Coexisting melt (MI), fluid-melt (FMI) and fluid (FI) inclusions in quartz from the Oktaybrskaya pegmatite, central Transbaikalia, have been studied and the thermodynamic modeling of PVTX-properties of aqueous orthoboric-acid fluids has been carried out to define the conditions of pocket formation. At room temperature, FMI in early pocket quartz and in quartz from the coarse-grained quartz–oligoclase host pegmatite contain crystalline aggregates and an orthoboric-acid fluid. The portion of FMI in inclusion assemblages decreases and the volume of fluid in inclusions increases from the early to the late growth zones in the pocket quartz. No FMI have been found in the late growth zones. Significant variations of solid/fluid ratios in the neighboring FMI result from heterogeneous entrapment of coexisting melts and fluids by a host mineral. Raman spectroscopy, SEM EDS and EMPA indicate that the crystalline aggregates in FMI are dominated by mica minerals of the boron-rich muscovite–nanpingite CsAl2[AlSi3O10](OH,F)2 series as well as lepidolite. Topaz, quartz, potassium feldspar and several unidentified minerals occur in much lower amounts. Fluid isolations in FMI and FI have similar total salinity (4–8 wt.% NaCl eq.) and H3BO3 contents (12–16 wt.%). The melt inclusions in host-pegmatite quartz homogenize at 570–600 °C. The silicate crystalline aggregates in large inclusions in pocket quartz completely melt at 615 °C. However, even after those inclusions were significantly overheated at 650±10 °C and 2.5 kbar during 24 h they remained non-homogeneous and displayed two types: (i) glass+unmelted crystals and (ii) fluid+glass. The FMI glasses contain 1.94–2.73 wt.% F, 2.51 wt.% B2O3, 3.64–5.20 wt.% Cs2O, 0.54 wt.% Li2O, 0.57 wt.% Ta2O5, 0.10 wt.% Nb2O5, 0.12 wt.% BeO. The H2O content of the glass could exceed 12 wt.%. Such compositions suggest that the residual melts of the latest magmatic stage were strongly enriched in H2O, B, F, Cs and contained elevated concentrations of Li, Be, Ta, and Nb. FMI microthermometry showed that those melts could have crystallized at 615–550 °C.
Crystallization of quartz–feldspar pegmatite matrix leads to the formation of H2O-, B- and F-enriched residual melts and associated fluids (prototypes of pockets). Fluids of different compositions and residual melts of different liquidus–solidus P–T-conditions would form pockets with various internal fluid pressures. During crystallization, those melts release more aqueous fluids resulting in a further increase of the fluid pressure in pockets. A significant overpressure and a possible pressure gradient between the neighboring pockets would induce fracturing of pockets and “fluid explosions”. The fracturing commonly results in the crushing of pocket walls, formation of new fractures connecting adjacent pockets, heterogenization and mixing of pocket fluids. Such newly formed fluids would interact with a primary pegmatite matrix along the fractures and cause autometasomatic alteration, recrystallization, leaching and formation of “primary–secondary” pockets. 相似文献
It is usually recognized that relatively large amounts of soil particles cannot be transported by raindrop splashes under windless rain. However, the splash-saltation process can cause net transportation in the prevailing wind direction since variations in splash-saltation trajectory due to the wind are expected in wind-driven rain. Therefore, determining the combined effect of rain and wind on the process should enable improvement of the estimation of erosion for any given prediction technique. This paper presents experimental data on the effects of slope aspect, slope gradient, and horizontal wind velocity on the splash-saltation trajectories of soil particles under wind-driven rain. In a wind tunnel facility equipped with a rainfall simulator, the rains driven by horizontal wind velocities of 6, 10, and 14 m s−1 were allowed to impact three agricultural soils packed into 20×55 cm soil pans placed at both windward and leeward slopes of 7%, 15%, and 20%. Splash-saltation trajectories were measured by trapping the splashed particles at distances downwind on a 7-m uniform slope segment in the upslope and downslope directions, respectively, for windward and leeward slopes. Exponential decay curves were fitted for the mass distribution of splash-saltation sediment as a function of travel distance, and the average splash-saltation trajectory was derived from the average value of the fitted functions. The results demonstrated that the average trajectory of a raindrop-induced and wind-driven soil particle was substantially affected by the wind shear velocity, and it had the greatest correlation (r=0.96 for all data) with the shear velocity; however, neither slope aspect nor slope gradient significantly predicted the splash-saltation trajectory. More significantly, a statistical analysis conducted with nonlinear regression model of C1(u*2/g) showed that average trajectory of splash saltation was approximately three times greater than that of typical saltating sand grain. 相似文献