Comparative studies of the kinetic parameters of various algaenans and kerogens via open-system pyrolyses     

Daniel Dessort  Jacques Connan  Sylvie Derenne  Claude Largeau 《Organic Geochemistry》1997,26(11-12)

Kinetic parameters were determined for the first time, via open-system pyrolyses, on algaenans (highly resistant biomacromolecules that are selectively preserved during kerogen formation) isolated from extant microalgae. Parallel studies were also carried out on 10 kerogens exhibiting, with one exception, a low level of maturity. These kerogens included samples chiefly derived from the selective preservation of the above algaenans and samples mainly, or almost exclusively, derived from the “natural vulcanization” pathway. Important differences in activation energy (E_a) distributions were observed between the four algaenans investigated and correlated with their chemical structures. The kerogens predominantly derived from algaenan-selective preservation (Pula alginite, NE 70 and BJ 248 Torbanites, Rundle Oil Shale) also exhibited pronounced differences in E_a distributions. These distributions provided: (i) information on the diversity of the source materials; and (ii) reflected the occurrence of important differences in chemical structures and thermal behaviour between three of the tested kerogens, even though they are all classified as low maturity type I. The Kimmeridge Clay samples and the Lorca Oil Shale showed broad E_a distributions shifted to low energies when compared with the above algaenans and kerogens. Such shifts reflect an important (or even almost exclusive for some of these kerogens) contribution of materials originating from sulphur incorporation into various lipids during early diagenesis. Finally, the kinetic data derived for the nine low maturity fossil samples were extrapolated to a very low, geological heating rate of 3°C Ma⁻¹ and the generation rate curves and cumulative yield curves thus obtained were compared.  相似文献   

中子活化分析在铼—锇法年龄测定中的应用     

屈文俊  杜安道 《岩矿测试》1997,16(4):289-292

同位素稀释中子活化分析铼与感耦等离子体质谱法测定锇相结合，应用于辉钼矿及铜＿镍硫化物矿物的铼＿锇年龄测定，取得了满意的结果，扩大了铼＿锇测年法的应用范围。  相似文献   

铂族元素迁移富集机理的新探   总被引：2，自引：1，他引：2  

郑大中 《四川地质学报》1997,(2)

在岩浆及高温热液中，拍族元素以纳米液态铂族元素单质、铂族元素与其它金属元素的纳米液态合金、纳米液态铂族元素的硫、砷化物迁移。在中、低温热液及表生条件下，除呈上述固态纳米铂族矿物随流体迁移外，还呈配合物形式迁移。然后它们在合适的条件下沉淀富集形成矿床。此外，还讨论了铂族元素与金地球化学条件的异同。  相似文献   

Constraints of Housing Age and Migration on Residential Mobility     

Dowell Myers  S. Simon Choi  Seong Woo Lee 《The Professional geographer》1997,49(1):14-28

This paper investigates the role of housing age in constraining residential mobility, measured as the percent of households that have moved into their homes in the past 15 months. The leading explanation for why mobility rates differ so much among regions of the United States has been the overall level of growth. The present analysis shows that the growth effect operates through both the newness of population (migration) and the newness of housing available for occupancy by all local residents. The posited explanation for this housing age effect is that progressively older units contain increasingly settled occupants, yielding fewer opportunities for in-movers in areas with older housing. It is empirically demonstrated that households in older housing have lower likelihood of recent mobility even after controlling for age, tenure, migration status, and state location of residence. The analysis reveals the temporal interdependency of mobility, migration, person age, and housing age.  相似文献   

Time-domain electromagnetic migration in the solution of inverse problems   总被引：5，自引：0，他引：5  

Michael S. Zhdanov  Oleg Portniaguine 《Geophysical Journal International》1997,131(2):293-309

Time-domain electromagnetic (TDEM) migration is based on downward extrapolation of the observed field in reverse time. In fact, the migrated EM field is the solution of the boundary-value problem for the adjoint Maxwell's equations. The important question is how this imaging technique can be related to the solution of the geoelectrical inverse problem. In this paper we introduce a new formulation of the inverse problem, based on the minimization of the residual-field energy flow through the surface or profile of observations. We demonstrate that TDEM migration can be interpreted as the first step in the solution of this specially formulated TDEM inverse problem. However, in many practical situations this first step produces a very efficient approximation to the geoelectrical model, which makes electromagnetic migration so attractive for practical applications. We demonstrate the effectiveness of this approach in inverting synthetic and practical TDEM data.  相似文献   

Resolution limits for crosswell migration and traveltime tomography   总被引：2，自引：1，他引：2  

Gerard T. Schuster 《Geophysical Journal International》1996,127(2):427-440

  相似文献   

茅台酒酿酒高梁的地质环境研究   总被引：2，自引：0，他引：2  

杨立铮  朱赫宇 《地学前缘》1996,3(2):224-233

茅台酒对酿酒高梁有严格要求，适于茅台酒传统酿造工艺的高梁只产于仁怀县的某些地区，主要是受地质环境的控制。仁怀高梁对某些常量和微量元素有着鲜明的选择性，对磷和钼表现出强烈的吸收作用。岩－土剖面元素的迁聚，对磷和铝的供应是确定仁怀高梁品质和产量的关键。侏罗系砂泥岩、二叠系煤系地层的岩－土剖面，元素淋溶微弱，总量丰富，有效态含量高，组合良好，能正常进行岩－土－高梁系统的物质转化与元素迁移，能充分供应高梁生长所需的磷和钼等元素，是茅台酒酿酒高梁的最宜种植区。  相似文献   

构造岩浆活化与秦岭金矿床   总被引：1，自引：1，他引：1  

赫英 《大地构造与成矿学》1996,20(1):61-66

本文论述了秦岭区构造岩浆活化作用与金矿床形成及演化的关系。作者将秦岭区金矿床分为五类，即；①岩浆活化矿床；②岩浆－构造活化矿床；③构造－岩浆活化矿床；④构造活化矿床；⑤构造－变质活化矿床。  相似文献   

陕西子长油田成藏地质特征   总被引：2，自引：0，他引：2  

刘勇  孙冬胜 《西北地质科学》1996,17(2):70-74

从烃源岩、储集层、圈闭、油气运移及富集条件等方面入手，对子长油田成藏地质特征进行了研究。认为子长油田延长组油气生成及油气初次运移条件均较好，但储层、油气二次运移及富集条件相对较差。延长组主要有五种油藏类型，油气分布主要受储层物性、岩性、岩相等条件所控制。  相似文献   

海南岛后地台造山-造盆模型:火成岩地球化学制约   总被引：9，自引：4，他引：9  

邹和平 《大地构造与成矿学》1997,21(2):117-123

海南岛自海西运动晚幕之后进入后地台活化或地洼阶段，并经历了晚海西-印支期挤压（碰撞）造山、地壳隆起和燕山期以来的块断型造山-造盆作用的过程。火成岩研究资料表明，海南岛地区在晚海西-印支运动期间曾形成一个具有加厚陆壳的后地台造山带；燕山晚期开始出现的裂陷作用是在仍有山根（约60km厚的陆壳）存在的条件下造山带拉伸塌陷阶段的产物；岩石圈底层剥离与地壳山根的去除并最终导致了海南及其邻区从大陆型壳体向陆缘扩张带型壳体的转化。  相似文献