煤中黄铁矿的成因研究   总被引：14，自引：0，他引：14  

唐跃刚  任德贻 《地质论评》1996,42(1):64-70

本文在系统地研究四川晚二叠世高硫煤中黄铁矿矿物学的基础上，运用微区电子探针、中子活化、Ｘ光电子能谱和硫同位素等多 种方法综合地研究煤中黄铁矿的结构、成分、价态及同位素等成因标型特征，对黄铁矿标型特征进行了成因探讨，有效地判别了成岩期形成的Ｉ型脉状黄铁矿及后生热液Ⅱ型脉状黄铁矿。同时提出直接沉淀系列（自形晶→集合→聚晶）和复杂成因（微粒、莓粒→圆球→结核→团块）等两大类成因演化模式。它不仅对不同类型  相似文献   

面向21世纪的煤化工   总被引：8，自引：0，他引：8  

魏贤勇  高晋生 《华北地质矿产杂志》1996,11(1):1-8

煤炭是中国的主要能源和资源，但同时也是主要的污染源。从保护环境、合理利用有限的化石资源的角度和中国的具体国情考虑，应该大力开发温和化高效煤的新工艺，使煤炭资源逐步由能源型利用转化为材料型利用，近年来，我们在煤的溶剂萃取，脱硫降灰机理，煤相关模型化合物反应，煤焦油中稠环芳香族化合物的分离精制，功能性高分子单体合成及一氧化碳高效吸附剂的制备等方面做了大量的研究工作，结合这些研究工作，本文介绍了煤化工的  相似文献   

印尼中加里曼丹波拉湾煤勘探区的构造解析     

杨雄庭  王泽安 《湖南地质》1996,15(4):234-238

本文从区域构造背景出发，根据波拉湾煤勘探区地表及钻孔资料综合分析，建立了逆冲断层Ｆ１、Ｆ２及其配套的ｆ１、ｆ２……构造，理顺了错综复杂的构造格局，将推覆构造理论成功地用于援外生产实践。  相似文献   

Surface chemical analysis in coal preparation research: complementary information from XPS and ToF-SIMS     

A. N. Buckley  R. N. Lamb 《International Journal of Coal Geology》1996,32(1-4)

The application of X-ray photoelectron spectroscopy (XPS) to coal surface characterisation for preparation research is described. Progress towards the acquisition of complementary surface chemical information by time-of-flight secondary ion mass spectrometry (ToF-SIMS) is also discussed. Surface-based beneficiation techniques such as flotation are assuming greater importance as the proportion of fines in raw coal increases due to the proliferation of high capacity mining methods. A necessary condition for the floatability of a coal particle is adequate hydrophobicity, and the degree of hydrophobicity of the flotation concentrate is one factor influencing the ease with which its dewatering can be affected. The hydrophobicity of a coal is very difficult to measure directly because of microporosity, and it is often necessary to deduce the degree of hydrophobicity from a knowledge of the surface chemistry. XPS is able to provide sufficient analytical data to allow relative levels of hydrophobicity to be estimated. In principle, ToF-SIMS should be able to supply additional information enabling refinement of such estimates; however, there are insufficient data at present to allow the ionic fragments detected to be related to specific functional groups at the coal surface.  相似文献   

Characterisation of brown coal humic acids and modified humic acids using pyrolysis gcms and other techniques     

W. R. Jackson  G. D. Bongers  P. J. Redlich  G. Favas  Y. Fei  A. F. Patti  R. B. Johns 《International Journal of Coal Geology》1996,32(1-4)

It has been proposed that Victorian brown coal can be considered as a two-component structure — a lignocellulosic “host”, containing various amounts of weakly bound or entrapped “guest” material together with very small amounts of inorganic and/or mineral matter. The latter predominantly consists of wax esters and/or terpenoid material. In this paper we describe attempts to gain structural information regarding the more complex, “host” component of the coal. Our initial model compound has been humic acid that can be readily obtained from the coal by alkaline extraction. It has been found that “pure” humic acid, free from material associated with the “guest” components of the coal, can be obtained by a highly selective, low-yielding alkaline extraction. This humic acid has been studied by nmr spectroscopy and pyrolysis gas chromatography-mass spectroscopy (py-gc/ms). The products arising from py-gc/ms have been compared with those obtained from similar pyrolysis of whole coals. Alkylation of humic acids using alkyl halides in the presence of base has been successfully carried out and reactivity of the resulting materials compared with those of the parent coal and humic acid.  相似文献   

三江盆地七星河区成因地层分析   总被引：1，自引：0，他引：1  

邹艳荣  蔡玉兰 《煤田地质与勘探》1996,24(1):1-4

区内存在５种等时性地层界面，据此将含煤岩系划分为６个成因单元，１０个亚单元。沉积环境经历了５个演化阶段，其中扇三角洲废弃阶段为最有利的聚煤时期。聚煤的有利部位位于废弃的扇三角洲体之上。  相似文献   

水压与钻孔联合爆破拆除大型地面煤仓          下载免费PDF全文

李玉民  赵锦桥  孙文进 《探矿工程》1996,(6):47-48

分析了水压与钻孔联合爆破的特点，给出了设计方法及参数，实践表明，在坚固筒体内构筑物拆除中应用该技术可取得安全，快速解体破碎和定向倾倒的良好效果。  相似文献   

淮南谢—矿煤的组成对甲烷吸附性的影响     

姚多喜 《中国煤田地质》1996,(Z1)

从淮南谢—矿五层煤（Ｃ＿（１３）、Ｂ＿（１１ｂ）、Ｂ＿（１０）、Ｂ＿（４ｂ）和Ａ＿３）中精选出镜煤、壳质暗煤、惰性暗煤及构造煤，采用重量法，分别测定它们的甲烷吸附量，从而研究不同成分组成的煤其甲烷吸附性能。  相似文献   

华北石炭——二叠纪煤系粘土岩夹矸中铝的氢氧化物矿物研究   总被引：4，自引：0，他引：4       下载免费PDF全文

梁绍暹  任大伟 《地质科学》1997,32(4):478-486

华北石炭——二叠纪煤系太原组和山西组不同煤层粘土岩夹矸中,广泛含有一水软铝石、一水硬铝石和三水铝石。大多数一水铝石矿物呈薄纹层状、似层状及层状聚集于富岩质及富有有机质粘土岩夹矸条带中,有的呈细脉状沿炭质条带及粘土岩夹矸层理的节理裂隙分布,并与玉髓、方解石、高岭石或迪开石和铵云母细脉共生。铝的氢氧化物矿物可以作为成岩古温度和成岩阶段划分的标志矿物。最后还讨论了该矿物的成因。  相似文献   

井筒及围岩应力,应变观测方法研究     

苏仲杰  隋惠全 《岩土力学》1997,18(3):82-87

采用最新研制的岩体应力、应变匹配传感器对西安立井煤柱开采引起的井筒附加应力特别是对井筒穿过断层附近产生的附加应力进行了较系统的观测，并对观测结果进行了分析和总结。  相似文献