等离子体发射光谱法直接测定海洋沉积物中的微量稀土元素   总被引：1，自引：2，他引：1       下载免费PDF全文

陈道华  张欣 《岩矿测试》2003,22(1):61-63

应用全谱直读电感耦合等离子体发射光谱法对海洋沉积物中微量稀土元素的测定进行了研究，选择了最佳的仪器工作条件，采用多谱线拟合技术进行校正，样品的加标回收率为94．0％-110．0％。方法采用海底沉积物国家一级标准物质进行验证，测定结果与标准值较吻合，各元素10次测定的RSD≤11．3％。  相似文献   

碱熔沉淀-等离子体质谱法测定地质样品中的多元素   总被引：14，自引：17，他引：14       下载免费PDF全文

王蕾  何红蓼李冰 《岩矿测试》2003,22(2):86-92

采用过氧化钠焙融或偏硼酸锂熔融分解样品，将提取液碱性沉淀，通过过滤分离掉大量熔剂，再将沉淀用酸复溶后用等离子体质谱测定26个元素。通过对比，偏硼酸锂熔融—酸提取—碱性沉淀的方案，空白低，易操作，成本低，大多数元素测定结果的相对误差＜10％，相对标准偏差＜5％(n＝10)，与标准值相吻合。  相似文献   

乙醇增强—电感耦合等离子体质谱法直接测定地质样品中碲   总被引：9，自引：3，他引：9       下载免费PDF全文

韩丽荣李冰  马新荣 《岩矿测试》2003,22(2):98-102

建立了HF—HN03密封酸溶以及Na2O2熔融处理样品，乙醇增强灵敏度，电感耦合等离子体质谱直接测定地质样品中微量和超痕量碲的方法。样品溶液中加入乙醇(φ＝4％)，在0．85L/min的载气流速下，碲信号可增强2．5倍以上。碲的方法检出限(100，DF＝1000)为0．02μg/g。用土壤和水系沉积物国家一级标准物质验证了方法的准确度，标准物质的绝大多数分析结果与标准值的误差在允许范围内。分析了大洋多金属结核样品及深海沉积物样品中的微量碲，结果与其他方法相符，精密度试验RSD(n＝3)＜10％。  相似文献   

单道扫描电感耦合等离子体发射光谱法测定珊瑚礁中主量和微量元素   总被引：1，自引：0，他引：1       下载免费PDF全文

林学辉  刘昌岭 《岩矿测试》2003,22(3):225-227

建立了用单道扫描电感耦合等离子体发射光谱法测定珊瑚礁中主量和微量元素的方法。珊瑚礁样品经酸溶解后,直接进行Ca、Mg、K、Na、V、Sr、Ba、Co、Ni、Pb、Li、Rb的测定,方法检出限为0.0004～0.1mg/L,精密度RSD<5%(n=6),样品的加标回收率为97%～105%。测定w(CaO)为50%的样品,结果与传统的EDTA容量法相符。方法经碳酸盐岩石国家一级标准物质验证可行,已用于大批量的珊瑚礁样品的测定。  相似文献   

原子荧光光谱法测定芦荟中砷和硒   总被引：5，自引：1，他引：5       下载免费PDF全文

林章金 《岩矿测试》2003,22(3):237-238

应用AFS 820型双道原子荧光仪测定芦荟中砷和硒,方法检出限分别为As0.51μg/L;Se0.42μg/L。经国家一级植物标准物质分析验证,结果与标准值相符。5次测定相对标准偏差As<2.3%;Se<3.1%。  相似文献   

高温密闭溶样电感耦合等离子体质谱准确测定辉钼矿铼-锇地质年龄   总被引：176，自引：28，他引：176  

屈文俊  杜安道 《岩矿测试》2003,22(4):254-257262

采用Carius管高温密闭溶样,电感耦合等离子体质谱(ICP MS)法对采自两个不同金属矿床的辉钼矿样品的Re Os同位素地质年龄进行了准确测定。所得出的Re Os年龄的平均值分别为14.26±0.19Ma和34.39±0.81Ma,相对标准偏差分别为1.3%(以2s计算,n=6)和2.4%(以2s计算,n=7)。采用国际通用的ISOPLOT软件按Model1模式对这两组样品分别进行处理,所得Re Os等时线年龄分别为14.32±0.46Ma和34.52±0.38Ma(均为95%置信水平)。同批次样品中所带的内部管理样JDC的Re Os年龄与国际先进实验室采用负离子热表面电离质谱测量所得的结果吻合也较好。说明在严格的质量体系保证及有效地降低实验室空白水平的前提下,ICP MS完全可以准确地测定辉钼矿的Re Os年龄。  相似文献   

原子荧光光谱法测定化探样品时有机质对As,Sb,Bi的干扰   总被引：1，自引：0，他引：1  

汪明启  刘应汉 《地质科技情报》2003,22(1):105-109

通过研究黑龙江省森林沼泽景观区有机水系沉积物（泥炭）、土壤中As,Sb,Bi的测定结果，发现样品中的有机质对王水消解氢化物原子荧光法测定上述元素存在极大的干扰，提出采用低温（＜450℃）灰化处理可完全消除干扰。对比研究还发现，过去森林沼泽景观区的区域化探扫面资料中的As,Sb,Bi数据存在问题，应专门对其进行评价研究。  相似文献   

Fluid mixing as the mechanism of formation of the Dajing Cu-Sn-Ag-Pb-Zn ore deposit,Inner Mongolia ——Fluid inclusion and stable isotope evidence   总被引：2，自引：0，他引：2  

刘伟  李新俊  谭骏 《中国科学D辑(英文版)》2003,46(7)

Since the 1990s, interest in the magmatic fluids and their relation to mineralization has been re-aroused[1—6]. Studies on stable isotopes of low-sulfidation deposits commonly show the predominance of meteoric water[7]. Paradoxically, the evidence for me…  相似文献   

Optimum multiple tuned mass dampers for structures under the ground acceleration based on the uniform distribution of system parameters     

Chunxiang Li  Yanxia Liu 《地震工程与结构动力学》2003,32(5):671-690

The five MTMD models, with natural frequencies being uniformly distributed around their mean frequency, have been recently presented by the first author. They are shown to have the near‐zero optimum average damping ratio (more precisely, for a given mass ratio there is an upper limit on the total number, beyond which the near‐zero optimum average damping ratio occurs). In this paper, the eight new MTMD models (i.e. the UM‐MTMD1～UM‐MTMD3, US‐MTMD1～US‐MTMD3, UD‐MTMD1 and UD‐MTMD2), with the system parameters (mass, stiffness and damping coefficient) being, respectively, uniformly distributed around their average values, have been, for the first time here, proposed to seek for the MTMD models without the near‐zero optimum average damping ratio. The structure is represented by the mode‐generalized system corresponding to the specific vibration mode that needs to be controlled. Through minimization of the minimum values of the maximum dynamic magnification factors (DMF) of the structure with the eight MTMD models (i.e. through the implementation of Min.Min.Max.DMF), the optimum parameters and values of Min.Min.Max.DMF for these eight MTMD models are investigated to evaluate and compare their control performance. The optimum parameters include the optimum mass spacing, stiffness spacing, damping coefficient spacing, frequency spacing, average damping ratio and tuning frequency ratio. The six MTMD models without the near‐zero optimum average damping ratio (i.e. the UM‐MTMD1～UM‐MTMD3, US‐MTMD1, US‐MTMD2 and UD‐MTMD2) are found through extensive numerical analyses. Likewise, the optimum UM‐MTMD3 offers the higher effectiveness and robustness and requires the smaller damping with respect to the rest of the MTMD models in reducing the responses of structures subjected to earthquakes. Additionally, it is interesting to note, by comparing the optimum UM‐MTMD3 with the optimum MTMD‐1 recently investigated by the first author, that the effectiveness and robustness for the optimum UM‐MTMD3 is almost identical to that for the optimum MTMD‐1 (without inclusion of the optimum MTMD‐1 with the near‐zero optimum average damping ratio). Recognizing these performance benefits, it is preferable to employ the optimum UM‐MTMD3 or the optimum MTMD‐1 without the near‐zero optimum average damping ratio, when installing the MTMD for the suppression of undesirable oscillations of structures under earthquakes. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Evaluating foundation mass,damping and stiffness by the least‐squares method     

S. H. Ju 《地震工程与结构动力学》2003,32(9):1431-1442

This paper discusses how to use the three‐dimensional (3D) time‐domain finite‐element method incorporating the least‐squares method to calculate the equivalent foundation mass, damping and stiffness matrices. Numerical simulations indicate that the accuracy of these equivalent matrices is acceptable when the applied harmonic force of 1+sine is used. Moreover, the accuracy of the least‐squares method using the 1+sine force is not sensitive to the first time step for inclusion of data. Since the finite‐element method can model problems flexibly, the equivalent mass, damping and stiffness matrices of very complicated soil profiles and foundations can be established without difficulty using this least‐squares method. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献