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藏南查拉普金矿床载金矿物特征与金的赋存状态 总被引：1，自引：0，他引：1
黄铁矿和毒砂是卡林型和造山型金矿床重要的载金矿物。文章通过电子探针(EPMA)分析研究了藏南查拉普金矿床不同类型黄铁矿和毒砂中Au、As、S、Fe等元素的含量变化和分布规律,发现不同阶段的黄铁矿具有不同的结构特征和元素组成特点。沉积成岩期黄铁矿(Py1)主要呈草莓状、胶状,常构成环带状黄铁矿的核心,其中金的含量最高,显示了金在沉积成岩期的大量富集。热液期早阶段黄铁矿(Py2)主要呈自形-半自形的立方体,与Py1元素(S、Fe、As)组成相近,显示了一定的继承演化关系。热液期主阶段黄铁矿(Py3)与毒砂共生,多呈自形-半自形的五角十二面体、立方体,常包裹早期的黄铁矿形成环带结构。Py3中As的含量明显升高,其增加量近似等于S的减少量,说明As主要进入黄铁矿晶格替代了S的位置。各个阶段的黄铁矿和毒砂中Au的分布在EPMA微束的分辨率下均显示是不均匀的,Au在Py1和大部分Py2中主要以纳米级自然金(Au0)的形式存在;而在Py3中主要以(Au+)的形式存在,少部分以纳米级自然金(Au0)形式存在。Py1的结构及元素组成与典型卡林型金矿和造山型金矿沉积成岩期黄铁矿的特点相似,而Py3的大量发育则符合卡林型金矿的特征。 相似文献
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对巴隆岩金矿成矿地质背景、矿体特征、矿石特征及其控矿因素等进行分析研究。认为区内矿体与NWW向断裂关系密切,NWW向昆中主断裂为矿床的导矿构造,NWW向F1断裂为矿床的配矿构造,矿区内F2,F3,F4,F5等NWW向次级断裂为矿床的容矿构造;尤其是在拐弯或膨胀处;强烈的印支期岩浆活动,剧烈的构造运动为金元素的活化、迁移、富集、沉淀提供了通道和成矿空间;矿石类型主要为构造蚀变岩型;重砂矿物标志、地貌标志、颜色标志、气味标志、化探异常标志等是该区的主要找矿标志。结合区域上成矿背景分析认为该矿区有着良好的找矿前景,并建议对矿床深部及外围做进一步工作。 相似文献
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含金矿物中金及微量元素的质子探针分析 总被引：3，自引：0，他引：3
利用质子探针对黄铁矿、毒砂、人工合成矿物中的Ａｕ、Ｃｒ、Ｍｎ、Ｃｕ、Ａｓ、Ｐｂ微量元素进行了分析,实验表明,质子探针微区分析技术可测定痕量金及其它微量元素;不同矿物中金的检出限不同,黄铁矿中Ａｕ的检出限３μｇ／ｇ,毒砂中Ａｕ的检出限为３０μｇ／ｇ。 相似文献
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Arsenopyrite is one of very important and common auriferous minerals in endogenetic gold deposits. In seven gold deposits, the prospecting typomorphic characteristics of arsenopyrite, such as morphological typomorphism, composition typomorphism, pyroelectricity typomorphism and so on, were established. The crystal form of arsenopyrite is simple, and the form symbols mainly are {101}, {120}, {210}, {140}, {230}, {012}, etc. The smaller groin and poor crystal form arsenopyrite indicates the better auriferous characteristics. The major elements (Fe, As and S) of gold- bearing arsenopyrite usually show Fe/As + S ＞ 0.5, As/S＜ 1 which deviates from its theoretical value. The most important trace element is Au and next is Ag in arsenopyrite, and they often show the positive correlation. The pyroelectricity of arsenopyrite can reflect the mineralization epoch, and it also is related to the crystal form and granudarity. 相似文献
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Abstract Fluids with compositions in the system CO2 -H2 O-NaCl were trapped in quartz veins enclosed in low-grade metamorphic rocks (chlorite zone) on the southern flank of the Canigó Massif, eastern Pyrenees. The veins, which also contain arsenopyrite crystals, were formed contemporaneously with the main Hercynian foliation and metamorphism. Volumetric properties of the fluid and the results of arsenopyrite geothermometry suggest P-T trapping conditions of 4.6–6 kbar and 450–530° C. This implies that an episode of metamorphism with an average geothermal gradient of 25° C km−1 occurred during the main deformation event. This episode preceded the low- P /high- T metamorphism described around domes and to date considered as characteristic of the Hercynian orogeny in the Pyrenees. 相似文献
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通过系统的显微镜鉴定及扫描电镜观察,将黔西南普安泥堡金矿床中的黄铁矿按形貌特征划分为6种类型,即立方体状、草莓状、细粒状、粗粒状、环带状及长条状黄铁矿。黄铁矿电子探针分析结果表明,主要载金矿物为含砷黄铁矿(环带状黄铁矿、细粒状黄铁矿)和毒砂。环带状黄铁矿核部和环带形成于不同的成岩、成矿阶段,其核部贫Au、As,富Fe、S,属成岩期的产物;环带富Au、As,贫Fe、S,形成于主成矿期。黄铁矿环带中Au与As具有正对应关系,在一定的楔形空间呈正相关,高Au含量往往与中等As含量(2%~6%)相对应;而As与S呈明显负相关,说明富砷环带是As取代S而进入黄铁矿晶格所致。细粒状黄铁矿具有高Au、As,低Fe、S的特点,类似于环带状黄铁矿环带部位的特征,推测富As环带与细粒状黄铁矿同属主成矿阶段的产物。毒砂常穿插或沿含砷黄铁矿边缘分布,表明其形成晚于热液期含砷黄铁矿。因此,泥堡金矿床中载金矿物的结晶顺序大致为:贫砷沉积成因黄铁矿(核部)→富砷黄铁矿环带和细粒状黄铁矿→毒砂。电子探针点分析和面波普扫描显示,Au在载金矿物含砷黄铁矿和毒砂中具有不均匀分布的特征,根据Au的溶解度极限(Au/As 0.02)和lgw(As)—lgw(Au)图解,推测Au主要以"不可见"固溶体(Au~(+1))形式赋存于含砷黄铁矿和毒砂中,极少量可能为纳米级自然金(Au~0)。 相似文献
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次显微金在毒砂,黄铁矿等矿物中富集的成因研究 总被引：7，自引：0，他引：7
本文详细探讨了次显微金在毒砂、黄铁矿等矿物中富集的成因机制，指出这些矿物生长时生长面附近出现的氧化还原电位局部降低和（或）（ＡｓＳ）３－，Ｓ２－等组分的局部负异常会导致金的络合物变得不稳定和易于分解，从而引起次显微金在这些矿物中富集。由此笔者解释了次显微金龙富集于小颗粒的毒砂、黄铁矿中及特别富集于这些矿物边缘的原因。同时笔者认为普遍呈小圆球形态出现于载金矿物中的金颗粒可能是金胶体沉聚下来形成的。文中还对黄铁矿含Ａｕ量与含Ａｓ量之间具正相关关系以及黄铁矿和黄铜矿的含Ａｕ量在不同矿床中互有高低的原因予以了解释 相似文献
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Mohamed ABD EL MONSEF 《《地质学报》英文版》2020,94(5):1451-1470
Gold-silver deposits in the Atalla area occur as hydrothermal quartz veins in NE–SW pre-existing fractures within the Atalla granitic pluton. The orientation of such quartz veins has been attributed to extensional behavior related to the Atalla Shear Zone (ASZ). The Atalla area is covered by a variety of lithologies that are (from oldest to youngest): metasedimentary rocks, metavolcanic rocks, ophiolite assemblage (serpentinites/talc-carbonates), Atalla granite and Dokhan volcanic rocks. Microscopically, Atalla granite ranges in composition from granodiorite to monzogranite. Whole-rock geochemistry constrains the calc-alkaine affinity of the Atalla granite that was intruded within an orogenic (syn-collision) tectonic regime. The ore minerals are represented by gold/silver (electrum), pyrite (Py1 & Py2), arsenopyrite, pyrrhotite, sphalerite, chalcopyrite, galena, covellite and goethite. The temperature of ore formation ranges from 240 to 285°C and the estimated fluid pressure is in the range of 20–100 MPa. Based on the geological setting, ore textures and fluid characteristics; the Atalla Au-Ag deposits are considered to be orogenic in nature, formed from a continental collision (~653-590 Ma), synchronous with the emplacement of calc-alkaline magmatism during the evolutionary history of the Arabian Nubian Shield (ANS). The initial ore-forming fluid was primarily derived from a metamorphic source related to ophiolitic-serpentinite rocks under deep regional conditions of greenschist-amphibolite facies, where the Atalla granitic eruption provided the required temperature conditions for the metamorphic process to take place. Under such conditions, the transportation of ore metals as bisulfide complexes is favoured. The deposition of ore minerals was triggered by fluid-wallrock interaction through fracture pathways in conjunction with a temperature-pressure drop that is likely to have been related to uplift into the crustal levels. 相似文献