全文获取类型
收费全文 | 148篇 |
免费 | 14篇 |
国内免费 | 78篇 |
专业分类
大气科学 | 1篇 |
地球物理 | 11篇 |
地质学 | 156篇 |
海洋学 | 48篇 |
综合类 | 15篇 |
自然地理 | 9篇 |
出版年
2024年 | 1篇 |
2023年 | 4篇 |
2022年 | 6篇 |
2021年 | 6篇 |
2020年 | 6篇 |
2019年 | 4篇 |
2018年 | 6篇 |
2017年 | 4篇 |
2016年 | 5篇 |
2015年 | 5篇 |
2014年 | 10篇 |
2013年 | 16篇 |
2012年 | 8篇 |
2011年 | 11篇 |
2010年 | 8篇 |
2009年 | 15篇 |
2008年 | 13篇 |
2007年 | 20篇 |
2006年 | 17篇 |
2005年 | 15篇 |
2004年 | 8篇 |
2003年 | 7篇 |
2002年 | 2篇 |
2001年 | 3篇 |
2000年 | 6篇 |
1999年 | 2篇 |
1998年 | 6篇 |
1997年 | 7篇 |
1996年 | 2篇 |
1995年 | 2篇 |
1994年 | 1篇 |
1993年 | 4篇 |
1991年 | 1篇 |
1990年 | 2篇 |
1987年 | 1篇 |
1985年 | 4篇 |
1984年 | 1篇 |
1983年 | 1篇 |
排序方式: 共有240条查询结果,搜索用时 15 毫秒
61.
The uptake of zinc and cadmium by a species of marine diatom Thalassirosira weissflogii and the nutrient variation (phosphorus and silicon) in the culture medium were estimated when exposed to zinc and cadmium stress under controlled laboratory conditions.It was found that low cadmium addition could stimulate the culture to grow with a relatively high rate and exert its toxicity at the elevated concentration.The cellular uptake of zinc and cadmium by the diatom varied in the ranges of 1.21~3.75 and 0.060~0.629 fmol per cell respectively in the whole cultivation period.The mean cellular phosphorus and silicon drawdowns were constant with 0.26~0.42 and 0.30~0.46 pmol per cell respectively in those healthy cultures.It is illustrated that the algal cells can adjust some physiological mechanisms to decrease metal accumulation and keep metal homeostasis in the organism.The correlation analysis results further indicate that the cellular cadmium uptake might be closely related with the cellular phosphorus, silicon drawdown and the growth rate of diatom (P<0.05, 0.001, 0.01); and the cultures grow better in good conditions, the lower amount of phosphorus, silicon materials are consumed by a single cell to keep a high efficiency of utilization. 相似文献
62.
63.
Effect of salinity on heavy metal mobility and availability in intertidal sediments of the Scheldt estuary 总被引:8,自引:0,他引:8
G. Du Laing R. De Vos B. Vandecasteele E. Lesage F.M.G. Tack M.G. Verloo 《Estuarine, Coastal and Shelf Science》2008,77(4):589-602
The effect of the flood water salinity on the mobility of heavy metals was studied for intertidal sediments of the Scheldt estuary (Belgium). Soils and sediments of 4 sampling sites were flooded with water of different salinities (0.5, 2.5, and 5 g NaCl L−1). Metal concentrations were monitored in pore water and surface water. To study the potential effects of flood water salinity on metal bioavailability, duckweed (Lemna minor) was grown in the surface water. The salinity was found to primarily enhance the mobility of Cd and its uptake by duckweed. Cadmium concentrations in pore water of soils and sediments and surrounding surface waters significantly exceeded sanitation thresholds and quality standards during flooding of initially oxidized sediments. Moreover, the effect was observed already at lower salinities of 0.5 g NaCl L−1. This implies that risks related to Cd uptake by organisms and Cd leaching to ground water are relevant when constructing flooding areas in the brackish zones of estuaries. These risks can be reduced by inducing sulphide precipitation because Cd is then immobilised as sulphide and its mobility becomes independent of flood water salinity. This could be achieved by permanently flooding the polluted sediments, because sulphates are sufficiently available in the river water of the brackish part of the estuary. 相似文献
64.
黄、渤海是我国重要的海洋经济渔业开发区域,海水中痕量金属的含量及其存在形态会对海洋环境、海洋渔业产生重要影响。随着近年我国痕量金属采集与分析测试技术的发展,数据的准确性有了新的提升。2016-06—07采集黄、渤海40个站位的海水样品,测定其溶解态金属Cd的总浓度,并应用电化学方法(阳极溶出伏安法)分析Cd存在形态。结果表明,渤海海水中的总溶解态Cd浓度是南黄海海水中的2~3倍,这可能与渤海海水停留时间较长,水深较浅,周边较多河流输入有关。20%~92%以上的溶解态Cd是以有机络合物形态存在,以自由离子态存在的Cd浓度不超过100 pmol/L,低于Cd对浮游生物的毒性阈值。渤海比黄海的金属配体浓度高出2倍以上,高值出现在黄河口周围海域,表明黄河水携带较多有机配体输入。推测我国近海有机配体来源可能包括陆源输入、沉积物再悬浮的解析过程以及藻类分泌。研究还表明,黄、渤海海水中溶解态Cd的有机配体络合常数较其他海域的稍高,这与我国近海废、污水排放的有机络合配体类型有关。 相似文献
65.
Daniel J. Meininger William S. Kinman Susan K. Hanson 《Geostandards and Geoanalytical Research》2023,47(2):457-465
The isotopic composition of cadmium in nuclear debris was measured by multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS). Mass-independent perturbations due to fission product decay on the isotopes of Cd were observed. Relative fission yields for masses 111, 112, 114 and 116 were determined in each sample of nuclear debris and compared with reported values found in irradiated plutonium and uranium fuels. Mass spectrometry measurements of the valley fission product endpoints are extremely challenging due to the low cumulative fission yields and small amounts of each isotope that are produced. To overcome these challenges, a new purification method for Cd was developed and validated by examination of a number of geological reference materials. 相似文献
66.
Melisa Daiana Fernández Severini Sandra Elizabeth BottéMónica Susana Hoffmeyer Jorge Eduardo Marcovecchio 《Estuarine, Coastal and Shelf Science》2009
Cadmium and copper in the dissolved and particulate phase and in zooplankton were determined in the Bahía Blanca estuary during six surveys from March to December 2005. Temperature, pH, salinity, dissolved oxygen, suspended particulate matter, particulate organic matter and chlorophyll-a were also considered. Dissolved Cd was below the detection limit (0.2 μg L−1) for almost the entire study period whereas Cu concentrations (0.5–2.4 μg L−1) indicated a continuous dissolved Cu input. Particulate Cd concentrations ranged from below the detection limit (<0.01) to 28.6 μg g−1 d.w. while particulate Cu ranged from below the detection limit (<0.04) to 53.5 μg g−1 d.w. Cd in mesozooplankton ranged from below the detection limit (<0.01) to 37.4 μg g−1 d.w. Some of the Cd levels were higher than those reported for other aquatic ecosystems. Cu in the mesozooplankton ranged from 1.3 to 89.3 μg g−1 d.w., values which were within the reported values or higher than other studies. The log of the partition coefficients (log (Kd)) of Cd was 0.04, while log (Kd) for Cu ranged from −0.39 to 2.79. These values were lower than both those calculated for other estuaries and the typical coefficients for marine environments. The log of the bioconcentration factor (log BCF) of Cd was 1.78, indicating that Cd concentration was higher in the zooplankton than in the dissolved phase. Log BCF of Cu ranged from 1.15 to 3. The logs of the biomagnification factors (log BMF) of Cd were low, with a range between −3.45 and 2.21 and those for Cu ranged from −0.1 to 3.35. Positive values indicate biomagnification while negative values indicate biodiminution. In general, no significant dissolved Cd concentration appeared to be present in the Bahía Blanca estuary and Cu values did not indicate a critical environmental status. The particulate phase seemed to be the major carrier for Cd and Cu and TPCu values were within the normal values for an anthropogenically stressed estuary but not for a strongly polluted system. This fraction was the most important metal source for the mesozooplankton. Moreover, the highest metal concentrations were in the mesozooplankton since most of the bioconcentration and biomagnification factors were positive, especially for Cu. 相似文献
67.
研究了410哌啶树脂对Cd的吸附行为,在2%~20%HCI介质中[CdCl_3] ̄-被树脂吸附,采用4%~30/HNO_3溶液可以解脱Cd,回收率在96%以上。测定了Cd在该树脂上的分配系数为5490,对含Cd0.067μg/g的标样GSR-3平行测定6次,相对标准偏差为9.5%。方法用于化探样品中0.0X×10 ̄-6级Cd的测定,结果满意。 相似文献
68.
计算极谱法同时测定镉镍的研究 总被引:1,自引:0,他引:1
采用普通极谱仪与计算机联机技术,用卡尔曼滤波处理以KSCN为支持电解质的Cd~(2+)和Ni~(2+)混合溶液的示波极谱重叠波。实验表明,极谱可逆波具有较好的加和性,可采用计算极谱方法对多组分(尤其是难以分开的重叠波)进行同时测定。 相似文献
69.
甲基异丁基酮负载泡塑富集—原子吸收测定岩矿中痕量金银铊镉 总被引:4,自引:4,他引:4
研究了多种负载泡塑对Au、Ag、Ti、Cd的富集行为。提出了在HCI-KI-抗坏血酸介质中用甲基异丁基酮(MIBK)负载泡塑同时萃取,然后用2%硫脲-1%HCl解脱的富集方法,并采用火焰原子吸收连续测定地质样品中痕量Au、Ag、Tl和Cd,方法的测定下限(μg/g)分别为:0.2g、0.05、0.20和0.04。 相似文献
70.
某冶炼厂附近农田镉污染调查与对策 总被引:5,自引:2,他引:3
对遭受某铜矿冶炼厂镉污染的湖北省某镇约30km^2的农田土壤进行了调查,对土壤耕作层与亚耕层以及污染源(废气、废水和炉渣)中全量Cd和有效态Cd含量的系统测定结果表明:未受Cd污染、受轻度污染及受中度污染的土壤面积分别占3.6%,82.1%,14.3%;土壤中全量Cd及有效态Cd含量的分布规律均表现为西灌区>东灌区>灌间区;土壤耕作层与亚耕层中全量Cd含量的差异不大,而有效态Cd则主要富集于土壤耕作层中;受土壤pH值的影响,Cd在污染区土壤中的活化率低于远离冶炼厂未受污染的农田对照区。该镇农田的Cd污染主要来源于某铜矿冶炼厂的废气和废水,而炉渣的污染相对较小。运用生态方法治理该镇农田的Cd污染具有一定的可行性和适用性,值得研究利用。 相似文献