Constraints of stable isotopes on the origin of alunite from advanced argillic alteration systems in Bulgaria     

C. Lerouge  A. Kunov  C. Flhoc  S. Georgieva  A. Hikov  J.L. Lescuyer  R. Petrunov  N. Velinova 《Journal of Geochemical Exploration》2006,90(3):166-182

Voluminous areas of advanced argillic alteration (AAA) constitute major exploration targets for surficial Cu–Au epithermal and potentially underlying porphyry-type deposits. In Bulgaria, more than 30 alunite occurrences are recognised, few of them being associated with a mineralised system. A mineralogical study combined with a stable isotopic (O, H, S) study has been carried out on nine alunite occurrences of advanced argillic zones hosted by volcanic rocks of Late Cretaceous age in the Srednogorie belt and of Oligocene age in the Rhodopes belt. This work was realised in order to constrain the origin of alunite and to define criteria to discriminate alunite from ore deposits and alunite from large barren alteration systems.Mineralogy of the nine occurrences consists of alunite + quartz + minor alumino-phospho-sulphates, associated with more or less kaolinite, dickite, pyrophyllite, diaspore and zunyite, depending on formation temperature. Alunite generally occurs as tabular crystals but is also present as fine-crystalline pseudocubic phases at Boukovo and Sarnitsa, in Eastern Rhodopes. In the advanced argillic alterations associated with economic ore, the presence of zunyite in the deeper parts indicates acid–fluorine–sulphate hydrothermal systems, whereas it is absent in uneconomic and barren advanced argillic alteration. All occurrences are formed at temperatures between 200 and 300 °C.(H, O, S) isotopic signatures of alunite combined with mineralogical features from all the studied occurrences, whatever their type, show characteristics of magmatic-hydrothermal systems. Sulphur data indicate essentially a magmatic origin for sulphur. Oxygen and hydrogen data suggest that hydrothermal fluids result from a mixing between magmatic fluids and an external component, which is identified as seawater-derived fluids or meteoric water in the vicinity of a sea. In most of the alunite occurrences, magmatic fluids are dominant and H₂S/SO₄ ratios are estimated to be higher than 2. Two exceptions exist in the Rhodopes. At Boukovo and Sarnitsa, where the estimated formation temperatures of alunite are the lowest, the external fluids are dominant and H₂S/SO₄ratios are estimated to be lower than or close to 1.At this stage of the work, the mineralogical and isotopic criteria do not enable a clear distinction between economic and uneconomic systems. However, some features are common in the economic ore deposits: the presence of zunyite in the deeper part of the system, the relatively high temperatures suggested by the zunyite + pyrophyllite + alunite + diaspore assemblages, the (O, H, S) signature of alunite, which is characteristic of dominant magmatic–hydrothermal acid–sulphate–fluorine systems.  相似文献   

Indium Enrichment in the Meng'entaolegai Ag-Pb-Zn Deposit, Inner Mongolia, China   总被引：3，自引：0，他引：3  

Qian Zhang    Xiaoqing Zhu    Yuliang He  Junjie Jiang  Dapeng Wang 《Resource Geology》2006,56(3):337-346

Abstract. The Meng'entaolegai In-rich Ag-Pb-Zn deposit is located in the eastern part of Inner Mongolia. It is one of the In-richest deposits in China. Large amounts of quartz and sulfide minerals constitute a hydrothermal quartz-sulfide vein deposit within a Hercynian acidic granite massif, which occupies an area of about 400 km². Thirty-six orebodies, controlled strictly by the E-W trend faults, are found in the orefield of 6 km in length from east to west and 200 to 1,000 m in width from south to north. The ore minerals are mainly galena, sphalerite and pyrite, and subordinate chalcopyrite, arsenopyrite, cassiterite and stannite with many Ag-minerals. The gangue minerals are mainly quartz, calcite, sericite and chlorite. Economic components of the deposit are dominated by Pb andZn (reserves of Pb and Zn are 0.17 Mt and 0.37 Mt, and their grades are 1 % and 2.3 %, respectively), with Ag, Sn, In and Cd (1,800 t Ag, >2,000 t Sn, >500 t In and 1,800 t Cd) as by-products. Indium is highly enriched in ores and its contents are 9 to 295 ppm in ores and 85 to 2,660 ppm in sphalerite. Analytical results show that the ore-forming fluid of this deposit contains 0.8–3.5 ppm In and 4–36 ppm Sn, and the two elements show a very good positive correlation with a correlation coefficient of 0.8672, while the correlation between In and Zn in the ore-forming fluids, with a correlation coefficient of 0.5723, is not as good as that between In and Sn. This indicates that indium has an affinity with tin in the ore-forming fluids. The authors think that this is probably the main reason why those In-rich deposits spread over the world are simultaneously enriched in tin.  相似文献   

日本自然灾害现状与新态势   总被引：3，自引：0，他引：3  

毛德华  何梓霖  秋山道雄 《世界地理研究》2006,15(2):41-47

日本是一个多灾且严重的国家,依据最新资料,分析了日本自然灾害的现状特征;自然灾害影响社会经济发展,而社会经济变化可能成为新的致灾因素并形成新的灾害形式。本文特别对城市化、过疏化、高龄化和网络化与灾害进行了论述;最后论述了“自助”“共助”和“公助”三位一体的防灾基本对策的内容。这些对正处于高速经济发展和城市化的我国来说,具有重要的借鉴作用。  相似文献   

Methylmercury and human biomarkers： Questioning the evidence     

《中国地球化学学报》2006,25(B08):239-239

Methylmercury （MeHg） is a powerful neurotoxicant in humans. In terms of biomarkers of MeHg exposure, hair and blood have long been used in epidemiological studies as the biomarkers of choice. In fact, total hair mercury （Hg） content as well as organic blood Hg concentrations reflects exposure to organic Hg from food consumption. Extensive studies, establishing a constant and linear relation between MeHg intake versus Hg levels in hair and blood, were conducted by governmental officials to establish guidelines on safe levels of MeHg exposure, which were translated into threshold daily fish consumption rates （usually expressed as μg MeHg per kg bodyweight）. Nowadays, in most epidemiologic studies blood or hair mercury （Hg） level is commonly used as a valid proxy to estimate human exposure to methylmercury （MeHg） through fish consumption without relating this signal to actual fish consumption patterns among populations. Human variability in mercury toxicokinetics was identified and measurement error has been pointed out to be a substantial contributor to observed variability, particularly where dietary information is retrospective and self-reported. However, experimental evidence indicates that significant variability among individuals may exist in the biokinetics of mercury. Also recent findings from previous population-based studies through COMERN initiative also revealed that MeHg metabolic processes might greatly vary across populations. In fact, it is unlikely that the magnitude of the difference measured between observed and expected levels of mercury, given the reported intake, can be entirely explained by laboratory measurement errors or reporting bias.  相似文献   

北极苔原新奥尔松地区的地表辐射特征   总被引：2，自引：0，他引：2       下载免费PDF全文

邓海滨  陆龙骅  卞林根 《极地研究》2006,18(4):254-264

利用我国北极黄河站所在地,德国Koldewey站1993-2003年的资料,对新奥尔松地区的地表辐射特征进行了初步分析。结果表明,由于云的影响,新奥尔松极昼期间的日照百分率仅为32.2%。暖季由于下垫面地表冰雪融化,地表反射率迅速减小,地面吸收辐射和地面有效辐射都迅速增大。全年累计的净辐射为正值;暖季是接受太阳辐射能的主要时段,寒季接受的太阳辐射能极少。虽近10年来新奥尔松地区的气温增加十分显著,但各辐射量的变化趋势不明显。地表辐射实测值与同期NCEP/NCAR相邻格点逐日资料的比较表明,NCEP资料对各辐射项模拟的精度不高。  相似文献   

快速城市化过程中城市土地覆被的时空动态特征     

龚建周  夏北成 《福建地理》2006,(4)

1990~2005年间,是广州市经济快速发展和城市景观变化最大的时期,以同时段TM影像解译得到广州市的土地覆被类型图,从数量结构、空间信息及位置转移和景观等方面,分析了广州市土地覆被的动态特征.数量结构的研究结果显示:在快速城市化过程中广州市的耕地、林地等自然资源的利用程度在加大,自1995年起,这种变化的趋势开始减缓;土地覆被类型之间的信息与位置的转移变化频繁,并且表现出空间位置分异的特征.景观特征指数分析结果表明:广州市城市土地覆被向破碎化方向发展,城市建设用地呈扩展之势.  相似文献   

Climatic characteristics of summer high temperature and assessment methods in the large cities of North China     

ZHANG Shangyin  ZHANG Dekuan  WANG Shourong  SONG Yanling 《地理学报》2006,16(1):13-22

Based on the high temperature data of June to August in 1961-2000 in North China, the high temperature weather processes are investigated, and a more complete data set for severe high temperature processes is created. The climatic characteristics of adverse high temperature weather in Beijing, Tianjin, Shijiazhuang, Jinan and Taiyuan are analyzed respectively. The major features of the East-Asia Subtropical High and Transformed Continental High are discussed. The outcomes indicate that the influence of both East Asia Subtropical High and Transformed Continental High on these weather events varies, by a larger margin, from one city to another over North China and they are also closely related to the relative humidity. It is found that the behaviours of East-Asia Subtropical High and Transformed Continental High are the major important systems that give rise to the summer high temperature weather over the region. Based on these findings, the 5-day, 10-day and monthly assessment models for such high impact events have been developed. The assessment outcomes prove to be useful in assessing severe high-temperature events in major cities of North China.  相似文献   

塔里木盆地东河砂岩沉积和储层特征及综合分析   总被引：21，自引：0，他引：21  

贾进华  张宝民  朱世海  朱运成  李占银 《古地理学报》2006,8(3):339-352

东河砂岩是一套海侵初期的沉积产物，东河砂岩不是一个等时沉积体，相当于晚泥盆世晚期至早石炭世早期沉积，具体沉积时间各地有差异。由于东河砂岩是覆盖广泛的海侵初期沉积，因此具有海侵初期填平补齐的特征，其沉积相决定于海侵的速度、沉积物的供给和海侵前的古地貌。塔北地区受塔北古隆起的阻挡，海水在古隆起周围滞留时间较长，又有较粗粒的物源供给，其沉积产物主要是滨岸海滩沉积；塔中地区由于地形复杂，沉积类型也比较复杂，底部砾岩段有河流相沉积，而块状砂岩段和砂砾岩段有河口湾和滨岸海滩沉积，不同段在成分、分选性和粒级上有较大的差异；而其它低平地区主要是海侵期快速的滨岸和陆架沉积。受沉积因素影响，东河砂岩有效储层的分布具有地域性；除沉积因素外，低的地温梯度和短期的深埋藏是优质储层发育的重要控制因素。  相似文献   

湖南船岭脚锡矿区矿化特征及成因探讨   总被引：2，自引：1，他引：2  

曾永红  王廷江  郑时干  曾志方 《华南地质与矿产》2006,(2):13-17

船岭脚锡矿为南岭锡多金属成矿带的一大型锡矿床。矿化类型较多,以构造蚀变带-矽卡岩复合型、接触带矽卡岩型锡矿为主,分布于中侏罗世姑婆山岩体接触带,且具分带性,自岩体内接触带往外依次为构造蚀变带-矽卡岩复合型、接触带矽卡岩型。矿化与成矿岩体及构造复合等因素密切相关,成矿物质主要来源于岩浆,为一与花岗岩有关的中高温矽卡岩型矿床。  相似文献   

洪山预测区煤层赋存的可能性分析     

尚洪田 《中国煤田地质》2006,18(4):25-26,52

分析了洪山预测区西部洪山岩体地质特征及其向外围扩散的范围和程度，研究了北掌勘查区和焦窑煤矿两邻区煤层受岩浆岩影响的程度，认为洪山岩体对预测区煤系及煤层赋存的影响较小，岩体外围仍有煤系赋存。为下一步找煤指明了方向。  相似文献