Observations of C₂H₆ and C₂H₂ in the stratosphere of Saturn     

Pedro V. Sada  Gordon L. Bjoraker  Paul N. Romani 《Icarus》2005,173(2):499-507

We have performed high-resolution spectral observations at mid-infrared wavelengths of C₂H₆ (12.16 μm), and C₂H₂ (13.45 μm) on Saturn. These emission features probe the stratosphere of the planet and provide information on the hydrocarbon photochemical processes taking place in that region of the atmosphere. The observations were performed using our cryogenic echelle spectrometer Celeste, in conjunction with the McMath-Pierce 1.5-m solar telescope in November and December 1994. We used Voyager IRIS CH₄ observations (7.67 μm) to derive a temperature profile on the saturnian atmosphere for the region of the stratosphere. This profile was then used in conjunction with height-dependent volume mixing ratios of each hydrocarbon to determine global abundances for ethane and acetylene. Our ground-based measurements indicate abundances of for C₂H₆ (1.0 mbar pressure level), and for C₂H₂ (1.6 mbar pressure level). We also derived new mixing ratios from the Voyager mid-latitude IRIS observations; 8.6±0.9×¹⁰⁻⁶ for C₂H₆ (0.1-3.0 mbar pressure level), and 1.6±0.2×¹⁰⁻⁷ for C₂H₂ (2.0 mbar pressure level).  相似文献   

Synthesis, crystal structure and crystal chemistry of ferri-clinoholmquistite, ?Li ₂Mg ₃Fe ³⁺ ₂Si ₈O ₂₂(OH) ₂     

G. Iezzi  F. Cámara  R. Oberti  G. Della Ventura  G. Pedrazzi  J-L Robert 《Physics and Chemistry of Minerals》2004,31(6):375-385

This work reports the synthesis of ferri-clinoholmquistite, nominally _Li2(Mg₃Fe³⁺₂)Si₈O₂₂(OH)₂, at varying f_O2 conditions. Amphibole compositions were characterized by X-ray (powder and single-crystal) diffraction, microchemical (EMPA) and spectroscopic (FTIR, Mössbauer and Raman) techniques. Under reducing conditions ( NNO+1, where NNO = Nickel–Nickel oxide buffer), the amphibole yield is very high (>90%), but its composition, and in particular the FeO/Fe₂O₃ ratio, departs significantly from the nominal one. Under oxidizing conditions ( NNO+1.5), the amphibole yield is much lower (<60%, with Li-pyroxene abundant), but its composition is close to the ideal stoichiometry. The exchange vector of relevance for the studied system is ^M2(Mg,Fe²⁺) ^M4(Mg,Fe²⁺) ^M2Fe³⁺_–1 ^M4Li_–1, which is still rather unexplored in natural systems. Amphibole crystals of suitable size for structure refinement were obtained only at 800 °C, 0.4 GPa and NNO conditions (sample 152), and have C2/m symmetry. The X-ray powder patterns for all other samples were indexed in the same symmetry; the amphibole closest to ideal composition has a = 9.428(1) Å, b = 17.878(3) Å, c = 5.282(1) Å, = 102.06(2)°, V = 870.8(3) ų. Mössbauer spectra show that Fe³⁺ is strongly ordered at M2 in all samples, whereas Fe²⁺ is disordered over the B and C sites. FTIR analysis shows that the amount of ^CFe²⁺ increases for increasingly reducing conditions. FTIR data also provide strong evidence for slight but significant amounts of Li at the A sites.  相似文献   

建筑结构抗震研究若干基本问题概述及讨论   总被引：3，自引：1，他引：2  

孙景江 《震灾防御技术》2006,1(2):87-96

本文介绍和讨论了结构抗震研究中的一些基本问题,包括地震反应分析选择地面运动输入应注意的问题,高层结构地震模拟试验问题和结构地震反应分析中的主要分析方法和存在的问题,最后简要介绍了目前常用结构反应分析程序。  相似文献   

The crystal chemistry of lithium and Fe3+ in synthetic orthopyroxene     

Fernando Cámara  Gianluca Iezzi  Massimo Tiepolo  Roberta Oberti 《Physics and Chemistry of Minerals》2006,33(7):475-483

Lithian ferrian enstatite with Li₂O = 1.39 wt% and Fe₂O₃ 7.54 wt% was synthesised in the (MgO–Li₂O–FeO–SiO₂–H₂O) system at P = 0.3 GPa, T = 1,000°C, fO₂ = +2 Pbca, and a = 18.2113(7), b = 8.8172(3), c = 5.2050(2) Å, V = 835.79(9) Å³. The composition of the orthopyroxene was determined combining EMP, LA-ICP-MS and single-crystal XRD analysis, yielding the unit formula ^M2(Mg_0.59Fe _0.21 ²⁺ Li_0.20) ^M1(Mg_0.74Fe _0.20 ³⁺ Fe _0.06 ²⁺ ) Si₂O₆. Structure refinements done on crystals obtained from synthesis runs with variable Mg-content show that the orthopyroxene is virtually constant in composition and hence in structure, whereas coexisting clinopyroxenes occurring both as individual grains or thin rims around the orthopyroxene crystals have variable amounts of Li, Fe³⁺ and Mg contents. Structure refinement shows that Li is ordered at the M2 site and Fe³⁺ is ordered at the M1 site of the orthopyroxene, whereas Mg (and Fe²⁺) distributes over both octahedral sites. The main geometrical variations observed for Li-rich samples are actually due to the presence of Fe³⁺, which affects significantly the geometry of the M1 site; changes in the geometry of the M2 site due to the lower coordination of Li are likely to affect both the degree and the kinetics of the non-convergent Fe²⁺-Mg ordering process in octahedral sites.  相似文献   

kSZ from patchy reionization: The view from the simulations     

Ilian T. Iliev  Ue-Li Pen  J. Richard Bond  Garrelt Mellema  Paul R. Shapiro   《New Astronomy Reviews》2006,50(11-12):909

We present the first calculation of the kinetic Sunyaev–Zel’dovich (kSZ) effect due to the inhomogeneus reionization of the universe based on detailed large-scale radiative transfer simulations of reionization. The resulting sky power spectra peak at ℓ = 2000–8000 with maximum values of [ℓ(ℓ + 1)C_ℓ/(2π)]_max  4–7 × 10 ⁻¹³. The scale roughly corresponds to the typical ionized bubble sizes observed in our simulations, of 5–20 Mpc. The kSZ anisotropy signal from reionization dominates the primary CMB signal above ℓ = 3000. At large-scales the patchy kSZ signal depends only on the source efficiencies. It is higher when sources are more efficient at producing ionizing photons, since such sources produce larger ionized regions, on average, than less efficient sources. The introduction of sub-grid gas clumping in the radiative transfer simulations produce significantly more power at small-scales, but has little effect at large-scales. The patchy reionization kSZ signal is dominated by the post-reionization signal from fully-ionized gas, but the two contributions are of similar order at scales ℓ  3000 − 10⁴, indicating that the kSZ anisotropies from reionization are an important component of the total kSZ signal at these scales.  相似文献   

孟加拉湾风暴Mala结构及对云南强降水的影响   总被引：1，自引：0，他引：1  

金少华  杨明  李华宏  艾永智 《气象科学》2010,30(1):74-81

利用实时观测资料和NCEP(1°×1°)的6 h再分析资料,对2006年春季发生在孟加拉湾的超强风暴Mala的移动路径、强度变化、环流背景以及风暴温湿场、动力场特征等进行分析。结果表明:Mala在阿拉伯副热带高压和西太平洋副热带高压两高间辐合区生成、加强,并沿西太平洋副热带高压西侧西南或偏南气流移动。风暴发展、成熟到消亡,湿度对风暴的作用比温度明显;动力场结构除具有台风结构的一般特征外,在风暴发展期,中心附近散度场从低层到高层为辐合和辐散交替结构,表明风暴内部高空辐散抽吸作用对于风暴发展起到重要作用。登陆后风暴低压内自身能量和水汽与冷空气共同作用下,在冷暖交汇处出现强烈的上升运动和激发出中尺度辐合线是造成云南强降水主要原因。  相似文献   

Spatial and short-term temporal variations in Uranus’ near-infrared spectrum     

J.W. Norwood  N.J. Chanover 《Icarus》2009,203(1):331-335

We obtained near-infrared spectra of Uranus at NASA’s Infrared Telescope Facility during the planet’s September 2006 and September 2007 oppositions. Ratios between the spectra indicate that in 2006, Uranus’ methane windows appeared much brighter in the south than in the north, and that between 2006 and 2007 they grew dimmer in the south and brighter in the north; we interpret these variations to be primarily caused by changing brightness in Uranus’ upper cloud layer near 2 bars.  相似文献   

文章已录用：阴山晚中生代板内造山特征及其动力机制-以内蒙古大青山为例     

杜菊民 《地质学报》2009,83(7):910-922

内蒙古大青山属我国典型的板内造山带阴山山脉的南部山系,其西段缺少大型低角度推覆构造及大型深成岩对前期演化历史的干扰,是研究阴山板内造山特点及过程的理想区域。通过对大青山西段的构造进行几何学和运动学的分析表明,古老结晶基底以逆冲推覆及基底褶皱的形式广泛的巻入中生代构造变形,以及先存构造样式的广泛复活并对后期地层沉积和断层发育的控制作用是内蒙古大青山地区中生代板内造山的两个基本特征。这些变形特征反映了阴山带板内造山过程中,是以结晶基底为受力层,并控制上覆盖层进行构造变形的,进而表明板内造山主要是由水平挤压应力造成的。结合研究区构造变形特点及邻区中生代构造地质情况的分析认为,晚侏罗世时期之所以在阴山带形成强烈的板内造山运动,是由其北部西伯利亚板块与蒙古褶皱带碰撞产生的板缘应力的远程传递,以及其南侧强硬的鄂尔多斯地块的阻挡共同作用而形成的。  相似文献   

Ab initio quantum mechanical study of γ-AlOOH boehmite: structure and vibrational spectrum     

Yves Noel  Raffaella Demichelis  Fabien Pascale  Piero Ugliengo  Roberto Orlando  Roberto Dovesi 《Physics and Chemistry of Minerals》2009,36(1):47-59

The structure and vibrational spectrum of boehmite have been investigated at the quantum-mechanical level with the CRYSTAL code, using a Gaussian-type basis set and the B3LYP Hamiltonian. Three space groups are considered in this study: Cmcm, Cmc2₁, P2₁/c. Cmcm turns out to correspond to a transition state, whereas Cmc2₁ and P2₁/c are minimum energy structures. The difference among them is the position of H atoms only, the Al-O frame being essentially the same. Harmonic frequencies at the Γ point have been computed. The comparison between calculated and experimental frequencies shows a good agreement for the Al-O part of the spectrum (under 790 cm⁻¹). For the Al-OH bending modes (800–1,300 cm⁻¹) an absolute differences of 50–100 cm⁻¹ is observed; for the OH stretching modes (3,200–3,500 cm⁻¹) it increases to 120–200 cm⁻¹: anharmonicity is large because OH groups are involved in strong hydrogen bonds.  相似文献   

北京西山煤田滑脱构造的遥感研究     

夏炎  王文侠  张大顺 《国土资源遥感》1995,6(4):26-31

本文利用多种遥感资料提供的大量的新的构造信息,对北京西山煤田已有的地质认识和成果进行了重要补充和修改,划分出推覆型和滑型两种基本类型的滑脱构造,并详细研究了各个滑脱构造系统的影像特征、展布规律、几何形态、成因机制、演化历史以及控煤作用。  相似文献