紫金山金铜矿二元铜硫化物成分特点的初步研究   总被引：6，自引：3，他引：3  

刘羽  刘文元  王少怀 《矿床地质》2011,30(4):735-741

文章在电子显微成分分析的基础上,结合XRD、振动光谱等研究手段,对高硫型浅成热液形成的紫金山金铜矿床中铜硫化物的成分、物相特点进行了研究.首次在该区找到了久辉铜矿(Cu1.97S)、雅硫铜矿(Cu1.25S)等铜硫二元组分系列矿物,并发现了铜蓝被蓝辉铜矿明显交代的现象,进而推断它们基本上是同期形成的,但其所处的氧化-还...  相似文献   

福建上杭紫金山高硫化型铜矿床矿化分带特征   总被引：3，自引：0，他引：3  

陈可  邱小平  邓俊斌 《福建地质》2013,(4):255-263

通过矿相学,系统分析铜硫化物以及脉石矿物的结构构造、形态特征以及嵌布特征,主要铜硫化物为铜蓝、斜方蓝辉铜矿;通过电子探针,分析铜硫化物各种元素含量,尤其是主量元素Cu/S比值垂向变化规律在钻孔浅部无明显规律,随着深度增加Cu/S比值逐渐减小,最后趋近于一个常数约为1.3。铜矿成矿影响因素:(1)火山机构的温度影响范围有限,并未改变铜硫化物的矿物组合特征,只是影响铜硫化物Cu/S比值分配,表现为越远离火山机构Cu/S比值越高;(2)高氧逸度条件是形成稳定铜硫化物的重要条件。氧逸度垂向由上至下先是具有高氧逸度,随着深度增加氧逸度逐渐减小,最后增加为高氧逸度。Cu/S比值变化规律为今后紫金山铜矿深部找矿提供重要的矿化信息。  相似文献   

The nature and origin of pigments in black opal from Lightning Ridge,New South Wales,Australia     

J. R. Herrmann  R. Maas  P. F. Rey  S. P. Best 《Australian Journal of Earth Sciences》2013,60(7):1027-1039

Abstract

Black opal (opal-AG) owes its dark coloration to a fine-grained pigment commonly inferred to be mainly carbon, yet chemical compositions for black opals suggest there may be additional components. Here we search for such components in pigment concentrates prepared by dissolving black opal nodules (nobbies) from Lightning Ridge (NSW) in hydrofluoric acid, using electron microscopy (scanning electron microscopy, transmission electron microscopy), X-ray diffraction and laser-ablation ICP-MS. The results demonstrate the presence of sulfides—predominantly pyrite and chalcopyrite, with minor galena and Ti-oxide phases, as additional components of the pigment. ATR-FTIR analysis indicates the presence of C=O and C–H groups, consistent with an organic origin. Transmission electron microscopy images of pigment show variously deformed, originally spherical ～100?nm particles rich in sulfide and carbon, which are interpreted as thin coatings of pigment on now dissolved opaline silica spheres. Laser-ablation ICP-MS analysis identifies remnant silica in pigment concentrates, which may be interpreted as opaline silica surviving HF treatment protected as inclusions in sulfides. When examined within the context of petrographic observations from more than 1000 opal nodules (nobbies) at Lightning Ridge, these new results suggest that pigment carbon and sulfides in the nodules formed microbially under initially anoxic groundwater conditions, within pre-existing cavities concurrently being filled with silica sol ultimately derived from chemical weathering of feldspar-rich volcaniclastic sediment. Intensely black pigment layers observed at the floor of many nodules indicate settling of dark, high-density (sulfide–Ti-oxide-rich) pigment within cavities, with the implication that sulfate-reducing bacterial (SRB) activity commences early during the silica sol-gel ripening process. Microbial activity may persist until after the cavity has completely filled with the silica sol, as illustrated by abundant black opals with uniformly distributed pigment. Pigment formed at this stage may no longer be able to settle out within the ripening and increasingly viscous silica gel, thus forming pigmentation throughout the opal cavity. The existence of ‘amber’, pigment-poor opal with intensely black basal pigment layers is interpreted as signalling a lack of sulfate to sustain further SRB activity, or a change to more oxidising conditions, possibly related to interaction with surface waters within a downward-penetrating weathering front. A change in redox conditions would shut off activity of SRB and thus sulfide pigment production and allow development of aerobic microbial activity as described by others.  相似文献   

Hydrothermal Activity Events at Kairei Field,Central Indian Ridge 25°S     

Yejian WANG  Xiqiu HAN  Xianglong JIN  Zhongyan QIU  Zhibang MA  Haili YANG 《Resource Geology》2012,62(2):208-214

The Kairei hydrothermal field is located on the Central Indian Ridge at 70°02′E, 25°19'S, which was discovered in 2000. Eight representative hydrothermal product samples including massive sulfide, sulfide chimney and mineralized rock breccia samples collected from this field were age‐dated using the ²³⁰Th/²³⁴U and ²¹⁰Pb/Pb methods. Four episodes of hydrothermal activity were determined: 94.5 to 96.3 ka (event I), 56.6 to 61.2 ka (event II), 8.4 to 10.6 ka (event III), and <180 a to present (event IV). Among them, event I is the oldest and is characterized by the low‐temperature mineralization of rock breccias which probably represents for the onset of the hydrothermal activity of the field. Events II to IV represent the episodic high‐temperature hydrothermal activities characterized by Cu and Zn‐rich sulfides. The recent hydrothermal activity has lasted for at least 180 a.  相似文献   

PGE distribution in massive sulfides from the P<Emphasis Type="SmallCaps">ACMANUS</Emphasis> hydrothermal field,eastern Manus basin,Papua New Guinea: implications for PGE enrichment in some ancient volcanogenic massive sulfide deposits     

Jan?Pa?avaEmail author  Anna?Vymazalová  Sven?Petersen  Peter?Herzig 《Mineralium Deposita》2004,39(7):784-792

The distribution of platinum group elements (PGE) in Cu- and Zn-rich samples from the Roman Ruins and Satanic Mills vent sites in the PACMANUS hydrothermal field (Papua New Guinea) was studied and compared to that from selected ancient volcanogenic massive sulfide (VMS) deposits. Samples from the Satanic Mills site are enriched in Pd and Rh when compared to samples from Roman Ruins and reach highest values in active and inactive Cu-rich black smoker chimneys and chalcopyrite-cemented dacite breccias (up to 356 ppb Pd and up to 145 ppb Rh). A significant positive correlation was established between Cu and Pd and Rh in samples from both vent sites. Comparisons of chondrite normalized patterns and values of Pd/Pt and Pd/Ir ratios in Cu-rich sulfides and probable source rocks (felsic volcanic rocks/MORB) along with the evidence for a magmatic component in the PACMANUS hydrothermal system indicate that leaching of back-arc volcanic rocks together with addition of magmatic volatiles to the convecting hydrothermal system was the most important factor for PGE enrichment at PACMANUS and likely at some PGE-enriched ancient VMS deposits.An erratum to this article can be found at Editorial handling: B. Lehmann  相似文献   

New insights into the Re-Os systematics of sub-continental lithospheric mantle from in situ analysis of sulphides   总被引：1，自引：0，他引：1  

Olivier Alard  William L. Griffin  Norman J. Pearson 《Earth and Planetary Science Letters》2002,203(2):651-663

The Os isotopic compositions of mantle rocks generally are considered to be established during melt-depletion events and to be robust to subsequent disturbances (e.g. metasomatism). Consequently, Os isotopes are used to date the main melting event that a mantle section has undergone, i.e. transformation of fertile asthenospheric material into a depleted, buoyant lithosphere. However, Os resides almost entirely in Fe-Ni-Cu sulphides, which can be very mobile under mantle conditions. In situ laser ablation multi-collector ICP-MS measurement of Re/Os isotopic ratios in sulphides from spinel peridotite xenoliths demonstrates that whole-rock Os-isotope signatures record the mixing of multiple sulphide populations. Sulphides residual after melting events have unradiogenic Os isotopic compositions reflecting ancient melt depletion; those introduced by later metasomatism events contain more radiogenic Os. Therefore, the whole-rock Os isotopic signature can be strongly altered by metasomatic processes, and studies of mantle-derived xenoliths show that such disturbance is quite common in the lithospheric mantle. Because melt-depletion ages estimated from individual sulphide inclusions are systematically older than those obtained from whole-rock analysis, caution is essential in the interpretation of the Os model ages derived from whole-rock analysis, and their use and abuse in geodynamic models. This work suggests that sulphide could become a key phase in unravelling the formation and evolution of the lithosphere.  相似文献   

Determination of the "Difficult" Elements Ag, B, Ge, Mo, Sn, Tl and W in Geochemical Reference Samples and Silicate Rocks of the GeoPT Proficiency Testing Series by DC Arc Atomic Emission Spectrometry     

Albina I. Kuznetsova  Nina L. Chumakova 《Geostandards and Geoanalytical Research》2002,26(3):307-312

Reference samples of rocks from the Institute of Geochemistry, Irkutsk (IGI) and the Research Institute of Applied Physics, Irkutsk University (RIAP) and silicate rocks from the GeoPT proficiency testing series were analysed with the aim of determining Ag, B, Ge, Mo, Sn, Tl and W abundances by an atomic-emission method with air-stabilized D.C. arc excitation. Many of the results reported are without recommended or assigned values. The results are compared with compilation data from the literature and, where possible, with assigned values for samples of the Geo PT series.  相似文献   

The Source of Silica and Trace Metals in Particulate Matter in Framvaren Fjord     

David W. Dyrssen 《Aquatic Geochemistry》1997,3(4):329-343

The lake and streams in the Framvarenwatershed were sampled and analyzed in September 1983.The results can be explained by the precipitation ofacid rain containing some sea salts and thedissolution of Farsundite, the dominating rock in thecatchment area. The runoff supplies the surface waterof Framvaren with silica, aluminium, manganese, iron,copper, zinc, cadmium and lead. Reasonablecalculations show that the runoff most likely is themain source for the particulate matter found insediment traps and by filtering off suspendedparticles. Thus the calculations supplement recentstudies of Skei et al. (1996). This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Archean Mass-independent Fractionation of Sulfur Isotope:New Evidence of Bedded Sulfide Deposits in the Yanlingguan-Shihezhuang area of Xintai, Shandong Province     

LI Yanhe  HOU Kejun  WAN Defang  YUE Guoliang 《《地质学报》英文版》2008,82(2):444-450

Multiple sulfur isotope ratios （^34S/^33S/^32S） of Archean bedded sulfides deposits were measured in the Yanlingguan Formation of the Taishan Group in Xintai, Shandong Province, East of China; 633S = -0.7%o to 3.8‰,δ^34S = 0.1‰-8.8‰, △^33S = -2.3‰ to -0.7‰. The sulfur isotope compositions show obvious mass-independent fractionation （MIF） signatures. The presence of MIF of sulfur isotope in Archean sulfides indicates that the sulfur was from products of photochemical reactions of volcanic SO2 induced by solar UV radiation, implying that the ozone shield was not formed in atmosphere at that time, and the oxygen level was less than 10-5 PAL （the present atmosphere level）. The sulfate produced by photolysis of SO2 with negative △^33S precipitated near the volcanic activity center; and the product of element S with positive △^33S precipitated far away from the volcanic activity center. The lower △^33S values of sulfide （-2.30‰ to --0.25‰） show that Shihezhuang was near the volcanic center, and sulfur was mostly from sulfate produced by photolysis. The higher △^33S values （-0.5‰ to -‰） indicate that Yanlingguan was far away from the volcanic center and that some of sulfur were from sulfate, another from element S produced by photolysis. The data points of sulfur isotope from Yanlingguan are in a line parallel to MFL （mass dependent fractionation line） on the plot of δ^34S--δ^33S, showing that the volcanic sulfur species went through the atmospheric cycle into the ocean, and then mass dependent fractionation occurred during deposition of sulfide. The data points of sulfur isotope from Shihezhuang represent a mix of different sulfur source.  相似文献   

A preliminary discussion on the bio-metallogenesis of Tl deposits in the low-temperature minerogenetic province of southwestern China     

ZHANG Zhong  ZHANG BaoGui  HU Jing  YAO LinBo & TIAN YiFu The Key Laboratory of Ore Deposit Geochemistry  Institute of Geochemistry  Chinese Academy of Sciences  Guiyang  China 《中国科学D辑(英文版)》2007,50(3):359-370

Starting with the research status of bio-metallogenesis of Tl deposits and their geology, this work deals with the geological background of Tl enrichment and mineralization and the mechanism of bio- metal-logenesis of Tl deposits, as exemplified by Tl deposits in the low-temperature minerogenetic province. This research on the bio-metallogenesis of Tl deposits is focused on the correlations between bio-enrichment and Tl, the enrichment of Tl in micro-paleo-animals in rocks and ores, bio-fossil casts in Tl-rich ores, the involvement of bio-sulfur in minerogenesis and the enrichment of bio-genetic organic carbon in Tl ores. Thallium deposits have experienced two ore-forming stages: syngenetic bio- en-richment and epigenetic hydrothermal reworking (or transformation). Owing to the intense epigenetic hydrothermal reworking, almost no bio-residues remain in syngenetically bio-enriched Tl ores, thereby the Tl deposits display the characteristics of hydrothermally reoworked deposits.  相似文献