不同浓度Li2SO4水溶液结构的X射线衍射研究          下载免费PDF全文

房艳  房春晖  高世扬 《盐湖研究》2003,11(2)

用θ～ 2θ型粉末衍射仪反射法精确测量了不同浓度的Li2 SO4水溶液的衍射数据 ,通过数据处理给出了溶液的结构函数和径向分布函数 ,由几何结构模型的最小二乘法精修 ,得到了溶液中阳离子和阴离子第一、二水合层的结构参数。  相似文献   

TiO2柱撑蒙脱石的X射线衍射和扫描电镜研究   总被引：5，自引：0，他引：5  

李湘祁  汤德平  翁国坚 《福建地质》2003,22(1):33-36

通过TiCL4在HCL溶液中的水解制备了TiO2柱撑蒙脱石，用X射线粉末衍射（XRD）、扫描电镜（SEM）及N2吸附－脱附实验对所得材料进行表征。结果表明，煅烧能有效地改善柱撑蒙脱石层间TiO2柱体的结晶程度，但同时也会引起TiO2晶粒长大、比表面积下降以及硅酸盐片层之间平行有序分布的程度降低。  相似文献   

光催化氧化法处理难降解废水的研究进展   总被引：8，自引：3，他引：8  

梁喜珍  黄国林  陈中胜  覃业贤  郑建英 《华东地质学院学报》2003,26(2):179-182

综述了光催化氧化处理难降解废水的研究现状及发展趋势。介绍了影响光催化氧化反应速率的因素及光催化氧化法在处理难降解废水中的应用。  相似文献   

陕北新庄地区延长组长2油层组储层特征   总被引：10，自引：2，他引：10  

孙冬胜  李文山  罗纪红  赵靖舟 《西北地质》2003,36(1):59-61

一般河道砂体的正粒序性决定了其下部物性条件优于上部，但新庄地区长2油层组河道砂体的物性特征截然相反，而是中上部物性条件好，下部物性条件普遍差。在储层岩石学特征、孔隙类型等研究的基础上，对此进行了探讨，认为造成其特殊性的原因主要是由于压实、胶结、次生加大等作用。指出河道边滩砂体中上部储层为该区的主力储层。  相似文献   

利用高铁钾长石粉合成13X沸石分子筛的实验研究   总被引：6，自引：3，他引：6       下载免费PDF全文

章西焕  马鸿文杨静 肖万 《岩石矿物学杂志》2003,22(2):167-172

对江苏丰县的富钾页岩进行预处理，得到钾长石含量达76．4％的钾长石粉，其Fe2O3含量高达7．52％。以此钾长石粉为原料经过焙烧处理、水热合成实验，在铁含量较高情况下成功合成了13X沸石分子筛，并采用正交实验法确定了优化工艺参数。对实验产物的主要性能测试表明，合成的富铁沸石产品与13X沸石分子筛工业产品相似，吸附量达到国家化学工业产品标准，可用于对含重金属离子废水的吸附处理。  相似文献   

A comparison of the evolution of diamondiferous quartz-rich rocks from the Saxonian Erzgebirge and the Kokchetav Massif: are so-called diamondiferous gneisses magmatic rocks?     

Hans-Joachim Massonne 《Earth and Planetary Science Letters》2003,216(3):347-364

The petrography and chemical composition of minerals of quartz-rich diamondiferous rocks from the Kokchetav Massif, especially the zonation of garnet, were studied and compared with diamondiferous quartzofeldspathic rocks from the Saxonian Erzgebirge. Many compositional and textural features were found to be similar. For instance, microdiamonds are enclosed systematically in a specific intermediate growth zone of garnet in these rocks. On the basis of experimental data, a magmatic scenario was constructed to check if the quartz-rich diamondiferous rocks are of magmatic origin. By this, the P-T paths, derived here for the Kokchetav rocks, and the textural observations it is concluded that the minerals of the diamondiferous rocks have crystallized from silicate melts. These melts originated by anatexis of deeply submerged metasediments (Erzgebirge: at T as high as 1200°C, Kokchetav Massif: at 50-100°C lower T) and ascended from at least 200 km depth. Relics of the pre-anatectic evolution are still present, for instance, as garnet cores. After ascent and emplacement of the magma in deep portions of thickened continental crust (Kokchetav Massif: 45-50 km close to 800°C, Erzgebirge: 55-60 km at 30-50°C lower T) considerable quantities of (white and/or dark) micas formed by peritectic reactions from melt. For instance, garnets could be resorbed at this stage and biotite grew instead. After the magmatic stage, retrogression took place much stronger in the Kokchetav Massif. This was accompanied by deformation transforming broadly the magmatic texture of quartz-rich diamondiferous rocks from the Kokchetav Massif to a gneissic texture.  相似文献   

深圳市东湖矿泉水形成机理探讨   总被引：5，自引：0，他引：5  

苏春利  李义连  王焰新 《地质科技情报》2003,22(4):85-90

深圳市东湖矿泉水是自然界十分稀少的锶—锌—偏硅酸碳酸复合型矿泉水，通过对矿泉水赋存地的地质与水文地质条件的分析，并结合其水文地球化学特征，认为东湖矿泉水形成的主要控制性因素是构造作用和变质作用；在特定的水文地质条件下，深部碳酸盐类岩石受热硅化变质而产生大量CO2气体，使得各种化学元素在含有大量CO2的地下水的溶滤作用下不断迁移和富集而形成该区地下水中良好的元素组合。在其特征成分中，偏硅酸来自裂隙渗透水的溶滤和岩浆期后热液水的作用，微量元素锶主要来源于钾长石、钙长石，锌则主要来自岩浆活动以及岩脉中的黑云母、角闪石、辉石等铁镁硅酸盐矿物；并认为目前矿泉水含水层仍处于良好的地质环境保护下。  相似文献   

柴达木盆地三湖地区第四系生物气的形成途径与运聚方式   总被引：22，自引：1，他引：22  

张晓宝  徐自远  段毅  马立元  孟自芳  周世新  贺鹏 《地质论评》2003,49(2):168-174

柴达木盆地三湖(台吉乃尔湖、涩聂湖、达布逊湖)地区第四系生物气区是我国最大的生物气区。笔者系统采集了该气区21个天然气样品,测量了其组分和碳同位素组成,重点探讨了生物气形成途径和运聚方式。生物气δ~(13)C_1和δ~(13)C_(CO_2)均随深度增大而变重,显示了CO_2还原途径成气的特征。生物气δ~(13)C_1、δ~(13)C_(CO_2)和δD分布与CO_2还原方式形成的生物气的相应同位素值分布范围接近。在有关成因图解中这些数据主要位于CO_2还原途径成气范围内。生物气CO_2和CH_4之间的碳同位素分馏系数α_c>1.055,具有CO_2还原途径成气的特征。柴达木盆地第四纪干旱的古气候、较低的古温度、较高的沉积速率和水体中较高的硫酸盐含量使得甲烷菌的大量繁殖只能在较大的深度范围内才能实现,从而,有利于CO_2还原途径成气作用进行。涩北一号、涩北二号气田生物气δ~(13)C_1组成分布可能表明,生物气形成以后沿疏导层水平运移进入气藏,基本不存在垂向运移。该项研究对于进一步深入探讨生物气成因、形成条件,确定生物气模拟实验方式与条件,计算生物气资源量,建立成藏模式和选择天然气有利勘探区块均具有重要价值。  相似文献   

Geochemical Characteristics of Granitoids of the Erdenet Porphyry Copper Deposit, Mongolia   总被引：4，自引：0，他引：4  

Haruhisa Morozumi 《Resource Geology》2003,53(4):311-316

Abstract. The Erdenet porphyry copper deposit is one of the major mineral deposits in Mongolia. The geochemical data of granitoids acquired for the Erdenet and its surrounding areas are re-examined. The granitoids of the Erdenet deposit with hypogene type mineralization show the lowest TiO₂ content. Although Ti was possibly lost through the pyritization, it is also possible that the hypogene type mineralization occurred accompanied with the most differentiated granitoids. The variation of the element contents related to the mineralization of the Erdenet deposit shows the decrease of MgO and CaO contents, rather constant K₂O content, rather constant to decrease of Na₂O content, with respect to the Cu contents. The rather constant Na₂O in the mineralized zone is owing to the residual albite against the sericitic alteration. The granitoids of the Erdenet area show an increase of Na₂O content and a decrease of K₂O content with an increase of SiO₂ content. This trend makes clear contrast to granitoids in the surrounding areas. The granitoids of the Erdenet area might have the adakitic nature based on the Sr and Y contents.  相似文献   

Rivers, chemical weathering and Earth's climate   总被引：4，自引：0，他引：4  

Bernard Dupr  Cline Dessert  Priscia Oliva  Yves Goddris  Jrme Viers  Louis Franois  Romain Millot  Jrme Gaillardet 《Comptes Rendus Geoscience》2003,335(16):1141-1160

We detail the results of recent studies describing and quantifying the large-scale chemical weathering of the main types of continental silicate rocks: granites and basalts. These studies aim at establishing chemical weathering laws for these two lithologies, describing the dependence of chemical weathering on environmental parameters, such as climate and mechanical erosion. As shown within this contribution, such mathematical laws are of primary importance for numerical models calculating the evolution of the partial pressure of atmospheric CO₂ and the Earth climate at geological timescales. The major results can be summarized as follow: (1) weathering of continental basaltic lithologies accounts for about 30% of the total consumption of atmospheric CO₂ through weathering of continental silicate rocks. This is related to their high weatherability (about eight times greater than the granite weatherability); (2) a simple weathering law has been established for basaltic lithologies, giving the consumption of atmospheric CO₂ as a function of regional continental runoff, and mean annual regional temperature; (3) no such simple weathering law can be proposed for granitic lithologies, since the effect of temperature can only be identified for regions displaying high continental runoff; (4) a general law relating mechanical erosion and chemical weathering has been validated on small and large catchments. The consequences of these major advances on the climatic evolution of the Earth are discussed. Particularly, the impacts of the onset of the Deccan trapps and the Himalayan orogeny on the global carbon cycle are reinvestigated. To cite this article: B. Dupré et al., C. R. Geoscience 335 (2003).  相似文献