西秦岭温泉斑岩钼矿床岩浆-热液演化   总被引：5，自引：3，他引：2  

邱昆峰  宋开瑞  宋耀辉 《岩石学报》2015,31(11):3391-3404

西秦岭北缘广泛出露印支期中酸性侵入岩和相关的斑岩-矽卡岩矿床。温泉矿床位于该矿带东段,是其内已探明规模最大的斑岩钼矿床。温泉矿床发育多阶段热液脉体,黄铁矿作为其中的贯通性金属硫化物,其化学组成蕴含着岩浆-热液演化及金属沉淀过程等诸多信息,对于斑岩系统模型的厘定具有重要意义。温泉矿床热液脉体时序为:钾长石-黑云母-石英脉(A脉)、石英-黄铜矿脉、石英-辉钼矿脉(B脉)和石英-绢云母-黄铁矿脉(D脉)。A脉是斑岩系统岩浆-热液演化的最早期脉体,主要矿物组合为钾长石+黑云母+石英+黄铁矿±磁铁矿±磷灰石±黄铜矿,代表了引起早期基性岩浆矿物被蚀变为黑云母的流体通道;B脉与钾长石化蚀变关系密切,围岩中斜长石斑晶大量被蚀变为钾长石;石英-辉钼矿脉切割所有早期黑云母化-钾化蚀变阶段的石英-硫化物网脉,并形成于所有斑岩侵位之后,少量黄铁矿和黄铜矿共生于辉钼矿裂隙及边部;D脉是斑岩系统岩浆-热液成矿作用的最晚期事件,其主要被黄铁矿和石英及少量黄铜矿填充,发育晚期的绢英岩化和泥化蚀变,长石多发生破坏性蚀变。四个阶段石英网脉中黄铁矿电子探针分析显示,A脉的黄铁矿中Cu、Mo和Au含量均较低,有少量的金属硫化物(黄铁矿+黄铜矿)沉淀,但通常不能形成规模矿体;石英-黄铜矿脉的黄铁矿中Cu含量明显较高,且多与高品位Cu矿体的空间产出位置相一致,可能是斑岩系统伴随钾化蚀变作用主要的铜沉淀阶段;B脉的黄铁矿中Mo含量明显较高,与高品位钼矿体空间产出关系密切,可能代表了斑岩系统钼成矿作用的主要阶段;D脉的黄铁矿中Au含量明显升高,可能代表了金在斑岩系统岩浆-热液成矿作用的最晚期事件中的沉淀。  相似文献   

Determination of allowable subgrade frost heave with the pavement roughness index in numerical analysis     

HongYan M  Feng Zhang  DeCheng Feng  Bo Lin 《寒旱区科学》2015,7(5):587-593

Frost heave is an upward swelling of soil during cryogenic conditions in cold regions. It is caused by the accumulation of ice crystals in subgrade soil, which grow upwards when freezing temperatures penetrate into the subgrade. This study establishes the allowable soil subgrade frost heave based on the roughness standard of asphalt pavement in China, and aims to balance the pavement design and frost heave resistance of subgrades in cold regions. We formulated a mechanical model of pavement supported by the boundary conditions of differential frost heave, based on the elastic layered system theory. The differential soil subgrade frost heave was modeled as a sinusoidal function, and the allowable frost heave and the roughness index were modeled as the displacement boundaries for the top and bottom of the pavement structure. Then the allowable frost heave was back-calculated according to the roughness standard. Numerical results show that the allowable frost heave depends on the pavement structure, material properties, the highway grade, and other factors. In order to ensure that the actual soil subgrade frost heave is lower than the allowable frost heave, pavement structures and materials need to be selected and designed carefully. The numerical method proposed here can be applied to establish the frost heave resistance of subgrade when the pavement structure and materials are determined.  相似文献   

A range of fault slip styles on progressively misoriented planes during flexural-slip folding,Cape Fold Belt,South Africa     

《Journal of Structural Geology》2015

Flexural slip folds are distinctive of mixed continuous-discontinuous deformation in the upper crust, as folding is accommodated by continuous bending of layers and localized, discontinuous slip along layer interfaces. The mechanism of localized, layer-parallel slip and the stress and fluid pressure conditions at which flexural slip occurs are therefore distinctive of shear localization during distributed deformation. In the Prince Albert Formation mudstone sequence of the Karoo Basin, the foreland basin to the Cape Fold Belt, folds are well developed and associated with incrementally developed bedding-parallel quartz veins with slickenfibers oriented perpendicular to fold hinge lines, locally cross-cutting axial planar cleavage, and showing hanging wall motion toward the fold hinge. Bedding-parallel slickenfiber-coated veins dip at angles from 18° to 83°, implying that late increments of bedding-parallel shear occurred along unfavorably oriented planes. The local presence of tensile veins, in mutually cross-cutting relationship with bedding-parallel, slickenfiber-coated veins, indicate local fluid pressures in excess of the least compressive stress.Slickenfiber vein microstructures include a range of quartz morphologies, dominantly blocky to elongate-blocky, but in places euhedral to subhedral; the veins are commonly laminated, with layers of quartz separated by bedding-parallel slip surfaces characterized by a quartz-phyllosilicate cataclasite. Crack-seal bands imply incremental slickenfiber growth, in increments from tens of micrometers to a few millimeters, in some places, whereas other vein layers lack evidence for incremental growth and likely formed in single slip events. Single slip events, however, also involved quartz growth into open space, and are inferred to have formed by stick-slip faulting. Overall, therefore, flexural slip in this location involved bedding-parallel faulting, along progressively misoriented weak planes, with a range of slip increments.  相似文献   

Structurally controlled fluid flow associated with breccia vein formation     

R. K. VALENTA  I. CARTWRIGHT  N. H. S. OLIVER 《Journal of Metamorphic Geology》1994,12(2):197-206

A breccia vein sampled from a shear zone in greenschist facies metapelites at Mount Isa, Queensland, Australia, shows a systematic variation in vein geometry that is related to the geometry of folding and faulting within the sample. Calcite vein-fill is coarse grained and equigranular, suggesting precipitation in a fluid-filled space. Partially folded veins suggest that veining occurred during folding and faulting. The breccia vein contains a central zone in which dilation has occurred simultaneously in all directions in the plane of section, implying that this was a zone of high fluid pressure and nearly isostatic differential stress during folding and faulting. From these observations, it can be inferred that the breccia vein was a zone of high permeability and a likely fluid channel during deformation. This hypothesis was tested by stable isotope analysis of veins and host rocks. The calcite veins have δ¹³C values of -11.1 ± 0.1% and δ¹⁸O values of 6-10%_o, whereas the host metapelite has δ¹³C values of -10.62 and -10.11% and δ¹⁸O values of 14-15%_o. These values are consistent with an igneous-derived, H₂O-dominated fluid that exchanged little oxygen with the host rocks, but derived much of its carbon from the wall rock. The isotopic disequilibrium between the veins and the wall rock confirms that the fluid was externally derived, and that the breccia vein acted as a channel for large-volume fluid flow within the shear zone.  相似文献   

Geological, mineralogical and geochemical characteristics of the Radzimowice Au–As–Cu deposit from the Kaczawa Mountains (Western Sudetes, Poland): an example of the transition of porphyry and epithermal style     

Stanislaw Z. Mikulski 《Mineralium Deposita》2005,39(8):904-920

The sheeted quartz–sulfide veins of the Radzimowice Au–As–Cu deposit in the Kaczawa Mountains are related to Upper Carboniferous post-collisional potassic magmatism of the composite Zelezniak porphyry intrusion. Multiple intrusive activity ranges from early calc-alkaline to sub-alkaline and alkaline rocks and is followed by multiple hydrothermal events. Early crustally derived dacitic magma has low mg# (<63) and very low concentrations of mantle-compatible trace elements, high large-ion lithophile elements (LILE), moderate light rare-earth elements (LREE), and low high-field-strength elements (HFSE). Later phases of more alkaline rocks have higher mg# (60–70), and LILE, LREE, and HFSE characteristics that indicate mafic magma contributions in a felsic magma chamber. The last episode of the magmatic evolution is represented by lamprophyre dikes which pre-date ore mineralization and are spatially related to quartz–sulfide–carbonate veins. The dikes consist of kersantite and spessartite of calc-alkaline affinity with K₂O/Na₂O ratios of 1.1–1.9, mg# of 77–79, and high abundances of mantle-compatible trace elements such as Cr, Ni, and V. They have high LILE, low LREE, and low HFSE contents suggesting a subduction-related post-collisional arc-setting. The mineralization started with arsenopyrite that was strongly brecciated and overprinted by multiple quartz–carbonate phases associated with base-metal sulfides and Au–Ag–Bi–Te–Pb±S minerals. The sulfur isotope composition of sulfides ranges from –1.1 to 2.8 ³⁴S and suggests a magmatic source. At least two generations of gold deposition are recognized: (1) early refractory, and (2) subsequent non-refractory gold mineralization of epithermal style. Co-rich arsenopyrite with refractory gold and pyrite are the most abundant minerals of the early stage of sulfide precipitation. Early arsenopyrite formed at 535–345°C along the arsenopyrite–pyrrhotite–loellingite buffer and late arsenopyrite crystallized below 370°C along the arsenopyrite–pyrite buffer. Non-refractory gold associated with base-metal sulfides and with Bi–Te–Ag–Pb–S mineral assemblages has an average fineness of about 685, and is represented by electrum of two generations, and minor maldonite (Au₂Bi). Fluid inclusions from various quartz generations co-genetic with base-metal sulfides and associated with carbonates, tellurides and non-refractory gold indicate fluids with moderate salinity (9–15 wt% NaCl equiv.) and a temperature and pressure drop from 350 to 190°C and 1.2 to 0.8 kbar, respectively. According to the result of the sulfur isotope fractionation geothermometer the temperature of base-metal crystallization was in the range from 322 to 289°C. Preliminary results of oxygen isotope studies of quartz from veins indicate a gradual increase in the proportion of meteoric water in the epithermal stage. The gold to silver ratio in ore samples with >3 ppm Au is about 1:5 (geometric mean). Hydrothermal alteration started with sericitization, pyritization, and kaolinitization in vein selvages followed by alkaline hydrothermal alteration of propylitic character (illitization and chloritization), albitization and carbonatization. The mineralization of the Radzimowice deposit is considered as related to alkaline magmatism and is characterized by the superposition of low-sulfidation epithermal mineralization on higher-temperature and deeper-seated mesothermal/porphyry style.Editorial handling: B. Lehmann  相似文献   

Gas formation mechanism of marine carbonate source rocks in China   总被引：5，自引：1，他引：4  

ZHAO Wenzhi  WANG Zhaoyun  HE Haiqing  ZHANG Mingjie  WANG Hongjun  WANG Yunpeng & QIN Yong . Research Institute of Petroleum Exploration & Development  PetroChina  Beijing  China  . PetroChina Exploration & Production  Beijing  China  . Department of Geology  Lanzhou University  Lanzhou  China  . Guangzhou Geochemical Institute  Chinese Academy of Sciences  Guangzhou  China  . China University of Mining  Technology  Xuzhou  China 《中国科学D辑(英文版)》2005,48(4):441-453

It has been proven in exploration practice that thecarbonates in China not only can generate hydrocar-bons, but also form commercial reservoirs. The car-bonates are different from clastic rocks in view of theirdeposition environment as well as their sedimentaryand diagenetic processes. Therefore, the evaluationcriteria and hydrocarbon generation mechanism forcarbonates can not be the same as that for clasticrocks, and it is important to establish a special hydro-carbon generation mechanism and…  相似文献   

Fluid inclusion studies of the Abawso gold prospect,near the Ashanti Belt,Ghana   总被引：1，自引：0，他引：1  

Sven?E.?WilleEmail author  Reiner?Klemd 《Mineralium Deposita》2004,39(1):31-45

The major Ghanaian lode gold deposits are preferentially aligned along the western and eastern contacts of the Kumasi Basin with the Ashanti and Sefwi Belts, respectively. The investigated area of the Abawso small-scale concession, covering the workings of the old Ettadom mine, is situated 3 km west of the lithological contact of the Birimian metavolcanic rocks of the Akropong Belt in the east with the Birimian metasedimentary rocks of the Kumasi Basin in the west. The rocks of the Abawso concession represent a steeply NW-dipping limb of a SE-verging anticline with an axis plunging to the SW. Quartz veining occurs predominantly in the form of en échelon dilatational veins along NNE–SSW-striking shear zones of a few metres width and shows evidence of brittle and ductile deformation. Also stockwork-style quartz veining occurs in the vicinity of the main shaft of the old Ettadom mine. Hydrothermal alteration includes sericitisation, sulphidation and locally carbonatisation. The auriferous quartz veins mainly follow the trend of brittle to ductile deformed quartz veins; however, some occur in stockwork. Fluid inclusion studies reveal a large number of H₂O inclusions along intragranular trails in auriferous quartz vein samples, as well as an overall dominance of H₂O and H₂O-CO₂ inclusions over CO₂ inclusions. Textural observations and physico-chemical fluid inclusion properties indicate post-entrapment modifications for all quartz vein samples due to grain boundary migration recrystallisation. This process is interpreted to be responsible for the generation of the CO₂ inclusions from a H₂O-CO₂ parent fluid. In comparison with mineralisation at the Ashanti and Prestea deposits, which are characterised by CO₂±N₂ inclusions, the observed inclusion assemblage may be due to a shallower crustal level of mineralisation, or different degrees and styles of recrystallisation, or a less pronounced development of laminated quartz veins due to comparably restricted pressure fluctuations. Furthermore, the microthermometric observations allow the reconstruction of a possible retrograde P-T path, depicting near-isothermal decompression in the P-T range of the brittle/ductile transition.Editorial handling: E. Frimmel  相似文献   

沥青实验与评价方法综述     

张海涛  潘勇  夏振雪 《海岸工程》2004,23(1):73-82

通过对常规沥青试验与评价方法和美国SHRP沥青路用性能规范(AASHTO MP1)的分析和比较,认为现阶段采用常规沥青试验与评价方法结合SHRP规范将是沥青质量控制与评价最有效的手段。  相似文献   

The Greening of Baltimore's Asphalt Schoolyards          下载免费PDF全文

Geoffrey L. Buckley  Christopher G. Boone  J. Morgan Grove 《Geographical review》2017,107(3):516-535

Asphalt was becoming an integral part of the urban American landscape by the end of the nineteenth century. Not only was it emerging as the preferred alternative for street paving, its promoters were endorsing it for other purposes as well. Although Baltimore was not in the vanguard when it came to adopting asphalt for road surfaces, it soon followed the trend. Like other cities, it too found other applications for this versatile petroleum product, including the paving of playgrounds and schoolyards. Despite low maintenance costs, widespread use of asphalt as a recreational surface started to meet resistance in Baltimore during the 1960s. Fifty years later, stringent storm‐water runoff requirements are causing city officials to rethink how they deploy asphalt in an urban setting. In an effort to meet these new requirements, while at the same time improve recreational opportunities for school children, an alliance of government agencies, nonprofit organizations, and private developers has developed a strategy to remove asphalt from schoolyards—one that may serve as a model for other cities facing financial and sustainability challenges similar to those of Baltimore.  相似文献   

Laboratory and field performance of recycled aggregate base in a seasonally cold region     

Tuncer B. Edil  Bora Cetin  Ali Soleimanbeigi 《寒旱区科学》2017,9(3):183-191

The objective of this project was to characterize the freeze-thaw properties of recycled concrete (RCA) and asphalt (RAP) as unbound base and to assess how they behaved in the field for nearly 8 years. This paper includes an examination of existing information, laboratory studies of freeze-thaw behavior, and evaluation of data from MnROAD field-test sections in a seasonally cold region, i.e., in Minnesota, USA. Test sections were constructed using recycled materials in the granular base layers at the MnROAD test facility. One test section included 100% RAP, another 100% RCA, a third one a 50/50 blend of RCA/natural aggregate, and a fourth one only natural aggregate (Class 5) as a control. The stiffness (i.e., elastic modulus) was monitored during construction and throughout the pavement life by the Minnesota Department of Transportation, along with the variation of temperatures and moisture regimes in the pavement to determine their effects on pavement performance. The resilient modulus of each material was determined by bench-scale testing in accordance with NCHRP 1-28a, as well as by field-scale tests incorporating a falling-weight deflectometer. Specimens were subjected to as many as 20 cycles of freeze-thaw in the laboratory, and the change in their resilient modulus was measured. In the field-test sections constructed with the same materials as the base course, temperature, moisture, and field modulus (from falling-weight deflectometer tests) were monitored seasonally for nearly 8 years. From the temperatures in the base course layer, the number of freeze-thaw cycles experienced in the field was determined for each test section. Inferences were made relative to modulus change versus freeze-thaw cycles. Conclusions were drawn for long-term field performances of the recycled base (RAB) in comparison to natural aggregate.  相似文献