发射光谱载体蒸馏法测定地质样品中微量硼铍锡银   总被引：2，自引：2，他引：2  

李滦宁  赵淑杰  王烨 《岩矿测试》2004,23(1):30-32

选择了适合的缓冲剂,利用载体蒸馏法将被测元素与基体元素分离,使Be转变为易挥发的氟化物与B、Sn、Ag同时蒸发;降低了谱线背景及元素检出限;加入内标元素Au、Bi,提高了方法的准确度和精密度;采用普通 3mm×3mm×0.7mm杯型电极,装样量少,操作简单。方法检出限(wB/10-6)分别可达B1.5、Be0.3、Sn0.8、Ag0.02;准确度(Δlog C)基本在-0.05～0.05,精密度(RSD,n=8)为2.9%～17%。  相似文献   

高倍稀释熔融制样X射线荧光光谱测定钨砂和铬铁矿中主含量   总被引：4，自引：5，他引：4  

吴秀兰  朱明达  张志峰  王伊琴 《岩矿测试》2004,23(1):73-74

用X射线荧光光谱测定钨砂中WO3和铬铁矿中Cr2O3,通过高倍稀释熔融玻璃片制样法,采用高纯WO3或Cr2O3作单一标准样测量X射线荧光强度计数,然后同未知样品测量所得X射线荧光强度计数相比,即可计算出WO3和Cr2O3的测量值.方法用于钨砂矿和铬铁矿中WO3和Cr2O3的测定,结果与标准值相符.  相似文献   

水流冲击管道内滞留气团的刚性数学模型   总被引：3，自引：0，他引：3       下载免费PDF全文

刘德有  索丽生 《水科学进展》2004,15(6):717-722

通过数学分析证明,在不计局部水头损失时,目前常用的几种简化刚性数学模型的最大气压计算结果相等,并与管道内初始充水段长度无关。但算例表明,对于初始充水段较短或滞留气团体积很小情况,这些简化模型的计算误差将达到不容忽视的程度,甚至导出错误结论。笔者导出的完整刚性数学模型,弥补了简化模型的不足,同时指出了刚性模型的理论缺陷和适用条件。  相似文献   

澜沧江某水电站左岸地下式厂房岩体质量分级     

喻望  卢书强 《矿产与地质》2004,18(3):282-286

通过大量的现场调查数据与统计工作结果，采用了多种岩体质量分级评价方案，对澜沧江某水电站左岸地下式厂房岩体质量进行了精细的评价，最后将各种结果进行对比分析，得到一个合理、科学的综合岩体质量综合评价分级。并根据评价结果，作出了研究区坝址左岸地下式厂房岩体在不同高程的岩体质量分区图，为下一步的参数选取工作奠定了必要的基础。  相似文献   

大兴安岭地区浅覆盖层对地面伽马能谱测量的影响   总被引：1，自引：2，他引：1  

刘菁华  王祝文  郝立波  田钢 《物探与化探》2004,28(2):111-113

讨论在大兴安岭地区进行地质填图中浅覆盖层对伽马能谱测量的影响问题。通过放射性元素的取样分析、岩石—土壤的矿物分析以及实测剖面分析,得知了伽马能谱测量的影响因素,从而为应用伽马能谱测量解决地质填图中的问题提供了依据。  相似文献   

Geological controls on rock mass classification of coal from Huntly East Mine, New Zealand     

Vicki Moon  Trisha Roy 《Engineering Geology》2004,75(2):201-213

Rock Mass Rating (RMR) measurements from 65 sites within Huntly East underground coal mine are presented. All measurements are in coal, for which the dominant discontinuities are vertical cleat. Basic RMR values using two discontinuity spacings are presented: overall RMR based on the average spacing of all individual discontinuities; and cleat zone RMR based on the average spacing between zones of cleat. Cleat orientations are highly variable, but on average approximately parallel horizontal stress axes (face cleat follows maximum horizontal stress axis, butt cleat follows minimum horizontal stress axis).Contours of RMR variations throughout the mine are used to compare rock mass conditions with geological structure. It is apparent that: (1) RMR is least within downthrown fault blocks, and particularly immediately on the downthrown sides of faults, and greatest in upthrown fault blocks; and (2) RMR contours parallel horizontal stress axes within fault-bounded blocks, and bend to parallel faults at block boundaries. From similar contours for parameters contributing to RMR, the Rock Quality Designation (RQD), groundwater rating, and discontinuity condition rating create most of the observed variations in RMR. RQD is determined from the measured discontinuity frequency and hence is a measure of the degree of fracturing of the rock mass. This is interpreted as influencing the groundwater and condition parameters directly by allowing greater water ingress. Discontinuity frequency is greatest (least spacing) in the immediate vicinity of faults, and in downthrown fault blocks, generating low RMR values. Within fault blocks RQD varies little, so RMR contours align with cleat orientations.As RMR contours, faults, stress field and cleat orientation are clearly interrelated, there is unequivocally a connection between RMR and structural geology; this allows some predictive capacity in terms of ground conditions. If geological features can be accurately defined through either drilling programs or seismic surveys, then ground conditions may be predicted before panels are driven.  相似文献   

The Shape and Volume of the Skaergaard Intrusion, Greenland: Implications for Mass Balance and Bulk Composition   总被引：6，自引：0，他引：6  

NIELSEN  TROELS F. D. 《Journal of Petrology》2004,45(3):507-530

Re-examination of the Skaergaard intrusion in the context ofits regional setting, combined with new data from explorationdrilling, has resulted in a revised structural model for theintrusion. It is modelled as an irregular box, c. 11 km fromnorth to south, up to 8 km from east to west, and 3·4–4km from the lower to the upper contact. The walls of the intrusionare inferred to follow pre-existing and penecontemporaneoussteep faults, and the floor and roof seem largely controlledby bedding planes in the host sediments and lavas, similar toregional sills. The suggested shape and volume are in agreementwith published gravimetric modelling. Crystallization alongall margins of the intrusion concentrated the evolving meltin the upper, central part of the intrusion, best visualizedas an ‘onion-skin’ structure inside the box. Thetotal volume is estimated to c. 280 ± 23 km³, of which13·7% are referred to the Upper Border Series (UBS),16·4% to the Marginal Border Series (MBS) and 69·9%to the Layered Series (LS). In the LS, the Lower Zone (LZ) isestimated to constitute 66·8%, the Middle Zone (MZ) 13·5%and the Upper Zone (UZ) 19·7%. The new volume relationshipsprovide a mass balance estimate of the major and trace elementbulk composition of the intrusion. The parental magma to theSkaergaard intrusion is similar to high-Ti East Greenland tholeiiticplateau basalts with Mg number c. 0.45. The intrusion representsthe solidification of contemporary plateau basalt magma trappedand crystallized under closed-system conditions in a crustalreservoir at the developing East Greenland continental margin. KEY WORDS: bulk composition; emplacement; mass proportions; Skaergaard intrusion; structure  相似文献   

Curve-Fitting Schemes for Fragmentation Data     

D. P. Blair 《Fragblast: International Journal for Blasting and Fragmentation》2004,8(3):137-150

Fragmentation measurements in the form of sieve passing and mass fraction data were used to test the capability of three different distributions to fit the observed data over a wide range in fragment size and mass. These distributions were based on Rosin-Rammler, lognormal and simple sigmoidal (S-shaped) functions, having 2 input parameters for the single-component versions and 5 input parameters for the two-component versions. Provided convergence was achieved in the non-linear curve-fitting technique, the two-component versions always provided superior fits to the observed data. However, these versions were very sensitive to variations in the values chosen for the input parameters. In this particular regard, the two-component sigmoidal function was the most robust. The present results also show that the two-component lognormal function provided the best fit to the fragmentation data in a general sense, and the two-component Rosin-Rammler function provided the worst fit. However, there was not a significant difference between any of the three methods.  相似文献   

Fuzzy set approaches to classification of rock masses   总被引：6，自引：0，他引：6  

A. Aydin   《Engineering Geology》2004,74(3-4):227-245

Rock mass classification is analogous to multi-feature pattern recognition problem. The objective is to assign a rock mass to one of the pre-defined classes using a given set of criteria. This process involves a number of subjective uncertainties stemming from: (a) qualitative (linguistic) criteria; (b) sharp class boundaries; (c) fixed rating (or weight) scales; and (d) variable input reliability. Fuzzy set theory enables a soft approach to account for these uncertainties by allowing the expert to participate in this process in several ways. Hence, this study was designed to investigate the earlier fuzzy rock mass classification attempts and to devise improved methodologies to utilize the theory more accurately and efficiently. As in the earlier studies, the Rock Mass Rating (RMR) system was adopted as a reference conventional classification system because of its simple linear aggregation.

The proposed classification approach is based on the concept of partial fuzzy sets representing the variable importance or recognition power of each criterion in the universal domain of rock mass quality. The method enables one to evaluate rock mass quality using any set of criteria, and it is easy to implement. To reduce uncertainties due to project- and lithology-dependent variations, partial membership functions were formulated considering shallow (<200 m) tunneling in granitic rock masses. This facilitated a detailed expression of the variations in the classification power of each criterion along the corresponding universal domains. The binary relationship tables generated using these functions were processed not to derive a single class but rather to plot criterion contribution trends (stacked area graphs) and belief surface contours, which proved to be very satisfactory in difficult decision situations. Four input scenarios were selected to demonstrate the efficiency of the proposed approach in different situations and with reference to the earlier approaches.  相似文献   

Lu–Hf and U–Pb isotope systematics of zircons from the Storgangen intrusion, Rogaland Intrusive Complex, SW Norway: implications for the composition and evolution of Precambrian lower crust in the Baltic Shield     

Tom Andersen  William L Griffin   《Lithos》2004,73(3-4):271-288

The Storgangen orebody is a concordantly layered, sill-like body of ilmenite-rich norite, intruding anorthosites of the Rogaland Intrusive Complex (RIC), SW Norway. 17 zircon grains were separated from ca. 5 kg of sand-size flotation waste collected from the on-site repository from ilmenite mining. These zircons were analysed for major and trace elements by electron microprobe, and for U–Pb and Lu–Hf isotopes by laser ablation microprobe plasma source mass spectrometry. Eight of the zircons define a well-constrained (MSWD=0.37) concordant population with an age of 949±7 Ma, which is significantly older than the 920–930 Ma ages previously reported for zircon inclusions in orthopyroxene megacrysts from the RIC. The remaining zircons, interpreted as inherited grains, show a range of ²⁰⁷Pb/²⁰⁶Pb ages up to 1407±14 Ma, with an upper intercept age at ca. 1520 Ma. The concordant zircons have similar trace element patterns, and a mean initial Hf isotope composition of ¹⁷⁶Hf/¹⁷⁷Hf_{949 Ma}=0.28223±5 (_Hf=+2±2). This is similar to the Hf-isotope composition of zircons in a range of post-tectonic Sveconorwegian granites from South Norway, and slightly more radiogenic than expected for mid-Proterozoic juvenile crust. The older, inherited zircons show Lu–Hf crustal residence ages in the range 1.85–2.04 Ga. One (undated) zircon plots well within the field of Hf isotope evolution of Paleoproterozoic rocks of the Baltic Shield. These findings indicate the presence of Paleoproterozoic components in the deep crust of the Rogaland area, but do not demonstrate that such rocks, or a Sveconorwegian mantle-derived component, contributed significantly to the petrogenesis of the RIC. If the parent magma was derived from a homogeneous, lower crustal mafic granulite source, the lower crustal protolith must be at least 1.5 Ga old, and it must have an elevated Rb/Sr ratio. This component would be indistinguishable in Sr, Nd and Hf isotopes from some intermediate mixtures between Sveconorwegian mantle and Paleoprotoerzoic felsic crust, but it cannot account for the initial ¹⁴³Nd/¹⁴⁴Nd of the most primitive, late Sveconorwegian granite in the region, without the addition of mantle-derived material.  相似文献