou spring rainfall mainly exhibits interannual variation of Quasi-biannual and interdecadal variation of 30 yrs, and is in the period of weak rainfall at interdecadal time scale. SST anomalies (SSTA) of Nino3 are the strongest precursor of Guangzhou spring rainfall. They have significant positive correlation from previous November and persist stably to April. Nino3 SSTA in the previous winter affects Guangzhou spring rainfall through North Pacific subtropical high and low wind in spring. When Nino3 SSTA is positive in the previous winter, spring subtropical high is intense and westward, South China is located in the area of ascending airflow at the edge of the subtropical high, and water vapor transporting to South China is intensified by anticyclone circulation to the east of the Philippines. So Guangzhou spring rainfall is heavy. When Nino3 SSTA is negative, the subtropical high is weak and eastward, South China is far away from the subtropical high and is located in the area of descending airflow, and water vapor transporting to South China is weak because low-level cyclonic circulation controls areas to the east of the Philippines and north wind prevails in South China. So Guangzhou spring rainfall is weak and spring drought is resulted.  相似文献   

建筑群对城市冠层动力、热力效应的数值试验研究     

宋金暖  王振会  何金海  许建明 《气象与减灾研究》2006,29(3):5-11

利用中尺度模式MM5,分别耦合传统的边界层参数化方案和城市冠层参数化方案,模拟了2001年冬季北京冠层大气的动力、热力特征,并和观测资料进行了对比分析.分析结果表明,城市冠层参数化方案更能细致描述建筑群对城市冠层大气的动力、热力作用.由于建筑群的动力、热力作用,使北京城区的温度升高,风速减小,湍流动能增强,形成了明显的增温区、阻风区和湍能增强区,中心均位于城区高大建筑群附近,并向郊区递减.  相似文献