Experiment and Pitzer Model Prediction for the Solid + Liquid Equilibria of the Ternary System LiCl–CaCl2–H2O     

MENG Lingzong  LI Dan  DENG Tianlong  GUO Yafei 《《地质学报》英文版》2014,88(Z1):356-358

正1 Introduction Lithium resources are widely distributed in the oilfield brine from the Nanyishan district in the Qaidam Basin(Fan et al.,2007).The investigation of the thermodynamics and phase diagram of the brine system is valuable in providing the theoretic foundation and scientific guidance in the comprehensive exploitation of the mixture salts effectively.Comprehensive  相似文献   

A virtual experiment technique on the elementary behaviour of granular materials with discrete element method     

Xia Li  Hai‐Sui Yu  Xiang‐Song Li 《国际地质力学数值与分析法杂志》2013,37(1):75-96

Multi‐scale investigations aided by the discrete element method (DEM) play a vital role for current state‐of‐the‐art research on the elementary behaviour of granular materials. Similar to laboratory tests, there are three important aspects to be considered carefully, which are the proper stress/strain definition and measurement, the application of target loading paths and the designed experiment setup, to be addressed in the present paper. Considering the volume sensitive characteristics of granular materials, in the proposed technique, the deformation of the tested specimen is controlled and measured by deformation gradient tensor involving both the undeformed configuration and the current configuration. Definitions of Biot strain and Cauchy stress are adopted. The expressions of them in terms of contact forces and particle displacements, respectively, are derived. The boundary of the tested specimen consists of rigid massless planar units. It is suggested that the representative element uses a convex polyhedral (polygonal) shape to minimize possible boundary arching effects. General loading paths are described by directly specifying the changes in the stress/strain invariants or directions. Loading can be applied in the strain‐controlled mode by specifying the translations and rotations of the boundary units, or in the stress‐controlled mode by using a servo‐control mechanism, or in the combination of the two methods to realize mixed boundary conditions. Taking the simulation results as the natural consequences originated from a complex system, virtual experiments provide particle‐scale information database to conduct multi‐scale investigations for better understanding in granular material behaviours and possible development of the constitutive theories provided the qualitative similarity between the simulation results from virtual experiments and observations on real material behaviour. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Explicit solutions for the instantaneous undrained contraction of hollow cylinders and spheres in porous elastoplastic medium     

A. Giraud  F. Homand  V. Labiouse 《国际地质力学数值与分析法杂志》2002,26(3):231-258

In this article we present closed‐form solutions for the undrained variations in stress, pore pressure, deformation and displacement inside hollow cylinders and hollow spheres subjected to uniform mechanical pressure instantaneously applied to their external and internal boundary surfaces. The material is assumed to be a saturated porous medium obeying a Mohr–Coulomb model failure criterion, exhibiting dilatant plastic deformation according to a non‐associated flow rule which accounts for isotropically strain hardening or softening. The instantaneous response of a porous medium submitted to an instantaneous loading is undrained, i.e. without any fluid mass exchange. The short‐term equilibrium problem to be solved is now formally identical to a problem of elastoplasticity where the constitutive equations involve the undrained elastic moduli and particular equivalent plastic parameters. The response of the model is presented (i) for extension and compression undrained triaxial tests, and (ii) for unloading problems of hollow cylinders and spheres through the use of appropriately developed closed‐form solutions. Numerical results are presented for a plastic clay stone with strain hardening and an argilite with strain softening. The effects of plastic dilation, of the strain softening law and also of geometry of the cavity on the behaviour of the porous medium have been underlined. Analytical solutions provide valuable benchmarks enabling various numerical methods in undrained conditions with a finite boundary to be verified. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

崩落法开采引起的岩层移动时效性研究     

刘轩廷  陈从新  夏开宗  郑先伟  王田龙  袁家好 《岩土力学》2023,(2):563-576

崩落法开采的金属矿山往往会伴随着一系列的地质灾害现象。为保证矿区安全生产,开展崩落法开采引起的岩层移动的时效性研究具有重要意义。以程潮铁矿西区下盘为研究对象,通过将地表10多年GPS监测数据的整理分析,并与现场破坏调查结果和工程地质条件相结合,进而探究不同分区下岩层移动的时效行为。研究结果表明：岩层移动的时效行为与其破坏过程有着密切的关系,不同分区下的岩层移动的时效行为是不同的,可分为初始变形、渐进变形、加速变形和残余变形共4个阶段,分别对应着稳定状态、临界状态、失稳状态以及采矿结束后的蠕变状态;初始变形阶段对应着岩体的初始蠕变过程,渐进变形阶段反映了岩体抵抗自身变形的过程,加速变形阶段与深部破坏面的形成和强烈的应力释放有关;崩落碎石在采矿作业停止后失去了流动空间,在岩体变形挤压下会对围岩提供支撑力进而限制了岩层移动的进一步发展;残余变形时间由岩体的蠕变特性和崩落碎石的压密过程所控制,倾倒滑移区因需要经历一个额外的碎石压密过程而导致残余变形时间更长。  相似文献   

Crucial control on magmatic-hydrothermal Sn deposit in the Tengchong block,SW China: Evidence from magma differentiation and zircon geochemistry     

《地学前缘(英文版)》2022,13(4):101401

Magmatic-hydrothermal Sn deposits are commonly associated with high silica magmas, but why most global high silica granites do not bear economic Sn ore grades remains unclear. Two crucial factors controlling magmatic-hydrothermal Sn mineralization, including advanced fractionation and depressurization-induced rapid cooling, were revealed in the case study of the Guyong granitic pluton linked with the Xiaolonghe Sn deposit, in the Tengchong block, SW China. The Guyong granitic pluton comprises three petrological facies: less evolved biotite syenogranite, evolved alkali granite and leucogranite, and highly evolved facies (the protolith of greisenized granite). Similar crystallization ages (～77 Ma) and gradual contact between different petrological facies indicate the Guyong granitic pluton records a continuous fractionation process. Monte Carlo-revised Rayleigh fractionation model suggests the fractionation degree of the Guyong pluton is markedly high (>87 wt.%) that can only be achieved by a high initial water (≥4 wt.%) content in the parent granitic magma revealed by rhyolite-MELTS calculation. Advanced degree fractionation causes the first Sn enrichment but it also significantly increases the viscosity of evolved magmas, suppressing the exsolution and transport of hydrothermal fluids. Hence, it must be compensated by the second critical factor: depressurization-induced rapid cooling, reflected by the occurrence of highly metamict zircons in the greisenized granite. The highly metamict feature, indicated by the large full width at half maximum (FWHM) values of zircon ν₃(SiO₄) peak (>19.5 cm^?1), suggests these zircons do not experience thermal annealing but rapidly ascend into a shallow cooling environment. Depressurization-induced rapid cooling facilitates exsolution and transport of hydrothermal fluids, interacting with wall rocks and resulting in Sn mineralization.  相似文献   

热力学计算模拟对初始月幔结构的约束SCIEI北大核心CSCD     

鞠东阳  庞润连  李瑞  杜蔚 《岩石学报》2022,38(4):1025-1042

月球岩浆洋结晶形成的初始月球内部结构是其后续演化过程的开端,其结晶过程受月球岩浆洋的初始深度和物质组成这两个参数的制约。由于缺少直接来自月球深部的岩石样品,目前关于月球岩浆洋演化过程的探讨主要依赖实验和计算模拟手段。岩浆洋模型中形成的月壳厚度是否与探测结果一致是月球岩浆洋演化模型合理性的重要约束。最新的GRAIL(Gravity Recovery and Interior Laboratory)探测数据推算月壳厚度为34~43km,低于阿波罗时期认为的约70km,这对已有的月球岩浆洋演化模型提出了挑战。本文采用并修正FXMOTR程序包,针对月球岩浆洋在不同的初始深度和物质组成情况下的结晶过程,进行了一系列热力学计算模拟。通过量化月球岩浆洋的初始深度和物质组成对月壳厚度的影响,结合关于月球内部微量元素分配的研究结果,对比了月球岩浆洋结晶后期的残余熔体与原始克里普组分(urKREEP)的成分。本文的模拟结果显示,一个全月幔熔融且初始成分为月球初始上月幔组成(LPUM)的岩浆洋将在其深部结晶2.5%石榴子石,形成的月壳厚度符合GRAIL的约束,并且结晶出了合适的urKREEP成分。在此模型的基础上获取了月球初始的内部成分和密度结构,并对后期月幔翻转(Overturn)的程度进行了探讨。  相似文献   

视剖面图温压计研究进展评述   总被引：3，自引：1，他引：2  

吴佳林  翟明国  张红  贾晓亮 《岩石学报》2015,31(6):1711-1721

视剖面图温压计是目前定量估算变质温度和压力的主要方法之一。其理论基础为热力学平衡原理与质量守恒定律。利用内恰的热力学数据库和相应的成分-活度模型对特定成分体系进行视剖面图计算,可以正演模拟给定温度和压力条件下的矿物组合、矿物丰度及其成分,与实测岩石对比,可以准确获取岩石的形成温度和压力。在应用视剖面图温压计时,应选择受全岩成分影响小、且受退变质作用影响微弱的矿物成分;对于有成分变化的体系,应结合多种方法恢复有效全岩成分。文中通过视剖面图对KFMASH(K2O-Fe O-Mg O-Al2O3-Si O2-H2O)体系下不同矿物组合内多硅白云母硅含量及其等值线斜率的研究,认为多硅白云母硅含量及其等值线斜率主要由不同矿物组合内多硅白云母参与的契尔马克替换及纯转换端元反应中的主导反应决定,进一步深化了对变质过程中控制矿物成分变化的内部缓冲反应机制的理解,从而也可为选择和应用矿物温压计提供指导。因此,视剖面图方法是目前研究变质岩石形成条件及变质作用精细过程的最佳方法之一。  相似文献   

Studies on the behaviour of nutrients in the Mandovi Estuary during premonsoon     

S.N. De Sousa 《Estuarine, Coastal and Shelf Science》1983,16(3):299-308

Behaviour of silicate, nitrate and phosphate in the Mandovi Estuary was studied during the premonsoon season. The study shows that silicate is removed from the water column while nitrate showed an internal source. This nitrate source has been identified as the wash water from an iron ore screening plant which discharges the muddy waste directly into the river. Applying mixing relations, the distribution of this nitrate both up- and downstream of the outfall has been studied. Phosphate showed very low concentrations in the low salinity region; however, its concentration increased slightly towards the higher salinity region.  相似文献   

Flounders follow the tides to feed: Evidence from ultrasonic tracking in an estuary     

Soetikno Wirjoatmodjo  T.J. Pitcher 《Estuarine, Coastal and Shelf Science》1984,19(2):231-241

Ultrasonically tagged flounders were tracked in the estuary of the River Bann, Northern Ireland, for periods of between 2 and 12 h (11 fish for a total of 92 h and 2·5 km), during their summer residence. Positions were determined by triangulation with two receivers.All fish remained within 400 m of the release point; on average flounders moved about 270 m during one tidal cycle, equivalent to 830 body lengths, or just over 1 body length per minute. Movements were most likely at dusk, but other parameters were not contingent upon time of day, although no data were gathered at dawn. Frequency, direction, distance, speed and duration of movement and turn rate were all significantly contingent upon state of the tide. The movement data are interpreted in terms of feeding behaviour, supported by results from other parts of the study. At high tide flounders made active but meandering searches for food on the inundated mudflats. Similar but faster searches heading downstream on falling tides reflected (a) completion of feeding while littoral invertebrates were still available and (b) avoidance of stranding. Flounders made infrequent but long and linear passages downstream at low tide, when they tended to bury themselves at the edge of the main channel where there was little food. Subsequently, the fish followed the rising tide upstream so that the cycle of movements kept most fish in the same area of the estuary in the short term. It is suggested that tolerance of changing salinities enables flounders, more than other flatfish species, to exploit dense populations of estuarine intertidal invertebrates as food.  相似文献   

Analytical evaluation of the relativistic thermodynamic functions using binomial expansion theorem and incomplete Gamma functions     

B.A. Mamedov 《New Astronomy》2012,17(3):353-355

A simple evaluation algorithm for calculation of the fermions and bosons relativistic thermodynamic functions with high accuracy is presented. This method is based on the use of the binomial expansion theorems and incomplete Gamma functions. The importance of this result is that it enables a series analytical formula to determine the thermodynamic functions of fermions and bosons in cases of degeneracy and relativity. The formulas obtained are numerically stable for ψ < 0. Examples of comparative calculations are given. Numerical results verify the effectiveness of the present approach and they are in good agreement with literature.  相似文献