Rare-earth element mobility during ore-forming hydrothermal alteration: A case study of Dongping gold deposit Hebei Province,China     

包志伟  赵振华 《中国地球化学学报》2003,22(1):45-57

REE mobility during hydrothermal ore-forming processes has been extensively investigated in recent years and the potential of REE to provide information about ore forming processes has commonly been recognized.The Dongping gold deposit,which is located in northwestern Hebei Province,China,occurring in the inner contact zone of the Shuiquangou syenite complex,is spatially,and probably genetically,related to the syenite,the deposit was formed under the moderate to high temperature(220℃ to 320℃),weakly acidic to weakly alkaline,rather high fo2(lgfo2=-30～-34)environment.The REE study of the host rocks,altered wall rocks,ores and gangue minerals from the deposit suggests that the REEs have been mobilized and differentiated during K-feldspathization and silicification.The extremely altered syenite enveloping auriferous quartz vein shows positive Ce anomaly and larger LREE/HREE ratio than that of the unaltered syenite.The REE concentrations and patterns of the ores are determined by the ore types and mineral assemblages,LREE/HREE ratios in the gangue quartz and hydrothermal Kfeldspars are relatively low.The most significant observation is that the gangue quartz shows significant positive Eu anomaly,whereas the hydrothermal K-feldspars show less significant or no positive Eu anomaly at all relative to the primary feldspar in the unaltered syenite. It is evident that the REEs are mobile during K-feldspathization and silicification in the ore forming process.Weak to moderate K-feldspathization caused REE mobility without apparent differentiation with the exception of extreme K-feldspathization and silicification which resulted in significant depletion of HREE and Eu and relative enrichment of Ce.The REE,Y,U,Th and Au contents of the syenite decrease as the degrees of K-feldspathization and silicification of the rocks increase towards the auriferous quartz veins.As the ores were deposited under a rather oxidized environment,Ce^4 predominated over Ce^3 .The precipitation of the former in the form of CeO2 or absorpted onto the secondary mineral assemblage resulted in the inconsistent removal of the REE and the relative Ce enrichment in the strongly altered rocks.in contrast,Eu was present mainly in a low valence state (Eu^2 ).The geochemical differences from the other REE^3 and much less sites in the secondary minerals to accommodate the Eu released form the original minerals resulted in the enrichment of Eu in the fluids.The mobility and differentiation of REE and the coherent mobilities of Y,U,Th and Au also support the argument that the syenite is one of the source rocks for gold mineralization.The REE contents and patterns of the altered rocks enveloping the auriferous quartz vein could be used as a guide for locating ore veins in mineral exploration.  相似文献   

龙门山前陆褶皱冲断带构造解析与川西前陆盆地的发育   总被引：57，自引：2，他引：55  

贾东  陈竹新  贾承造  魏国齐  李本亮  张惬  魏东涛  沈扬 《高校地质学报》2003,9(3):402-410

通过详细的野外地质调查和精细的地震剖面构造解析。揭示了龙门山前陆褶皱冲断带的基本构造特征。对比分析了龙门山北段与南段构造变形几何学和运动学的差异。提出龙门山北段主要表现为一系列复杂的逆冲推覆构造,晚三叠纪变形强于新生代;龙门山南段则以基底卷入的叠瓦状冲断为特点,晚白垩纪-早第三纪变形尤为突出。与前陆褶皱冲断带相对应的是,川西晚三叠纪时期的周缘前陆盆地主要表现在整个龙门山褶皱冲断带的前渊地区;而晚白垩纪-早第三纪再生前陆盆地却局限在川西盆地的南部,并且印-藏碰撞的持续挤压作用使得晚新生代构造变形不断向东扩展进入川西盆地南部。  相似文献   

2001年世界黄金供需形势     

王淑玲 《黄金地质》2003,9(2):55-60

2001年受美国经济放缓,尤其是"9·11"事件的影响,世界黄金需求下降2 6%,金价低迷,以271 04美元 盎司的年均金价再次刷新了1978年以来的最低价位。持续恶劣的价格环境,促进了黄金矿业公司间的相互兼并,以此降低经营成本,提高国际竞争能力。受金价下跌的影响,金矿勘查费用再次下降。尽管如此,2001年黄金仍是全球固体矿产勘查投资最多的矿种,是全球勘查开发热点,黄金储量和储量基础仍保持增长态势,金资源保证程度增加。金产量并未因金价下跌而减少。  相似文献   

阿尔金山中段清水泉-茫崖蛇绿构造混杂岩带地质特征   总被引：6，自引：1，他引：5  

校培喜 《西北地质》2003,36(2):20-29

清水泉—茫崖蛇绿构造混杂岩带沿阿尔金山南坡分布,呈醒目的“绿色岩带”,其主要由蛇绿岩、蛇绿岩上覆岩系和元古代外来岩片或岩块组成,现多为构造透镜体,蛇绿岩上覆岩系具远洋深海沉积特征;岩石地球化学资料研究证明,蛇绿岩中的玄武岩与洋内岛弧拉斑玄武岩相似;同位素测年结果显示蛇绿岩形成于早古生代,蛇绿岩源自亏损的软流圈地幔,同时有富集地幔物质加入,暗示早古生代研究区曾出现过小洋盆构造环境。  相似文献   

佛子冲火山岩区隐伏铜锌矿床的类型归属及成矿远景   总被引：2，自引：1，他引：1  

雷良奇  宋慈安等 《地质与勘探》2002,38(1):9-14

佛子冲铅锌成矿带包括两种矿床类型,即佛子冲式夕卡岩型矿床和牛卫式热液充填（交代）型矿床,这两类矿床矿体产状,围岩蚀变,矿物组合,以及单矿物中微量元素分布特征等方面区别明显,但硫化矿物的硫,铅同位素组成相同,并且均表现出强烈的均一化的特点,反映出两者的成矿条件及成矿方式虽然不同,但具有相同的物源－燕山期钙碱性火山岩系,在佛子冲矿带南部火山岩覆盖区,铅锌矿化组合空间展布呈“三层楼”结构,并且构造控矿作用明显：矿点主要分布于佛子冲隐伏背斜的轴部（“龙脊”）,特别是在隐伏背斜被NE向断裂切割部位,火山岩铅锌矿化大多属于佛子冲式矿床类型,即佛子冲矿带内主要的矿床类型,具有较大的找矿前景。  相似文献   

阿尔金北缘地区剥离断层控矿和金矿成因——以大平沟金矿床为例   总被引：5，自引：0，他引：5  

陈宣华  杨风  王小凤  陈柏林  陈正乐  王克卓 《吉林大学学报(地球科学版)》2002,32(2):122-127

阿尔金北缘大平沟金矿床是近年来在阿尔金山地区新发现的首例岩金矿床。为了阐明其矿床地质特征及其成因,采用构造解析与矿主档学研究相结合的方法。结果表明,（1）金矿物主要为金－银系列矿物,成色在915－946之间,金含量与K2O、Fe2O3呈正相关关系;（2）变粒岩、强片理化变粒岩、含金石英脉和无矿化纯净石英脉的稀土元素配分型式具有相似性;（3）主要成矿期温度范围198－290℃,为中温热液矿床;（4）成矿深度为1.77-2.68km;（5）氢氧同位素组成具有以岩浆水为主的特征。由此认为,大平沟金矿床是受阿尔金北缘断裂－剥离断层控制的金矿床,是该地区金矿找矿的方向。  相似文献   

海南岛抱板群岩石高温高压实验及金成矿机理探讨   总被引：2，自引：1，他引：1  

许德如 《大地构造与成矿学》2002,26(2):207-215

高温高压实验岩石学是地质学、岩石学领域中的“硬科学”犤1999,王德滋,等犦。目前高温高压实验岩石学研究主要是针对单一岩石的熔化和融离实验,而针对多物源成因的花岗岩模拟其物源贡献大小的实验岩石学及同时发生的成矿作用研究基本上是一个空白。文章根据海南岛戈枕含金剪切带中元古代花岗岩的物源特征及与之有关的戈枕式金矿成因特点,通过高温高压实验岩石学模拟,初步探讨古中元古代抱板群岩石高温高压下的熔融行为及金的成矿机理。实验结果表明,具原地-半原地性质的中元古代花岗岩很可能是由6份(或4份)石英绢云母片岩+1份斜长角闪片麻岩、在压力为1.879～2.143GPa、温度849～901℃的条件下部分熔融形成的,部分熔融过程同时还发生了金的聚集和活化迁移。  相似文献   

Permian radiolarians,chert and basalt from the Daxinshan Formation in Lancangjiang belt of southwestern Yunnan,China   总被引：2，自引：0，他引：2  

Qinglai?FengEmail author  Shangyue?Shen  Benpei?Liu  Dietrich?Helmcke  Xianggui?Qian  Weiming?Zhang 《中国科学D辑(英文版)》2002,45(1):63-71

The stratigraphical sequences composed of chert and basalt were found in the Daxinshan area of Simao and the Manbie area of Jinghong, southwestern Yunnan. The Middle Permian to ealiest Late Permian radiolarians, such as Follicucullus and Pseudoalbaillella, have been identified from the chert. The chert from the Manbie area of Jinghong is characterized by high SiO₂content (over 92%), large ratios of MnO/TiO₂ (2.15) and low ratios of Al/(Al+Fe+Mn) (≤0.1) and Ce/Ce*(0.4), which indicate that the chert was deposited in pelagic basin. The chert from the Daxinshan area of Simao, however, is characterized by low SiO₂ content, low ratios of MnO/TiO₂ (0.27) and high ratios of Al/(Al+Fe+Mn) (0.49) and Ce/Ce*(0.88), which imply that the chert was deposited in continental margin basin. The basalts from the both areas belong to tholeiite series, and the chemical compositions of their major, rare earth and trace elements show the characteristics of MORB. These results evidence that there are volcanic rocks and chert sequences representing pelagic basin and oceanic basin near continent. These sequences and the formerly reported island-arc volcanic rock sequences imply that the Daxinshan Formation in the Lancangjiang belt represents a sedimentary assemblage formed in active continental margin basin.  相似文献   

六盘山弧形构造带铜多金属矿床的成矿环境   总被引：1，自引：0，他引：1  

张韬  林畅松  丁孝忠  杜玉良  翟刚毅  张文秦 《地球学报》2002,23(6):553-558

六盘山弧形构造带位于青藏高原东北缘,自震旦-寒武纪以来,经历了“威尔逊旋回“构造演化。在陆内裂谷和板块俯冲阶段,成矿类型主要为海底火山块状硫化物型和与韧性剪切作用有关的构造蚀变岩型,而在碰撞造山和陆内造山阶段,成矿类型演变为与大型推覆体构造有关的似层状热液型,显示出不同构造演化阶段所反映的成矿环境不同。  相似文献   

辽宁小佟家堡子金矿床成矿时代探讨   总被引：12，自引：2，他引：10  

刘国平 《矿床地质》2002,21(1):53-57

小佟家堡子金矿床位于辽东金矿集中区,为产于古元古代变质岩系中的微细粒浸染型金矿,矿床类型独特。文章采用了绢云母^40Ar/^39Ar法对样品从450℃进行了8个阶段的加热分析。从绢云母石英交代岩型金矿石中挑选出与金矿化密切共生的绢云母单矿物,通过^40Ar/^39Ar快中子活化阶段加热法获得坪年龄为167Ma。绢云母^40Ar/^39Ar法测年结果与矿床的控矿构造特征、区域岩浆活动的演化规律相吻合,进一步证明了该金矿床为燕山期成矿。同时,绢云母^40Ar/^39Ar的马鞍形年龄谱还表明,在绢云母石英交代岩形成过程中,可捕获部分“过剩剩氩”,这可能是造成K－Ar法年龄值高、范围较大的原因之一。  相似文献