DTPA浸提-电感耦合等离子体质谱法测定石灰性土壤中的有效态钴和有效态铅   总被引：3，自引：1，他引：2  

韩张雄  熊英  王龙山  马娅妮  李力争  王晓雁  刘琦 《岩矿测试》2012,31(6):950-953

传统的原子吸收光谱和分光光度法测定土壤有效态钴和有效态铅,操作繁琐,且分析效率低,不适用于大量样品的测定;利用先进仪器测定虽然提高了分析效率,但由于浸提剂的浓度影响仪器灵敏度,测定结果不准确.本文用DTPA溶液浸提,电感耦合等离子体质谱法测定石灰性土壤中有效态钴和有效态铅的含量.稀释倍数实验表明,浸提液稀释2倍时,石灰性土壤国家标准物质的测定值与标准值基本一致;稀释5倍或10倍时,测定值较标准值偏高;不稀释时,由于浸提液的浓度较高,受到基体干扰,测定值偏低.本方法确定对浸提液稀释2倍进行实验,有效态钴的检出限为0.0130 μg/g,有效态铅的检出限为0.0142 μg/g,精密度(RSD,n=9)小于8％.用土壤国家标准物质进行验证,测定值与标准值的相对误差小于9％(n=9),满足了DD 2005 - 03对土壤样品中有效态钴和有效态铅的测定要求.  相似文献   

Sedimentary characteristics and provenance of the basal conglomerate of the Late Jurassic-Early Cretaceous Jiaolai Basin,eastern China and their implications for the uplift of the Sulu Orogenic Belt     

《International Geology Review》2012,54(5):521-538

ABSTRACT

The basal conglomerates (‘Linsishan Conglomerate’, LC, herein) are exposed discontinuously along the northern part of the Sulu Orogenic Belt (SOB) and the southern part of the Jiaobei Terrane. Studying these conglomerates can offer key constrains for the formation age of the Jiaolai Basin and improve our understanding of the uplift and erosional histories of the SOB and Jiaobei Terrane, which are still in great controversy. In Huangyadi section, the LC is characterized as debris-flow deposits, channel deposits, and sheet-flow deposits. However, in Shanjiao section, the LC is changed to sheet-flow and sieve deposits, as well as debris-flow and channel deposits. These deposit characteristics indicate an unstable tectonic setting during initial opening stage of the basin. Based on the data of conglomerate component, palaeocurrent, and debris zircons ages, it can be inferred that the sediments in the Laiyang region were sourced from the Jiaobei Terrane and Northern Sulu Orogenic Belt (NSOB), and the sediments in the Zhucheng and Wulian regions were derived from the Jiaobei Terrane and the Southern Sulu Orogenic Belt (SSOB). Besides, the sediments in the Haiyang and Jimo regions were provided by the NSOB and SSOB, respectively. The significant SHRIMP U–Pb ages of a tuff developing in the LC has been obtained, indicating that 149 ± 2.5 Ma is the oldest age constraint for the Jiaolai Basin. In addition, our result shows that the Latest Jurassic (ca. 149 Ma) may be a critical time; before this time, the Jiaobei Terrane and the SOB experienced a rapid uplift with minimal uplift velocity (~0.9 km/Ma); since then, the Orogen began to collapse and a series of basins formed rapidly in its core, which indicate the tectonic stress regime of the Dabie-Sulu Orogen varied from compressional stress to tensile stress.  相似文献   

桂西天峨—凤山地区碳酸盐岩台地韧性剪切变形带   总被引：1，自引：0，他引：1  

张能  卢海峰  严育通  吴年冬 《现代地质》2012,26(4):696-704

桂西天峨—凤山地区泥盆纪至二叠纪碳酸盐岩台地相地层均不同程度地发生过韧性剪切变形变质作用。在碳酸盐岩台地边缘,主要沿石炭系、二叠系的一定层位,形成了一套浅变质强变形、面型展布的钙质韧性剪切变形带,剪切变形带由强、弱变形亚带及两者之间过渡亚带组成。显微镜下观察发现:强变形带内变质变形岩石具糜棱结构,韧性剪切变形构造发育,属糜棱岩系列。研究表明,区内钙质韧性剪切变形带属浅层次逆冲型,主要是弧—陆碰撞挤压构造环境下变形分解作用的产物。  相似文献   

白彦砾岩的形成时代及砾石组构特征分析     

王照波  刘安同  王庆军 《山东地质》2012,(1):14-19

通过对白彦砾岩中孢粉取样鉴定及其砾石组构的统计研究,孢粉组合特征显示其形成时代为中侏罗世,并非通常认为的古近纪。砾石组构特征显示为湖滨相或海滨相成因,砾岩中金刚石特征显示出与蒙阴常马金刚石原生矿的相似性。综合分析认为,白彦砾岩形成于中侏罗世鲁西地区单断拉分盆地诞生之前,应为三台组沉积之前的沉积物。白彦砾岩沉积时代的确定,对恢复该区岩相古地理、确定金刚石原生矿的剥蚀与搬运等都具有重要意义。  相似文献   

南化塘区晚震旦世碳酸盐砾岩层序及其形成机制探讨     

李侠  胡健民  宋子新  刘护军 《地球科学与环境学报》1993,(Z1)

作者认为鄂西南化塘区晚震旦世发育的一套碳酸盐砾岩层序,是碳酸盐台地上台隆边缘形成的一种特殊沉积岩相,是古海洋面强烈波动的一种标志。文章从构造学和沉积学方面初步探讨了其建造过程和形成机制。  相似文献   

Occurrence of gold in hydrothermal pyrite,western Taupo Volcanic Zone,New Zealand     

Youjun Zhang  Lu Wang  Jianwei Li  Peng Feng  Yang Huang 《Geodinamica Acta》2016,28(3):185-198

The Taupo Volcanic Zone (TVZ) on the North Island of New Zealand is located above the subducting Pacific slab and hosts hydrothermal systems related to subduction, arc magmatism and crustal extension. In these systems, gold is transported primarily as sulphide complexes, with gold being deposited in response to boiling and mixing of the deep geothermal fluids. Conglomerate cobbles and hydrothermal fumaroles from the upper Retaruke River in the western TVZ are mineralised deposits that have been eroded from the nearby Miocene alluvial sedimentary plateau. Abundant gold-bearing pyrite was precipitated in the conglomerates and fumaroles by late hydrothermal process, primarily occurring as veinlets, disseminations and fine-grained aggregates which consists discrete euhedral microcrystals. Scanning electron microscopy combined with X-ray energy disperses spectroscopy shows that pyrites are commendably affected by late hydrothermal fluids, possibly by the carbonate fluid. Electron probe microanalysis revealed that the pyrite contains 20–120 ppm Au (averaging 60 ppm). Wavelength dispersive spectral elemental mapping suggests that gold is distributed uniformly in pyrite, indicating structurally bound gold (solid solution) in pyrite. Gold mineralisation recognised in the conglomerates and fumaroles demonstrates that the upper Retaruke River is a promising target for future gold exploration.  相似文献   

下扬子地区幕府山组古环境和构造背景：来自细粒混积沉积岩系元素地球化学的证据     

周江羽  陈建文  张玉玺  张银国  张悦  刘甜怡  万雪芳 《地质学报》2021,95(6):1693-1711

扬子地区寒武纪纽芬兰世广泛发育富含有机质的黑色细粒混积沉积岩系,开展细粒混积沉积岩的元素地球化学研究,对于恢复沉积期物质来源、源区构造背景、古气候、沉积环境及演化,以及泥页岩储层评价和页岩气勘探具有重要理论和现实意义.本文利用下扬子地区最新完钻的XYZ-1钻井资料,综合钻井岩芯、岩石薄片、XRD分析、ICP-MS分析等手段,开展寒武系纽芬兰统幕府山组细粒混积沉积岩系的地球化学研究.结果表明,幕府山组为一套形成于局限海湾—碳酸盐岩台地—潮坪体系的细粒混积沉积岩系,岩性以深灰色、黑色(含钙质碳质)泥岩、浅灰色泥质灰岩为主,夹云灰岩、泥晶灰岩、白云岩、含陆屑碳质灰岩、安山岩和角砾岩.幕府山组沉积期,具有干旱炎热-温暖潮湿交替的古气候,总体指示正常盐度的浅水-较深水古海洋环境,垂向上显示从贫氧—缺氧到滞留硫化环境的演变.幕府山组细粒混积岩物源来自江南造山带和南京台地,源区岩石未曾经历沉积再循环作用,形成于大陆岛弧和活动大陆边缘构造背景.具有相对高海平面的近岸局限海湾、半封闭滞留还原环境、较高的有机碳含量和古生产力水平,是形成富有机质黑色细粒混积沉积岩系的有利条件.  相似文献   

Nagaur — tertiary interface under Punjab-Haryana semi-desertic plains in western India     

R. C. Dey 《Journal of the Geological Society of India》2009,74(1):131-137

The subsurface Nagaur Basin in northwest Haryana and southwest Punjab hosts evaporite sequence, conformably overlain by Nagaur red beds and grey beds. A polymictic conglomerate intervenes the Nagaur sequence and the overlying Tertiary sequence. The focus is on the new finds of (i) distinctive ‘grey beds’ overlying ubiquitous red beds, (ii) ‘Malout conglomerate and grit’ horizon (Palaeocene-Miocene) marking an unconformity over the Nagaur Group (early Cambrian) and (iii) ‘entrapped gas and dried-up leaves/carbonaceous flakes’ in the conglomerate unit and succeeding Tertiary rocks. Palaeoenvironmental significance has been discussed. The Nagaur ‘red beds’ has been likened to ‘continental red beds’ of Schreiber (1978) and ‘reworked red beds’ of Krynine (1949). The ‘grey beds’ are channel fillings, fresh material having been derived from fresh cuttings by streams/rivers following structural grains in the Aravalli landscape where the interfluves provided weathered (oxidised) materials for the red beds. Association of continental red beds and grey beds is known in the Newark Series (Triassic) of the Eastern United States and the Keweenawan ‘late Precambrian’ of the Lake Superior region.  相似文献   

IMPEDANCE CHARACTERISTICS OF CALCAREOUS DEPOSIT   总被引：1，自引：0，他引：1  

温国谋  郑辅养  方炳福  马廷椿 《中国海洋湖沼学报》1996,14(3):276-281

The electrochemical impedance spectra for bare steel and sample covered with calcareous deposit in artificalseawater were determined; the dependence of the impedance on the potential was investigated, thesignificance of the impedance parameter R_f reflecting the effective protectiveness of the deposit is emphasized.Optimization of the cathodic polarization condition is discussed.  相似文献   

Pulsating oblate and prolate three-dimensional strains     

Ruud Weijermars 《Mathematical Geology》1997,29(1):17-41

The progressive ductile deformation of competent spherical inclusions is modeled analytically. Results of this study may help to understand better the limitations connected to geological field methods using competent inclusions for strain analyses. Parameters studied and quantified here are the strain magnitude, the progressive change in inclusion shape, the orientation of the finite strain axes, the frequency of pulsation, and the coupling between the strain ellipticity and viscosity contrast. Competent inclusions develop pulsating apparent strains if the host material is subjected to a component of simple shear and provided time or strain rate is sufficient to complete the strain cycle. The disparity between the strain magnitude inferred from competent viscous inclusions and that undergone by the host rock, increases for larger viscosity between them. The pulsation of the inclusion may suggest zero strain after a strain cycle has been completed, even though strain in the host rock is extremely large. The inclusion will develop pulsating oblate strains if a shortening rate is superposed normal to the plane of pulsation. Conversely, pulsating prolate strains occur if an extension rate is superposed instead of shortening. Stretching lineations outlined by deformed competent inclusions within shear zones beneath collapsing nappe sheets may even point perpendicular to the direction of nappe transport. This finding offers an explanation for the occurrence of mutually perpendicular pebble elongations in nearby locations within the Bygdin conglomerate beneath the Jotun nappe, Norwegian Caledonides.  相似文献