Lake bank filtration at Nainital,India: water-quality evaluation   总被引：6，自引：2，他引：4  

R. R. Dash  I. Mehrotra  P. Kumar  T. Grischek 《Hydrogeology Journal》2008,16(6):1089-1099

There are different water-supply schemes in Uttarakhand, India to tap the water from streams, rivers and lakes. At Nainital, seven tube-wells (depths 22.6–36.7 m), located at a distance of <100 m from the lake, are being used to abstract (1) lake water after passage through the soil and (2) subsurface water/groundwater flowing towards the lake. Water samples from the lake and tube-wells were analyzed in monsoon and non-monsoon periods from 1997 to 2006. Total dissolved solids, EC, alkalinity and hardness were found to be marginally greater in tube-well waters. The difference in hydrochemistry of tube-well water was mainly due to variation in flow regimes during monsoon and non-monsoon periods. Results clearly indicate that lake water as such is not potable as it contains unacceptable levels of organic matter in terms of COD (~44 mg/L), coliforms (~15.6 × 10⁴ MPN/100 mL) and nutrients. Coliform bacteria and COD have not been detected in any of the tube-well water samples over the years. Lake water, treated by sand filters did not conform to drinking water standards. These investigations have led to the closure of the treatment facility and installation of two tube-wells in addition to the existing five tube-wells.

---

Résumé  Il existe divers projets d’alimentation en eau dans l’état d’Uttarakhand, Inde, afin de capter l’eau de ruisseaux, de rivières et de lacs. A Nainital, sept puits tubés (profondeur de 22.6–36.7 m), situés à une distance < à 100 m du lac, sont utilisés pour prélever (1) de l’eau du lac après transit à travers le sol et (2) de l’eau de sub-surface/eau souterraine s’écoulant vers le lac. Des échantillons d’eau du lac et des puits tubés ont été analysés en périodes de mousson et de celles sans mousson 1997 à 2006. Résidu sec, C.E., alcalinité et dureté ont été trouvés marginalement supérieurs dans l’eau des puits tubés. La différence d’hydrochimie de l’eau des puits tubés était surtout due à la variation des régimes d’écoulement pendant les périodes de mousson et de celles sans mousson. Les résultats indiquent clairement que l’eau du lac en tant que telle n’est pas potable car elle contient des teneurs inacceptables de matière organique en termes de COD (~44 mg/L), de coliformes (~15.6 × 10⁴ MPN/100 mL) et d’éléments nutritifs. Des bactéries coliformes et du COD n’ont été détectés dans aucun des échantillons d’eau de puits tubés au fil des années. L’eau du lac traitée par des filtres à sable ne se conformait pas aux normes de l’eau potable. Ces recherches ont conduit à la fermeture de l’installation de traitement et à l’implantation de deux puits tubés en plus des cinq puits existants.

---

Resumen  En el estado de Uttarakhand, India, existen diferentes esquemas de abastecimiento de agua que explotan agua de arroyos, ríos y lagos. En Nainital, siete pozos (profundidades entre 22.6–36.7 m), ubicados a una distancia de <100 m del lago, se usan para extraer (1) agua del lago luego de su pasaje a través del suelo y (2) agua superficial y subterránea que fluye hacia el lago. En períodos de monzón y de no monzón de 1997 a 2006 se han analizado muestras de agua del lago y de las captaciones. Se halló que el agua de los pozos es ligeramente mayor en términos del total de sólidos disueltos, la conductividad eléctrica, la alcalinidad y la dureza. La diferencia en la hidroquímica del agua de las perforaciones se debe principalmente a la variación de los regímenes de flujo durante los períodos de monzón y de no monzón. Los resultados claramente indican que el agua del lago no es potable por su contenido inaceptable de materia orgánica medida como demanda de carbono orgánico/oxígeno –DCO- (~44 mg/L), coliformes (~15.6 × 10⁴ NMP/100 mL) y nutrientes. En el período, no se han detectado bacterias coliformes ni DCO en las muestras de agua de las captaciones. El agua del lago, tratada con filtros de arena, no conformó los estándares de agua para bebida. Estas investigaciones han demostrado la necesidad de clausurar las instalaciones de tratamiento y la adición de dos captaciones a las cinco ya existentes.

  相似文献   

塔里木盆地塔中低凸起地层水化学特征对不整合的响应          下载免费PDF全文

曾溅辉  吴琼  钱诗友  孔旭  马中良 《古地理学报》2008,10(5)

对塔中低凸起地层水化学特征与不整合之间关系的研究结果表明,地层水化学特征对不整合具有很好的响应。在遭受强烈抬升和剥蚀、之间形成不整合的奥陶系和志留系,以及紧靠不整合面附近的石炭系CⅢ油组,其地层水具有矿化度、Cl-含量、K Na 含量和r(Cl-Na)/rMg值相对较小,而HCO3-含量、rNa/rCl值和rSO42-×100/rCl值相对较大的特点,反映出地质历史时期大气降水的影响。在志留系与石炭系之间以及志留系与奥陶系之间的不整合面附近,地层水的矿化度、r(Cl-Na)/rMg值和B3 含量变小,而rNa/rCl值和rSO24-×100/rCl值变大,具有典型的遭受大气淋滤的地层水化学基本特征。  相似文献   

Micromechanical approach to unsaturated water flow in structured geomaterials by two-scale computations     

Adam Szymkiewicz  Jolanta Lewandowska 《Acta Geotechnica》2008,3(1):37-47

This article presents a micromechanical approach to the problem of unsaturated water flow in heterogeneous porous media in transient conditions. The numerical formulation is based on the two-scale model obtained previously by periodic homogenization. It allows for a coupled solution of the non-linear flow equations at macroscopic and microscopic scales and takes into account the macroscopic anisotropy of the medium and the local non-equilibrium of the capillary pressure. The model was applied to simulate two-dimensional water infiltration at constant flux into an initially dry medium containing inclusions of square and rectangular shapes. The numerical results showed the influence of the inclusion–matrix conductivity ratio and the local geometry on the macroscopic behavior. The influence of the conductivity ratio manifested itself by the acceleration or retardation of the onset of the macroscopic water flux at the outlet, while the local geometry (anisotropy) significantly affected the macroscopic spatial distribution of the water flux. Such type of approach can be extended to simulate coupled phenomena (for example hydro-mechanical problems) with evolving local geometry.  相似文献   

Environmental geochemistry of the River Gomti: A tributary of the Ganges River     

L. P. Gupta  V. Subramanian 《Environmental Geology》1994,24(4):235-243

Water and sediment samples collected from the Gomti River, a tributary of the Ganges River system, during the postmonsoon season have been analyzed to estimate major elemental chemistry. Water chemistry of the River Gomti shows almost monotonous spatial distribution of various chemical species, especially because of uniform presence of alluvium Dun gravels throughout the basin. The river annually transports 0.34×10⁶ tonnes of total suspended material (TSM) and 3.0×10⁶ tonnes of total dissolved solids (TDS), 69 percent of which is accounted for by bicarbonate ions only. Samples collected downstream of the city of Lucknow show the influence of anthropogenic loadings for a considerable distance in the river water. Na⁺, Cl^–, and SO₄ ^2– concentrations build up downstream. The bed sediment chemistry is dominated by Si (36 percent), reflecting a high percentage of detrital quartz, which makes up about 74 percent of the mineralogy of the bed sediments in the River Gomti. The average Kjeldahl nitrogen concentration (234 g/g) indicates indirectly the amount of organic matter in the sediments. The Hg concentration in sediments has been found to be higher (average 904 ppb) than the background value. The suspended sediments are well sorted, very finely skewed, and extremely leptokurtic, indicating a low energy condition of flow in the Gomti River. The influence of chemical loads in the Gomti has been found to be small or nonexistent on the Ganges River, perhaps because the water discharge of the Gomti (1.57 percent) to the Ganges is quite low.  相似文献   

Rate constants for the reactions of the NO3 radical with HCOOH/HCOO− and CH3COOH/CH3COO− in aqueous solution between 278 and 328 K     

M. Exner  H. Herrmann  R. Zellner 《Journal of Atmospheric Chemistry》1994,18(4):359-378

The kinetics of the aqueous phase reactions of NO₃ radicals with HCOOH/HCOO^– and CH₃COOH/CH₃COO^– have been investigated using a laser photolysis/long-path laser absorption technique. NO₃ was produced via excimer laser photolysis of peroxodisulfate anions (S₂O ₈ ^2– ) at 351 nm followed by the reactions of sulfate radicals (SO ₄ ^– ) with excess nitrate. The time-resolved detection of NO₃ was achieved by long-path laser absorption at 632.8 nm. For the reactions of NO₃ with formic acid (1) and formate (2) rate coefficients ofk ₁=(3.3±1.0)×10⁵ l mol^–1 s^–1 andk ₂=(5.0±0.4)×10⁷ l mol^–1 s^–1 were found atT=298 K andI=0.19 mol/l. The following Arrhenius expressions were derived:k ₁(T)=(3.4±0.3)×10¹⁰ exp[–(3400±600)/T] l mol^–1 s^–1 andk ₂(T)=(8.2±0.8)×10¹⁰ exp[–(2200±700)/T] l mol^–1 s^–1. The rate coefficients for the reactions of NO₃ with acetic acid (3) and acetate (4) atT=298 K andI=0.19 mol/l were determined as:k ₃=(1.3±0.3)×10⁴ l mol^–1 s^–1 andk ₄=(2.3±0.4)×10⁶ l mol^–1 s^–1. The temperature dependences for these reactions are described by:k ₃(T)=(4.9±0.5)×10⁹ exp[–(3800±700)/T] l mol^–1 s^–1 andk ₄(T)=(1.0±0.2)×10¹² exp[–(3800±1200)/T] l mol^–1 s^–1. The differences in reactivity of the anions HCOO^– and CH₃COO^– compared to their corresponding acids HCOOH and CH₃COOH are explained by the higher reactivity of NO₃ in charge transfer processes compared to H atom abstraction. From a comparison of NO₃ reactions with various droplets constituents it is concluded that the reaction of NO₃ with HCOO^– may present a dominant loss reaction of NO₃ in atmospheric droplets.  相似文献   

Brønsted reactions on oxide mineral surfaces and the temperature-dependence of their dissolution rates     

William H. Casey  Marcus A. Cheney 《Aquatic Sciences - Research Across Boundaries》1993,55(4):304-313

The pH-dependence of oxide dissolution rates is controlled by Brønsted acid-base reactions at the mineral surface. These reactions are rapid but depend explicitly on temperature, as do the subsequent slow rates of bond hydrolysis. The net result is that dissolution rates vary in a complicated fashion with temperature and solution pH. The enthalpy changes of acid-base reactions on oxide materials are sufficiently similar, however, that general statements can be made about their contribution. The enthalpy changes from proton adsorption to a hydroxyl functional group (SOH), or to a deprotonated functional group (SO ^–), are generally exothermic. The enthalpy changes become increasingly endothermic, however, as charge accumulates on the mineral surface and the charged species interact electrostatically. The result is that mineral dissolution rates are least sensitive to temperature, as measured with an Arrhenius-like rate law, at pH conditions near the Point of Zero Net Proton Charge.  相似文献   

Palaeoclimatic studies in South Shetland Islands,Antarctica, based on numerous stratigraphic variables in lake sediments     

Svante Björck  Hannelore Håkansson  Siv Olsson  Lena Barnekow  Jan Janssens 《Journal of Paleolimnology》1993,8(3):233-272

The hitherto longest found lake sediment sequence on Byers Peninsula, Livingston Island, South Shetland Islands, was analysed with respect to lithology, chronology, diatoms, Pediastrum, pollen and spores, mosses, mineralogy, and sediment chemistry. During the ca. 5000 year long development the sediments were influenced by frequent tephra fall-outs. This volcanic impact played a major role in the lake's history during two periods, 4700–4600 and 2800–2500 BP, but was of importance during the lake's entire history with considerable influence on many of the palaeoenvironmentally significant indicators. The large and complex data set was analysed and zonated with different types of multivariate analysis. This resulted in a subdivision of the sequence into 8 time periods and 21 variables. Redundancy analysis (RDA) of this data set, both without and with the tephra periods, and with 4–6 of the variables as explanatory environmental variables, reveal that climatic/environmental signals are detectable. The palaeoclimatic picture that emerged out of the tephra noise suggests that the first 100 years were characterized by mild, humid conditions. This was followed by a less mild and humid climate until ca. 4000 BP when a gradual warming seems to have started, coupled with increased humidity. These mild and humid conditions seem to have reached an optimum slightly after 3000 BP. At ca. 2500 BP a distinct climatic deterioration occurred with colder and drier conditions and long seasons with ice cover. This arid, cold phase probably reached its optimum conditions at ca. 1500 BP, when slightly warmer conditions might have prevailed for a while. Except for the modern sample with rather mild climate, the last 1400 years seem to have been fairly arid and cold, and the effects of the frequent volcanic activity during this period is only vaguely seen in the records.  相似文献   

Numerical study of droplet size dependent chemistry in oceanic,wintertime stratus cloud at southern mid-latitudes     

G. P. Ayers  T. V. Larson 《Journal of Atmospheric Chemistry》1990,11(1-2):143-167

Cloud droplet chemistry is modelled for the first 150 m of rise in a wintertime, mid-latitude, marine stratus cloud using observations made at and near the Cape Grim Baseline Station as a source of input parameters. The emphasis in this work was to study the variation in droplet chemistry as a function of both droplet size and nucleus composition, with a particular focus on the way in which oxidation of dissolved sulfur dioxide varied.At 150 m above the condensation level, solute concentration as a function of droplet size was found to increase by as much as 2 to 3 orders of magnitude for only a factor of 2 increase in droplet radius, primarily as a consequence of the 1/r dependence in the droplet growth equation. This type of size dependence exists at all levels in the model cloud, and has a significant influence on oxidation rate of sulfur dioxide in droplets growing on sulfate nuclei, oxidation by ozone being favoured in the smallest droplets, but oxidation by hydrogen peroxide being favoured in the larger droplets. Oxidation by ozone is favoured at all sizes in droplets formed on sea-salt nuclei as a result of the initially high alkalinity of these droplets, and in the cloud overall is calculated to be the more important oxidation pathway. Although based on a simplified chemical scheme, these results suggest that both size-dependent and nucleus-dependent chemistry of cloud droplets may need to be considered explicitly in cloud modelling work.Volume-weighted mean pH values in the range 5 to 6 were predicted from sensitivity studies in which input variables were varied over reasonable ranges, in agreement with two sets of bulk cloud-water pH data obtained by aircraft near Cape Grim.  相似文献   

Seasonal variation of atmospheric dimethylsulfide at Amsterdam Island in the southern Indian Ocean     

B. C. Nguyen  N. Mihalopoulos  S. Belviso 《Journal of Atmospheric Chemistry》1990,11(1-2):123-141

Daily measurements of atmospheric concentrations of dimethylsulfide (DMS) were carried out for two years in a marine site at remote area: the Amsterdam Island (37°50S–77°31E) located in the southern Indian Ocean. DMS concentrations were also measured in seawater. A seasonal variation is observed for both DMS in the atmosphere and in the sea-surface. The monthly averages of DMS concentrations in the surface coastal seawater and in the atmosphere ranged, respectively, from 0.3 to 2.0 nmol l^-1 and from 1.4 to 11.3 nmol m^-3 (34 to 274 pptv), with the highest values in summer. The monthly variation of sea-to-air flux of DMS from the southern Indian Ocean ranges from 0.7 to 4.4 mol m^-2 d^-1. A factor of 2.3 is observed between summer and winter with mean DMS fluxes of 3.0 and 1.3 mol m^-2 d^-1, respectively.  相似文献   

衡水湖湿地水环境分析及保护对策   总被引：3，自引：0，他引：3  

刘振杰 《湿地科学与管理》2006,2(2):41-44

衡水湖是华北平原惟一保存完整的内陆淡水湿地生态系统,生物多样性十分丰富,本文通过对衡水湖湿地水环境监测资料的收集整理,分析了衡水湖湿地水环境质量现状。结果表明:衡水湖在建立国家级自然保护区后,通过实施一系列严格的保护措施,目前水质仍保持较好。为了进一步保护衡水湖良好的生态环境,充分发挥衡水湖的生态功能,结合衡水湖的实际,提出了水环境保护建议。  相似文献