Adsorption of Copper, Nickel, and Cadmium on Goethite in the Presence of Organic Ligands   总被引：2，自引：0，他引：2  

Diane Buerge-Weirich  Philippe Behra  Laura Sigg 《Aquatic Geochemistry》2003,9(2):65-85

Adsorption of copper, cadmium and nickel at low concentrations on goethite was studied in the presence of the simple organic ligands oxalate, salicylate, and pyromellitate. The experimental metal adsorption behavior was compared to calculations with a surface complexation model to evaluate the most important interactions. Oxalate mostly decreased Cu and Ni adsorption at high pH-values by competition between solution and surface complexation but had no effect on Cd adsorption. Cu adsorption in the presence of oxalate below pH 6 could best be described by defining a ternary complex of type A (surface-metal-ligand). Salicylate had only minor effects on metal adsorption. The adsorption of Cu in the presence of salicylate above pH 5 could be explained by a ternary complex of type A. Pyromellitate increased the adsorption of Cu and Cd in the acidic pH-range, likely by formation of ternary surface complexes of type B (surface-ligand-metal).  相似文献   

Contrasting metamorphic evolution of metasedimentary rocks from the Çine and Selimiye nappes in the Anatolide belt, western Turkey   总被引：1，自引：0，他引：1  

J. L. Régnier  U. Ring  C. W. Passchier  K. Gessner  T. Güngör 《Journal of Metamorphic Geology》2003,21(7):699-721

Abstract P–T conditions, mineral isograds, the relation of the latter to foliation planes and kinematic indicators are used to elucidate the tectonic nature and evolution of a shear zone in an orogen exhumed from mid‐crustal depths in western Turkey. Furthermore, we discuss whether simple monometamorphic fabrics of rock units from different nappes result from one single orogeny or are related to different orogenies. Metasedimentary rocks from the Çine and Selimiye nappes at the southern rim of the Anatolide belt of western Turkey record different metamorphic evolutions. The Eocene Selimiye shear zone separates both nappes. Metasedimentary rocks from the Çine nappe underneath the Selimiye shear zone record maximum P–T conditions of about 7 kbar and >550 °C. Metasedimentary rocks from the overlying Selimiye nappe have maximum P–T conditions of 4 kbar and c. 525 °C near the base of the nappe. Kinematic indicators in both nappes are related to movement on the Selimiye shear zone and consistently show a top‐S shear sense. Metamorphic grade in the Selimiye nappe decreases structurally upwards as indicated by mineral isograds defining the garnet‐chlorite zone at the base, the chloritoid‐biotite zone and the biotite‐chlorite zone at the top of the nappe. The mineral isograds in the Selimiye nappe run parallel to the regional S_R foliation, parallel the Selimiye shear zone and indicate that the Selimiye shear zone formed during this prograde greenschist to lower amphibolite facies metamorphic event but remained active after the peak of metamorphism. ⁴⁰Ar/³⁹Ar mica ages and the tectonometamorphic relationship with the Eocene Cyclades–Menderes thrust, which occurs above the Selimiye nappe in the study area, suggests an Eocene age of metamorphism in the Selimiye nappe. Metasedimentary rocks of the Çine nappe 20–30 km north of the Selimiye shear zone record maximum P–T conditions of 8–11 kbar and 600–650 °C. An age of about 550 Ma is indicated for amphibolite facies metamorphism and associated top‐N shear in the orthogneiss of the Çine nappe. Our study shows that simple monophase tectonometamorphic fabrics do not always indicate a simple orogenic development of a nappe stack. Preservation in some areas and complete overprinting of those fabrics in other areas apparently occur very heterogeneously.  相似文献   

Metamorphic petrology and zircon geochronology of high-grade rocks from the central Mozambique Belt of Tanzania: crustal recycling of Archean and Palaeoproterozoic material during the Pan-African orogeny   总被引：7，自引：0，他引：7  

H. Sommer  A. Kröner  C. Hauzenberger  S. Muhongo  M. T. D. Wingate 《Journal of Metamorphic Geology》2003,21(9):915-934

New data on the metamorphic petrology and zircon geochronology of high‐grade rocks in the central Mozambique Belt (MB) of Tanzania show that this part of the orogen consists of Archean and Palaeoproterozoic material that was structurally reworked during the Pan‐African event. The metamorphic rocks are characterized by a clockwise P–T path, followed by strong decompression, and the time of peak granulite facies metamorphism is similar to other granulite terranes in Tanzania. The predominant rock types are mafic to intermediate granulites, migmatites, granitoid orthogneisses and kyanite/sillimanite‐bearing metapelites. The meta‐granitoid rocks are of calc‐alkaline composition, range in age from late Archean to Neoproterozoic, and their protoliths were probably derived from magmatic arcs during collisional processes. Mafic to intermediate granulites consist of the mineral assemblage garnet–clinopyroxene–plagioclase–quartz–biotite–amphibole ± K‐feldspar ± orthopyroxene ± oxides. Metapelites are composed of garnet‐biotite‐plagioclase ± K‐feldspar ± kyanite/sillimanite ± oxides. Estimated values for peak granulite facies metamorphism are 12–13 kbar and 750–800 °C. Pressures of 5–8 kbar and temperatures of 550–700 °C characterize subsequent retrogression to amphibolite facies conditions. Evidence for a clockwise P–T path is provided by late growth of sillimanite after kyanite in metapelites. Zircon ages indicate that most of the central part of the MB in Tanzania consists of reworked ancient crust as shown by Archean (c. 2970–2500 Ma) and Palaeoproterozoic (c. 2124–1837 Ma) protolith ages. Metamorphic zircon from metapelites and granitoid orthogneisses yielded ages of c. 640 Ma which are considered to date peak regional granulite facies metamorphism during the Pan‐African orogenic event. However, the available zircon ages for the entire MB in East Africa and Madagascar also document that peak metamorphic conditions were reached at different times in different places. Large parts of the MB in central Tanzania consist of Archean and Palaeoproterozoic material that was reworked during the Pan‐African event and that may have been part of the Tanzania Craton and Usagaran domain farther to the west.  相似文献   

Geology and Genesis of the Ta'ergou Skarn - Quartz Vein Tungsten Deposit in the North Qilian Caledonian Orogenic Belt, Northwest China     

Zuoheng Zhang    Jingwen Mao    Jianmin Yang    Zhiliang Wang  Zhaochong Zhang 《Resource Geology》2003,53(2):101-114

Abstract. The Ta'ergou tungsten deposit in Gansu province, northwestern China, is located in the western part of the North Qilian Caledonian orogen, and consists of scheelite skarn bodies and wolframite quartz veins. The tungsten‐bearing skarn developed by the replacement of carbonate layers intercalated in the Precambrian schist and amphibolite whereas wolframite‐quartz ore veins developed along a group of fractures that cut through horizontal skarns. The Ta'ergou tungsten deposit is genetically related to the Caledonian Yeniutan granodiorite intrusion and occurs ca. 500 m wide in the exo‐contact zone 300 ～ 500 m apart from the intrusion. The granodiorite displays a lower grade of differentiation, low content of SiO₂ and high contents of mafic components. There are three types of fluid inclusions in the wolframite‐quartz vein systems, i. e. aqueous, CO₂‐H₂O and CO₂‐rich. The homogenization temperature of aqueous inclusion ranges from 140 to 380d?C and their salinities from 6.4 to 17.4 equivalent wt% NaCl. Laser Raman spectroscopy shows that the inclusions contain a relatively high content of CO₂. The δ³⁴S values of skarn type sulfides range from +8.1 to +12.7 per mil and those of quartz vein sulfides from +9.3 to +14.9 per mil, similar to sulfides of the granodiorite with from +6.0 to +11.7 per mil. The δ¹⁸O values of quartz are between +10.5 and +13.3 per mil and those of wolframite between +3.4 and +5.1 per mil. The δ¹⁸O water values of ore forming fluids range from +0.6 to +6.4 per mil and suggest the mixture of magmatic fluids with meteoric water formed the ore‐forming fluids. It has been proved that Precambrian strata in the west sector of North Qilian region are enriched in tungsten. We propose the strata were remelted to be tungsten‐granitoid during subduction. The polymetallic tungsten was gradually accumulated into the roof pendants of the granite intrusion by fractional crystallization and then was deposited by hydrothermal fluids during metasomatism and infilling along fractures. On the other hand, the granite intrusion also acted as “heating machine” to make hydrothermal fluids leach out the metals from Precambrian strata and these metals joined the ore‐forming hydrothermal system.  相似文献   

Geochemical Characteristics of Granitoids of the Erdenet Porphyry Copper Deposit, Mongolia   总被引：4，自引：0，他引：4  

Haruhisa Morozumi 《Resource Geology》2003,53(4):311-316

Abstract. The Erdenet porphyry copper deposit is one of the major mineral deposits in Mongolia. The geochemical data of granitoids acquired for the Erdenet and its surrounding areas are re-examined. The granitoids of the Erdenet deposit with hypogene type mineralization show the lowest TiO₂ content. Although Ti was possibly lost through the pyritization, it is also possible that the hypogene type mineralization occurred accompanied with the most differentiated granitoids. The variation of the element contents related to the mineralization of the Erdenet deposit shows the decrease of MgO and CaO contents, rather constant K₂O content, rather constant to decrease of Na₂O content, with respect to the Cu contents. The rather constant Na₂O in the mineralized zone is owing to the residual albite against the sericitic alteration. The granitoids of the Erdenet area show an increase of Na₂O content and a decrease of K₂O content with an increase of SiO₂ content. This trend makes clear contrast to granitoids in the surrounding areas. The granitoids of the Erdenet area might have the adakitic nature based on the Sr and Y contents.  相似文献   

Layer parallel shortening in salt-detached folds: constraint on cross-section restoration     

M. Sans  J. Vergs  E. Gomis  J. M. Pars  M. Schiattarella  A. Trav  F. Calvet  P. Santanach  A. Doulcet 《Tectonophysics》2003,372(1-2):85-104

Cleavage-fissility perpendicular to bedding is a common feature in the external part of fold-and-thrust belts. Three techniques were used to determine the internal distortion in the frontal Southern Pyrenees: the analysis of strain markers such as burrows and rain drops, the measurement of fissility, and the measurement of anisotropy of magnetic susceptibility (AMS). The comparison of the three techniques showed a good fit although they differ in sensitivity to penetrative strain variations in the range of deformation values explored in the study case. On the regional scale, the values of layer parallel shortening (LPS) derived from the markers analysis are very constant and account for 16–23% of shortening. These values are two to three times larger than the shortening values calculated from the restoration of the macroscopic scale structures and indicate a good decoupling above the Cardona salt Formation. This study permitted an accurate restoration of the low-amplitude el Guix detached anticline.  相似文献   

Neoproterozoic accretionary and collisional events on the western margin of the Siberian craton: new geological and geochronological evidence from the Yenisey Ridge     

Valery A. Vernikovsky  A. E. Vernikovskaya  A. B. Kotov  E. B. Sal'nikova  V. P. Kovach 《Tectonophysics》2003,375(1-4):147

The geological, structural and tectonic evolutions of the Yenisey Ridge fold-and-thrust belt are discussed in the context of the western margin of the Siberian craton during the Neoproterozoic. Previous work in the Yenisey Ridge had led to the interpretation that the fold belt is composed of high-grade metamorphic and igneous rocks comprising an Archean and Paleoproterozoic basement with an unconformably overlying Mesoproterozoic–Neoproterozoic cover, which was mainly metamorphosed under greenschist-facies conditions. Based on the existing data and new geological and zircon U–Pb data, we recognize several terranes of different age and composition that were assembled during Neoproterozoic collisional–accretional processes on the western margin of the Siberian craton. We suggest that there were three main Neoproterozoic tectonic events involved in the formation of the Yenisey Ridge fold-and-thrust belt at 880–860 Ma, 760–720 Ma and 700–630 Ma. On the basis of new geochronological and petrological data, we propose that the Yeruda and Teya granites (880–860 Ma) were formed as a result of the first event, which could have occurred in the Central Angara terrane before it collided with Siberia. We also propose that the Cherimba, Ayakhta, Garevka and Glushikha granites (760–720 Ma) were formed as a result of this collision. The third event (700–630 Ma) is fixed by the age of island-arc and ophiolite complexes and their obduction onto the Siberian craton margin. We conclude by discussing correlation of these complexes with those in other belts on the margin of the Siberian craton.  相似文献   

Neoarchaean magmatism and metamorphism of the western granulites in the central domain of the Mozambique belt, Tanzania: U–Pb shrimp geochronology and PT estimates     

S. P. Johnson  H. N. C. Cutten  S. Muhongo  B. De Waele 《Tectonophysics》2003,375(1-4):125

U–Pb sensitive high resolution ion microprobe (SHRIMP) dating of zircons from charnockitic and garnet–biotite gneisses from the central portion of the Mozambique belt, central Tanzania indicate that the protolith granitoids were emplaced in a late Archaean, ca. 2.7 Ga, magmatic event. These ages are similar to other U–Pb and Pb–Pb ages obtained for other gneisses in this part of the belt. Zircon xenocrysts dated between 2.8 and 3.0 Ga indicate the presence of an older basement. Major and trace element geochemistry of these high-grade gneisses suggests that the granitoid protoliths may have formed in an active continental margin environment. Metamorphic zircon rims and multifaceted metamorphic zircons are dated at ca. 2.6 Ga indicating that these rocks were metamorphosed some 50–100 my after their emplacement. Pressure and temperature estimates on the charnockitic and garnet–biotite gneisses were obscured by post-peak metamorphic compositional homogenisation; however, these estimates combined with mineral textures suggest that these rocks underwent isobaric cooling to 800–850 °C at 12–14 kbar. It is considered likely that the granulite facies mineral assemblage developed during the ca. 2.6 Ga event, but it must be considered that it might instead represent a pervasive Neoproterozoic, Pan African, granulite facies overprint, similar to the ubiquitous eastern granulites further to the east.  相似文献   

Middle Paleozoic paleomagnetism of east Kazakhstan: post-Middle Devonian rotations in a large-scale orocline in the central Ural–Mongol belt     

Natalia M. Levashova  Kirill E. Degtyarev  Mikhail L. Bazhenov  Adam Q. Collins  Rob Van der Voo   《Tectonophysics》2003,377(3-4):249-268

In order to test different hypotheses concerning the Paleozoic evolution of the Ural–Mongol belt (UMB) and the amalgamation of Eurasia, we studied Middle Devonian basalts from two localities (11 sites) and Lower Silurian volcanics, redbeds, and intra-formational conglomerates from three localities (20 sites) in the Chingiz Range of East Kazakhstan. The Devonian rocks prove to be heavily overprinted in the late Paleozoic, and a high-temperature, presumably primary, southerly, and down component is isolated at only four sites from a homoclinal section. Most Silurian redbeds are found to be remagnetized in the late Paleozoic; in contrast, a bipolar near-horizontal remanence, isolated from Silurian volcanics, is most probably primary as indicated by positive tilt and conglomerate tests. Analysis of paleomagnetic data from the Chingiz Range shows that southward-pointing directions in Ordovician, Silurian, and Devonian rocks are of normal polarity and hence indicate large-scale rotations after the Middle Devonian. The Chingiz paleomagnetic directions can be compared with Paleozoic data from the North Tien Shan and with the horseshoe-shaped distribution of subduction-related volcanic complexes in Kazakhstan. Both paleomagnetic and geological data support the idea that today's strongly curved volcanic belts of Kazakhstan are an orocline, deformed mostly before mid-Permian time. Despite the determination of nearly a dozen new Paleozoic paleopoles in this study and other recent publications by our team, significant temporal and spatial gaps remain in our knowledge of the paleomagnetic directions during the middle and late Paleozoic. However, the paleomagnetic results from the Chingiz Range and the North Tien Shan indicate that these areas show generally coherent motions with Siberia and Baltica, respectively.  相似文献   

用卫星高光谱数据提取江西德兴铜矿矿山废水的pH值污染指标     

刘圣伟  甘甫平  王润生 《地质通报》2003,(Z1)

在对德兴铜矿矿山废水的光谱特征深入分析研究的基础上,总结了不同类型水体(酸性水、碱性水以及河流水)的特征光谱,并利用地物谱特征开展矿山废水pH值污染指标提取研究。针对水体光谱反射率低、特征光谱不明显的特点,采用矿区卫星Hyperion高光谱数据,应用ISA算法和掩膜技术识别出水体分布并进一步与MNF变换有效结合,根据波段散点图进行不同pH值水体的有效分割。为矿山废水污染的诊断和监测提供了新技术和理论支撑。  相似文献