滇西澜沧黑河地区超高压变质岩中金红石微量元素特征     

吕伟 《地质与勘探》2023,59(6):1260-1270

为研究黑河地区金红石微量元素特征及榴辉岩型金红石矿床的成矿地质条件,本文选取滇西澜沧黑河地区榴辉岩、石榴多硅白云母片岩中的金红石进行LA-ICP-MS微量元素分析。结果表明金红石微量元素呈现阶梯式三级分布特征,最富集Nb、Ta,其次是Zr、Hf,含量较少的元素有Ba、Rb、Sr、Th、REE;榴辉岩、榴闪岩类原岩属于变质基性岩类,含蓝晶石榴闪岩原岩属于玄武质凝灰岩类,石榴多硅白云母片岩类原岩属于泥质岩类;榴辉岩中金红石Nb/Ta比值均要高于其全岩Nb/Ta比值,金红石Nb、Ta含量与变质作用过程中元素在各矿物间的分配系数有关;采用金红石Zr含量温度计获得黑河地区榴辉岩的峰期变质阶段金红石形成温度为578～605℃,峰期变质作用后的退变质流体会造成金红石中Zr的再平衡。此外,黑河地区具备榴辉岩型金红石矿床形成的成矿物源、成矿作用的物理化学条件以及成矿的物质基础,有一定的找矿潜力。  相似文献   

中国萤石矿床分类及稀土元素地球化学特征     

刘道荣 《地质与勘探》2023,59(2):211-222

中国萤石资源丰富,矿床数量众多,但尚无统一的分类标准。在总结现有萤石矿床分类基础上,以成矿热液来源为依据,将单一型萤石矿床划分为岩浆期后热液型、火山-次火山热液型及热卤水型3种,并介绍了各类萤石矿床的主要地质特征。结合已有文献资料,总结归纳各类型萤石矿床的稀土元素组成特征,探讨了成矿热液演化过程。岩浆期后热液型矿床萤石具有较高的稀土总量(∑REE均值约70×10^-6)、较显著的铕负异常(δEu峰值在0.6～0.7)和较小的Y/Ho比值(主要变化范围30～65);火山-次火山热液型矿床萤石稀土总量与岩浆期后热液型接近,但具有显著的铕负异常或弱-中等的铕正异常(δEu峰值分别在0.1～0.2和1.1～1.2)和较小的Y/Ho比值(集中在40～50);热卤水型矿床萤石具有较低的稀土总量、显著的铕正异常(平均δEu>2)及较大的Y/Ho比值(均值约83)。与岩浆期后热液型和火山-次火山热液型矿床相比,热卤水型矿床的成矿流体可能经历了更复杂的演化过程。  相似文献   

Reconstruction of the Yangtze Ramp during Floian to Darriwilian (Ordovician) in South China: Its Morphology, Controlling Factors and Significances     

LUAN Xiaocong  André DESROCHERS  WU Rongchang  LIU Jianbo  WANG Guangxu  LIANG Yan  ZHANG Yuchen  WEI Xin  LI Lixi  ZHAN Renbin 《《地质学报》英文版》2023,97(6):1756-1777

A robust stratigraphic framework and a coherent depositional ramp model for the Zitai, Dawan, Meitan and Ningkuo formations of Floian–Darriwilian age (Early–Middle Ordovician) in the Yangtze (Daoba, Xiangshuidong, Daling, Gudongkou and Honghuayuan sections) and Jiangnan regions (Nanba section) was created based on lithofacies and major element analysis. Three siliciclastic (LF1–3) and six carbonate (LF4–9) lithofacies are recognized representing sediments that were deposited in mixed siliciclastic and carbonate ramp environment. The intensity of mixed sedimentation and terrigenous input were evaluated using the elemental proxies Intensity of Mixed sedimentation (IM) and Aluminum Accumulation Rate (AlAR), as well as their mean values during certain time intervals. Mixed sediments are most well-developed along the marginal Yangtze region, strongly impacted by recurrent influx of westerly derived terrigenous materials in response to global eustatic changes and regional tectonic movements, shaping the gently southeast-dipping morphology. Regular terrigenous influx resulted in periods of enhanced primary productivity on the Yangtze Ramp as evidenced by matching biodiversity peaks in planktonic organisms, i.e., chitinozoans and acritarchs. Brachiopods and other shelly fauna were also able to proliferate as new niches developed along the gently dipping ramp floor with substrate changes. The biodiversification patterns suggest that terrigenous influx controlled in part by regional tectonics played a more important role than previously thought in the development of Great Ordovician Biodiversification Event in South China.  相似文献   

Deformation induced decoupling between U-Pb and trace elements in titanite revealed through petrochronology and study of localized deformation     

《地学前缘(英文版)》2023,14(2):101496

In this contribution, we analyzed a pair of mafic samples collected from a recently identified shear zone and its proximal footwall from the Manicouagan Imbricate Zone (MIZ) of the central Grenville Province, Québec, Canada. Titanite petrochronology, metamorphic phase equilibria modelling, trace element thermometry, and electron backscattered diffraction data were used to define a Pressure-Temperature-time-Deformation path for the two samples. An interconnected dislocation network within titanite grains, as outlined with Kerneled Average Misorientation maps, are spatially correlated with variation in the U-Pb system but not with that observed for trace element These results suggest that the U-Pb system was decoupled from trace and rare earth elements and that deformation, rather than interface-coupled dissolution-precipitation reactions or re-crystallisation, was the main driver for this decoupling. In addition to highlighting a potential pitfall of titanite petrochronology, our P-T-t-D path reveals that ductile shear zones were active later than previously suggested within the MIZ.  相似文献   

New insights into the multiple magmatic fluid generations from scheelite in the Bastielieke W-polymetallic deposit,Chinese Altay (NW,China)     

《地学前缘(英文版)》2023,14(3):101532

Scheelite is the main ore mineral in skarn-type tungsten (W-Mo, W-Sn, and W-Cu) deposits, and is also a good proxy for ore-fluid evolution and mineralization. The Bastielieke deposit is the first medium-size W-polymetallic skarn deposit discovered in the Chinese (Xinjiang, NW China) Altay. Scheelite grains at Bastielieke are distributed in biotite granite, skarn and quartz-fluorite veins. They exhibit different textures, and can be divided into four types and six subtypes, including those in granite (Schm), prograde skarn (SchI), retrograde-altered rocks (SchII), and those in late-stage quartz-fluorite veins (SchIII).SchIa and SchIb were formed in the early and late prograde stage, respectively. SchI displays homogeneous texture, enrichments of light rare earth elements (LREEs) relative to heavy REEs (HREEs), and significantly negative Eu anomalies. SchIa has higher Sr-Mo contents and LREE/HREE than SchIb. SchII shows patchy texture by overgrowth and dissolution-reprecipitation, and can be subdivided into dark (SchIIa) and light (SchIIb) zone based in CL imaging. All SchII grains are LREE-enriched with negative Eu anomalies and relatively low LREE/HREE ratios. SchIIb has much higher W-Mo-Nb-Sr contents than SchIIa, which is ascribed to late-stage hydrothermal modifications. Schm and SchIII display homogeneous texture and similar MREE-enriched patterns, as well as very low Mo-W-Sr and different Nb contents.The texture and compositional variations in Bastielieke scheelites reveal that two magmatic fluids derived from different granitic magma reservoirs were involved in the mineralization. The earlier ore-fluid is relativly oxidized and has low HREE contents, forming the early prograde skarn-stage mineralization. Episodic influxes of later F-rich granitic magmatic fluids may have modified the earlier scheelite compositions, leading to multistage W enrichment and varying intragrain compositions.  相似文献   

2016年冬季京津冀豫大气污染的时空分布及影响因子研究     

江琪  王飞  张恒德  吕梦瑶  何佳宝 《气象》2019,45(5):695-704

利用2016年12月至2017年2月北京、天津、石家庄和郑州的PM2.5质量浓度、反应性气体质量浓度及其相对应的气象要素资料分析了大气污染的理化特征、传输和生消规律。结果表明:北京、石家庄、天津及郑州的PM2.5质量浓度分布频率均有两个较为明显的峰值,四个地区PM2.5质量浓度分布频率最高时均值分别为10.1、19.2、40.0和47.1μg·m^-3,大气的氧化程度为北京最低,其次为石家庄、天津,郑州最高。四个研究地区的交通源对环境大气污染均有重要贡献。PM2.5和CO的相关性在低相对湿度时高于高相对湿度时;而PM2.5和NO2的相关性在相对湿度较大时高于相对湿度较小时。四个研究地区的PM2.5质量浓度均随风速的增大呈快速降低后趋于平缓的趋势,其中北京、石家庄和郑州的风速阈值均为3m·s^-1,天津地区为4m·s^-1。受上游污染地区的影响,偏南风的输送作用滞后20~30h达到最大,而偏北风的影响作用在滞后8~12h达到最大。  相似文献   

黔西北普宜地区下三叠统嘉陵江组沉凝灰岩锆石LA- ICP- MS U- Pb年龄、微量元素特征     

缪宇  吴亮  肖长源  李锁明  李致伟  宋文婷  田瑜峰 《地质论评》2021,67(1):67020002-67020002

早三叠世时期频繁的火山事件是导致全球性气候和海洋环境异常的主要原因,前人对早三叠世重要界线时期的火山事件地层开展了大量研究,但对典型界线时期以外的其他火山事件地层却鲜有报道。本文以上扬子西南普宜地区嘉陵江组两件沉凝灰岩为研究对象开展了岩石学、岩相学、锆石年代学及微量元素组合特征等方面的研究。沉凝灰岩样品具有典型岩浆锆石的内部结构和微量元素组合特征,两组沉凝灰岩锆石谐和年龄分别为250. 6±0. 6 Ma和249. 1±0. 8 Ma,代表了母岩岩浆中新生锆石的结晶年龄。沉凝灰岩母岩主要以酸性花岗岩类为主,次为中性正长岩类和少量基性岩类。嘉陵江组沉凝灰岩与二叠系—三叠系界线(PTB)凝灰岩及Olenekian—Anisian界线(OAB)绿豆岩具有同源性,形成于活动大陆边缘的碰撞造山环境,源区很可能位于中越边境地区长山构造岩浆带—十万大山火山带,且在陆壳碰撞过程中源区地壳处于持续的增厚阶段,下地壳增厚部位的部分熔融形成补给岩浆上涌并使早期结晶矿物发生了部分熔蚀。本文嘉陵江组沉凝灰岩样品250. 6±0. 6 Ma年龄对应着Smithian—Spathian界线时期的全球性降温及短期生物复苏事件;249. 1±0. 8 Ma年龄的样品对应Spathian亚阶中期极端高温气候和生物再次灭绝事件,再次证明了早三叠世时期频繁的火山活动是导致气候改变和生物周而复始新生和灭绝的重要因素。其原因可能是阳伞效应和温室效应等因素综合反馈的结果,但具体证据仍需要将来更多学科综合研究成果的约束。  相似文献   

扬子北缘奥陶纪—志留纪之交泥岩地球化学特征及其源区、构造背景     

刘春来  熊国庆  董国明  崔伟 《地质论评》2021,67(3):67040002-67040002

近年来,扬子地块北缘奥陶纪—志留纪之交沉积构造背景一直存在不同认识。本文对渝东北城口厚坪五峰组—龙马溪组砂、泥岩进行系统采样和主、微量元素测试分析,从地球化学特征角度,来探讨该时期砂、泥岩物源源区及其构造环境。地球化学特征显示,五峰组—龙马溪组砂、泥岩主量元素SiO2含量为39.57%～87.16%,多数高于北美页岩,Al2O3含量为3.41%～14.98%,均低于北美页岩,MgO、CaO、MnO2和P2O5含量明显低于北美页岩,相比于四川盆地川南长宁—双河五峰组—龙马溪组泥岩,渝东北城口具有高SiO2和低MgO、CaO的特点,表明城口五峰组—龙马溪组泥岩碎屑组分主要以粉砂质和硅质等陆缘碎屑为主;微量元素Sc、Sr、Co、Zr、Hf较北美页岩相对亏损,V、U、Sb、Ba相对富集,Cr、Ni、Nb、Ta含量相近。稀土元素北美页岩标准化均表现为略微向右倾斜的配分模式,多数具有δCe负异常,观音桥段和龙马溪组δEu正异常指示了该时期存在海底热液活动。砂、泥岩主、微量元素的物源和构造背景图解表明沉积物源区源岩具有多样的物质组分,以长英质岩为主,同时混入了花岗质和安山质岩石组分;源岩形成时的构造背景主要为被动陆缘环境,少数为活动陆缘和大陆岛弧环境,这一结果与扬子地块北缘新元古代—早古生代处于被动大陆边缘的区域地质背景一致。  相似文献   

胶东夏甸金矿床地球化学特征及其地质意义     

李逸凡  李洪奎  陈国栋  张玉波  陈莉  梁太涛 《地质学报》2021,95(6):1822-1842

为探讨夏甸金矿床不同元素的地球化学成矿行为,本次以夏甸金矿床外围花岗岩、构造碎裂岩和金矿石的主微量和稀土元素地球化学资料为依据,研究其化学成分、微量元素和稀土元素在不同岩矿石中丰减富集变化及成矿过程.在化学成分方面,招平断裂带碎裂岩中具有较高的SiO2、K2 O值,Fe2 O3、Na2 O、CaO降幅较多,反映了成矿阶段存在有普遍的硅化现象和钾化现象和铁质流失现象进入到热液成矿中;矿石化学成分中SiO2、Al2 O3和Fe2 O3具有较大幅度的增升和降低的双重变化特点,尤其是铁、钾、钙增加比例较高,指示与成矿过程中普遍发育的黄铁矿化相一致,矿石中K2 O含量比玲珑花岗岩平均含量高30％,则代表钾化的岩石更有利于金矿的沉淀.夏甸金矿区的围岩中Au元素含量普遍低于正常的玲珑花岗岩,但Ag、W等元素含量则普遍较高,是平均值的3～10倍,断裂带碎裂岩中亲硫(亲铜)元素Ag、Cu、Pb、Zn明显增高,尤其是Ag和Zn分别是玲珑花岗岩的2.79倍和2.09倍,说明亲硫(亲铜)元素与金矿成矿作用关系密切;亲铁元素Cr、Co、Ni、Mo、Au、Sn、W整体上呈递增状况,大离子亲石元素Li、Be、Rb、Zr、Nb、W、Sr、Ba、As大多呈亏损状态.矿石中Au、Ag、W、Cu等具有强烈的富集,其中Au富集了381.40倍,W富集了3961.23倍,Ag富集了254.16倍,Cu富集了116.19倍,而Bi、Mo、As、Pb、Zn等富集度相对稍低,在3～20倍之间.在围岩、破碎蚀变带和金矿石中,皆出现了非常高的W元素富集,展示了招平断裂带具有独特的成矿地球化学行为.夏甸矿区围岩、构造蚀变碎裂岩和金矿石中的ΣREE总量分别为78.82×10-6、27.15×10-6和102.43×10-6,LREE/HREE比值分别为19.3、8.46和12.66,金矿石中具有相对较高的ΣREE、LREE和HREE,说明在成矿过程中外来物质的加入改变了稀土元素的含量和比值,也是区分矿与非矿的重要地球化学标志.矿区围岩、构造蚀变碎裂岩和金矿石的δEu分别为1.88、1.49和0.83,Eu/Sm值分别为1.57、2.05和0.69,Ce/Yb值分别为25.15、5.33和12.86,轻重稀土内部分馏均较小,成矿环境为弱氧化环境,说明夏甸金矿在成矿过程中,稀土元素更多地是反映从流体体系中带入到成矿的过程,使矿石中稀土元素含量相对增加.结合光片鉴定结果,在金成矿过程中,先期形成的黄铁矿多呈碎粒状,裂纹十分发育,黄铜矿呈他形粒状充填于黄铁矿裂纹中与金共生,说明自然金是与黄铜矿是同期形成的,而晚于黄铁矿的形成时间.  相似文献   

硼酸衬底压片制样-X射线荧光光谱法测定除尘灰中14种主次量元素     

周莉莉  董礼男  朱春要  张继明 《岩矿测试》2021,(4):612-618

除尘灰中过高含量的钾、钠、锌、氯等元素严重影响转底炉的正常生产和稳定运行,为解决钢铁行业中除尘灰的环保和资源再利用问题,需准确测定其中各组分的含量。除尘灰种类多,钾、钠、锌和氯含量范围宽,采用X射线荧光光谱法（XRF）测定易超出工作曲线测定范围。本文基于粉末直接压片,采用硼酸衬底镶边的方法,将氯化钾、氯化钠和氧化锌基准试剂加入铁矿石标样中制备更高含量的校准样品,扩展了除尘灰日常分析中钾、钠、锌和氯的测定范围,使钾的测定范围为1.36%~12.00%,钠的测定范围为0.43%~6.85%,锌的测定范围为0.24%~35.00%,增加了氯的测定范围为0.25%~10.00%。本方法测定除尘灰中14种主次组分的精密度（RSD,n=7）均小于5.2%,实际样品的测定值与标准方法测定值基本一致,准确度和精密度良好。  相似文献