Lipid Biomarkers and Their Stable Carbon Isotopes inAncient Seep Carbonates from SW Taiwan,China     

GUAN Hongxiang  XU Lanfang  WANG Qinxian  CHEN Duofu  WU Nengyou  MAO Shengyi 《《地质学报》英文版》2019,93(1):167-174

Four massive brecciated, chimney-like, and slender pipe network carbonate samples(JA-4, JA-5, JX-8 and BG-12) were collected from southwestern Taiwan, which were suggested to have formed as a result of anaerobic oxidization of methane(AOM). Considering that the environmental conditions of the carbonates precipitation and the sources of carbon and organic matter need to be further declared, molecular fossils and compound-specific carbon isotopic investigations of the carbonates were conducted in this study. According to lipid biomarkers of 2,6,10,15,19-pentamethyleicosane(PMI) and squalane diagnostic to methanotrophic archaea, as well as the extremely low δ¹³C values(as low as -1¹³.4‰) detected in samples JA-4, JA-5 and JX-8, these carbonates were revealed to be a result of AOM. Based on the varied δ¹³C values of characteristic archaea biomarkers in specific samples, biogenic methane was proposed to be responsible for the formation of samples JA-4 and JA-5, whereas a mixed carbon source of ¹³C-depleted methane and ¹³C-enriched residual CO_2 from methanogenesis was suggested for the carbonate of JX-8 due to the co-occurrence of a highly positive δ¹³ C_carb value(+8‰) and a moderate ¹³C depletion of PMI. The low content of AOM-related biomarkers and the absence of indicators for ANME-2 suggested that these carbonates were formed in weak seep settings. By comparison, no typical lipid biomarkers for methanotrophic archaea was detected in carbonate BG-12. The short-chain and long-chain n-alkanes accounted for 30% and 45% of all hydrocarbons, respectively, with a CPI value of 1.2, suggesting that the n-alkanes were derived from both marine organisms and terrestrial inputs. A low thermal maturity could be revealed by the incomplete equilibrium value of the C³¹αβ 22S/(22S+22R) ratio(0.5), and the carbonate BG-12 was probably deposited in a suboxic condition indicated by a value of Pr/Ph ratio(2.5).  相似文献   

Composition and origin of lipid biomarkers in the surface sediments from the southern Challenger Deep,Mariana Trench     

Hongxiang Guan  Linying Chen  Min Luo  Lihua Liu  Shengyi Mao  Huangmin Ge  Mei Zhang  Jiasong Fang  Duofu Chen 《地学前缘(英文版)》2019,10(1):351-360

The surface sediments collected from the southern Mariana Trench at water depths between ca. 4900 m and 7068 m were studied using lipid biomarker analyses to reveal the origin and distribution of organic matters. For all samples, an unresolved complex mixture (UCM) was present in the hydrocarbon fractions, wherein resistant component tricyclic terpanes were detected but C₂₇–C₂₉ regular steranes and hopanes indicative of a higher molecular weight range of petroleum were almost absent. This biomarker distribution patterns suggested that the UCM and tricyclic terpanes may be introduced by contamination of diesel fuels or shipping activities and oil seepage elsewhere. The well-developed faults and strike-slip faults in the Mariana subduction zone may serve as passages for the petroleum hydrocarbons. In addition, the relative high contents of even n-alkanes and low Carbon Preference Indices indicated that the n-alkanes were mainly derived from bacteria or algae. For GDGTs, the predominance of GDGT-0 and crenarchaeol, together with low GDGT-0/Crenarchaeol ratios (ranging from 0.86 to 1.64), suggests that the GDGTs in samples from the southern Mariana Trench were mainly derived from planktic Thaumarchaeota. However, the high GDGT-0/crenarchaeol ratio (10.5) in sample BC07 suggests that the GDGTs probably were introduced by methanogens in a more anoxic environment. Furthermore, the n-alkanes C₁₉–C₂₂ and the n-fatty acids C_20:0–C_22:0 were depleted in ¹³C by 3‰ compared to n-alkanes C₁₆–C₁₈ and the n-fatty acids C_14:0–C_18:0, respectively, which was interpreted to result from the preferential reaction of fatty acid fragments with carbon “lighter” terminal carboxyl groups during carbon chain elongation from the precursors to products. The abundance of total alkanes, carboxylic acids, alcohols and total lipids were generally increased along the down-going seaward plate, suggesting the lateral organic matter inputs play an important role in organic matter accumulation in hadal trenches. The extremely high contents of biomarkers in sample BC11 were most likely related to trench topography and current dynamics, since the lower steepness caused by graben texture and proximity to the trench axis may result in higher sedimentation rate. This paper, for the first time, showed the biomarker patterns in surface sediments of the Mariana Trench and shed light on biogeochemistry of the hardly reached trench environment.  相似文献   

Gas Chromatography-Mass Spectrometry in Geochemical Investigation of Organic Matter of the Grodziec Beds (Upper Carboniferous), Upper Silesian Coal Basin, Poland     

Monika J. Fabianńska  Gra?yna Bzowska  Aniela Matuszewska  Maria Racka  Urszula Skr?t 《Chemie der Erde / Geochemistry》2003,63(1):63-91

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CH₄-consuming microorganisms and the formation of carbonate crusts at cold seeps     

Giovanni Aloisi  Ioanna BouloubassiSander K. Heijs  Richard D. Pancost  Catherine PierreJaap S. Sinninghe Damsté  Jan C. GottschalLarry J. Forney  Jean-Marie Rouchy 《Earth and Planetary Science Letters》2002,203(1):195-203

To understand the role played by microorganisms in the formation of cold seep carbonates, we conducted an integrated microbial, mineralogical and organic geochemical study of methane-related authigenic carbonate crusts formed on eastern Mediterranean mud volcanoes. We show that supersaturation with respect to carbonate minerals is induced by microbial anaerobic oxidation of methane. Combined lipid biomarker analysis and 16S rRNA gene surveys identified a highly diversified methane-consuming archaeal community possibly comprising novel species, implying that the anaerobic oxidation of methane is phylogenetically widespread and directly implicating these organisms in the process of crust precipitation. Moreover, pore-water sulphate gradients produced by co-occurring methane-based sulphate reduction exert the main control on aragonite versus magnesian calcite precipitation. We propose that this may be the dominant mode of carbonate crust formation at cold seeps world-wide, in agreement with aquatic chemistry predictions and explaining carbonate mineralogy.  相似文献   

泥炭分子化石单体碳氢同位素的古气候意义   总被引：9，自引：0，他引：9  

谢树成  易轶  梁斌  郭建秋 《矿物岩石地球化学通报》2003,22(1):8-13

为了查明泥炭分子化石记录的古植被状况与古植物学分析结果的差异，并进一步探讨这些分子化石所记录的古气候信息，本文利用气相色谱仪(CC)、气相色谱—质谱联用仪(GC—MS)、气相色谱—燃烧-同位素比质谱仪(GC-C-IRMS)、气相色谱-热转换—同位素比质谱仪(CC—TC—IRMS)详细分析了一个40cm(约220年)长的泥炭岩芯中的分子化石及其单体碳、氢同位素组成。正构烷烃分子化石的主峰化合物(C23)及其碳、氢同位素组成与温度有很好的对应关系，工业革命以来化石燃料的燃烧效应也在单体碳同位素上反映出来。这些结果反映了泥炭分子化石具有很好的古气候和古环境意义。  相似文献   

Mass Spectrometry and reverse phase HPLC techniques for the identification of degraded fossil pigments in lake sediments and their application in palaeolimnology   总被引：3，自引：0，他引：3  

Dominic A. Hodgson  Simon W. Wright  Noel Davies 《Journal of Paleolimnology》1997,18(4):335-350

Accurate identification of fossil pigments is essential if they are to be used as biomarker compounds in palaeolimnological studies. In recent years High Performance Liquid Chromatography (HPLC) has greatly enhanced the efficiency with which fossil pigments can be characterised and quantified. Using HPLC, undegraded pigments are typically identified through retention times, absorbance spectra and co-chromatography with authentic reference standards. However, lake sediments may also contain degraded pigments for which there are often no standards, and which may be difficult to identify using HPLC alone. In this study, we submitted HPLC fractions of fossil pigments and pigment derivatives collected from a meromictic lake in south west Tasmania, to a combination of Mass Spectrometry (MS) techniques including Electron Impact (EI) and static Liquid Secondary Ion MS (LSIMS) to identify their molecular ion characteristics and organic chemical composition. Mass Spectrometry permitted the detection of specific mass ions which were used to verify the identity of pigments and their derivatives. These included five carotenoids, chlorophyll a and derivatives, three previously described bacteriochlorophyll c derivatives with molecular weights of 770, 784, and 802, and two undescribed derivatives of bacteriochlorophyll c with molecular weights of 766 and 788. With these improved identifications we speculate on the pathways and modes of pigment degradation in the lake and asses the value of the degraded pigments as biomarkers. The use of MS permitted the identification of a greater number of signature pigments of algal and bacterial communities thus increasing the palaeolimnological value of the sediments. These methods are best applied in fossil pigment studies where there are a large number of unknown pigments and pigment degradation products, and where there are no authentic standards for co-chromatography. Practical suggestions for pigment MS are included in the discussion.  相似文献   

Hydrous pyrolysis of Monterey asphaltenes     

Zvi Sofer   《Organic Geochemistry》1988,13(4-6)

Hydrous pyrolysis of asphaltenes has been tested as a method to reconstruct the chemical composition of biodegraded oils and oil seeps. The asphaltenes of three oils (a nondegraded oil, a biodegraded oil, and a biodegraded oil seep) from the Monterey Formation were studied. Results show that the aliphatic fraction generated by hydrous pyrolysis is very similar in chemical composition to the non-degraded oil. This makes the method very useful in correlation studies of biodegraded and nondegraded oils. It also allows to roughly estimate the maturity of the source of the biodegraded oil or oil seep.  相似文献   

Molecular genetic markers and maturity indices in intermontane lacustrine facies: Kishenehn formation, Montana     

Joseph A. Curiale 《Organic Geochemistry》1988,13(4-6)

Molecular markers have considerable promise as thermal maturation indicators in source rocks having a well-defined depositional environment. This occurs in the Kishenehn Formation (northwest Montana and southeast British Columbia), an Oligocene unit comprised of fluvial and lacustrine shales. Up to 3 km of these non-marine sediments were deposited in a 900 sq.km elongated half graben atop the Precambrian rocks of the Lewis Thrust sheet. Specific outcrops of the Coal Creek Member of the Kishenehn Formation are known to contain excellent potential source rocks, including extensive oil shales. The source rock potential and molecular marker geochemistry of most of the major Kishenehn outcrops have now been investigated, and regional results are presented in this paper.source rock analysis of a regional suite of Kishenehn samples indicates excellent petroleum potential (immature Type I kerogen) throughout the basin. Several classes of distinctive diagenetic molecular markers occur within the Coal Creek Member of the Kishenehn Formation, including diasterenes, spirosterenes, methylspirosterenes, B-ring monoaromatic anthrasteroids, ββ-hopanes and moretanes. Molecular markers indicative of non-marine deposition include dehydroabietane (conifer input) and an onocerane recently identified in leaf fossils of Miocene lacustrine beds in adjacent Idaho. Triterpane ratios are significantly more sensitive than vitrinite reflectance methods in assessing thermal maturation in the Kishenehn, and are successfully used in this study to order outcrop locations according to thermal maturity level. The systematic variation of specific markers with increasing thermal maturation suggests that molecular correlation is feasible, and could provide a method of assessing stratigraphic continuity in the basin.  相似文献   

Early generation of 20S-5α(H),14α(H),17α(H)- and 5α(H),14β(H),17β(H)-steranes in low salinity lacustrine shales     

Maowen Li  Steve R. Larter  Bowen Mei 《Organic Geochemistry》1994,22(6)

A quantitative sterane biomarker study was conducted on a series of paralic freshwater lacustrine shale samples ranging in maturity from immature to near oil window maturity taken from Section 3 of the Shahejie Formation (Es3) in the Liaohe Basin, N.E. China. Concentrations of 5α(H),14α(H),17α(H)-20S and 5α(H),14β(H),17β(H)-steranes remain nearly constant throughout the sample suite. However, the decrease in the absolute concentrations of the 20R-5α(H),14α(H),17α(H)-C₂₉ steranes with increasing maturity results in an increase in the conventionally defined maturity parameters, 20S/(20S + 20R)-ααα and αββ/(ααα + αββ) sterane ratios. In addition, the data suggest that relatively early generation of 5α(H),14α(H),17α(H)-20S and 5α(H),14β(H),17β(H)-steranes has occurred in lacustrine sediments with a vitrinate reflectance 0.3% (R_o). The data provide strong support for the major importance of relative thermal stability of epimers, but do not exclude the possibility of isomerization as a viable mechanism for production.  相似文献   

Extended saturated and monoaromatic tricyclic terpenoid carboxylic acids found in Tasmanian tasmanite     

D.A. Azevedo  F.R.Aquino Neto  B.R.T. Simoneit   《Organic Geochemistry》1994,22(6)

A series of tricyclic terpenoid carboxylic acids (C₂₀–C₄₀) was found in the acidic fraction of Tasmanian tasmanite bitumen, occurring as a mixture of stereoisomers with mainly the 13β(H), 14α(H)-and 13α(H),14α(H)-configurations. These dominant acidic tricyclic constituents have the same carbon skeleton as the ubiquitous tricyclic terpane biomarkers. A novel series of ring-C monoaromatic tricyclic terpenoid carboxylic acids was also characterized. The series ranges from C₁₉ to C₃₉ and is the acidic counterpart of the recently described series of monoaromatic tricyclic terpanes.  相似文献