湖泊无机碳酸盐矿物氧同位素组成差值及其单矿物同位素组成的确定          下载免费PDF全文

曾承  吴鑫  钱晨阳 《盐湖研究》2010,18(1):21-28

湖积物中不同无机碳酸盐矿物常常混杂在一起,其氧同位素组成(δ18O)差异会影响碳酸盐δ18O环境信息提取的可靠性。不同矿物之间δ18O差值明显且幅度不一。20~25℃时生成的白云石比共生的方解石富集18O可能为0‰~9‰不等,亦或方解石比白云石可能更富集18O达0‰~12.3‰。常温状态,相同条件下形成的文石δ18O值较方解石高出0‰~1‰,或者方解石较文石δ18O值高出0‰~4.47‰。镁方解石中MgCO3的mol百分含量每增加1%,其δ18O值相对于纯方解石δ18O值增加0.06‰~0.17‰。在利用碳酸盐δ18O进行气候及环境研究时,不能根据某种差值进行校正,而应进行单矿物测试。由此,对不同无机碳酸盐矿物的分离及同位素测试、推算方法进行了归纳和述评。  相似文献   

Origin of CO_2 in natural gas from the Triassic Feixianguan Formation of Northeast Sichuan Basin     

HUANG SiJing  HUANG KeKe  TONG HongPeng  LIU LiHong  SUN Wei & ZHONG QianQian State Key Lab of Oil  Gas Reservoir Geology  Exploitation 《中国科学:地球科学(英文版)》2010,(5)

The natural gas from the Triassic Feixianguan Formation of Northeast Sichuan Basin contains high H2S whereas relatively low CO2 concentrations and the CO2 display high δ13C values (ranging from -5.81‰ to 3.3‰ (PDB)). This seems to contradict the conventional wisdom that TSR should be a primary source of CO2 in natural gas from the Feixianguan Formation. In contrast, many authigenic calcite samples from these sites display very low δ13C values (ranging from -18.4‰ to -10.3‰ (PDB)). This suggests that the carbon from TSR source dominated the formation of calcite whereas the carbon from inorganic source came into CO2 in natural gas. In order to assess the origin of CO2 from these H2S-rich sites, we have calculated the relative contributions of organic and inorganic carbon sources to the CO2 and authigenic calcite. The organic carbon source possibly originated from TSR, whereas the inorganic one might be generated from marine carbonates dissolution. This calculation is based on the carbon isotopic compositions of CO2 and authigenic calcite as well as an isotopic mass balance. The results show that the contribution of organic carbon source to the CO2 is only 2%, whereas that to authigenic calcite is as high as 43% on average. Such results combined with thermodynamic evidence indicate that the isotopically light CO2 produced by TSR process may contribute to authigenic calcite precipitation during burial diagenesis. Distinguishable from Ordovician reservoir of Tarim Basin, Feixianguan reservoir of Northeast Sichuan Basin experienced rapid tectonic uplift due to Yanshanian movement after TSR occurred. Such tectonic event could induce temperature decrease and further promote carbonates dissolution. During these processes, secondary porosity has developed in Feixianguan carbonate reservoirs. Therefore, much attention should be paid to the structural highs in search of high quality carbonate reservoirs.  相似文献   

融合生态学和提升岩溶水数值模拟技术的国际前沿研究   总被引：2，自引：1，他引：1  

姜光辉 《中国岩溶》2016,35(1):1-4

岩溶水由于其脆弱性和非均质性被认为是水文地质领域的重点研究方向。2015年6月在英国伯明翰大学举办的岩溶水国际会议吸引了世界上100多位长期从事岩溶水研究的学者参加,会议从岩溶地质、岩溶水模拟、特殊生态系统、岩溶环境以及水文地质技术方法五个方面进行研讨,提出了很多新认识。例如利用岩溶水模拟进行管道位置的预测;发展分布式混合水流模型已经成为岩溶水模拟的主流;开展岩溶含水层地下生物多样性的调查;注重岩溶环境的评价、科普和保护的衔接等。未来岩溶水研究的动向具有以下特征:（1）岩溶水的研究范畴将扩大到生态学领域;（2）岩溶水模拟的精度将得到显著提高;（3）与人类健康有关的岩溶环境得到更多的关注。为此建议中国地质调查项目跟上国际岩溶水研究的形势,提高地质调查成果的科技含量,尽快实现模型化,增强服务社会的功能。   相似文献   

燕山地区1.6～1.0Ga时期碳酸盐岩碳、氧同位素组成、演化及其地质意义          下载免费PDF全文

旷红伟  李家华  彭楠  罗顺社  岑超 《地学前缘》2009,16(5):118

依据实测的燕山地区(1.6～1.0Ga)高于庄组—景儿峪组114个碳、氧同位素数据,研究、讨论了中、新元古界碳酸盐岩碳、氧同位素组成、演化及其地质意义。研究表明,燕山中、新元古界由下至上的地层序列上,碳、氧同位素表现明显的旋回性演化特征,二者多显正相关关系;δ13C在-3‰～3‰区间低幅、高频振荡;δ18O则表现为-2‰～-8‰的高幅、高频波动;δ13C值的增大与沉积环境由潮间向潮下演变、海平面上升、海水变淡、生物量增多相关;降低的δ13C多代表潮间—潮上环境。高于庄组瘤状灰岩及洪水庄组页岩δ13C为低负值,代表最大海泛期沉积。氧同位素组成和变化指示研究区总体为咸化环境,杨庄组上部和雾迷山组下部古海水盐度最高,之后盐度逐渐降低,至雾迷山组上部又有所升高。研究区与天津蓟县和北京十三陵地区的中、新元古代碳酸盐岩碳、氧同位素组成与演化表现出明显的相似性,反映了它们共同受燕山裂陷槽发育的控制;同时,与北美Belt超群和俄罗斯乌拉尔里菲期碳酸盐岩碳、氧同位素组成、演变的高度协同性,又说明了中、新元古代碳酸盐岩中碳、氧同位素组成、演化响应于全球古海洋背景和地球化学条件。  相似文献   

Carboniferous foraminifers from the lower part of Paleo-Tethyan seamount-type carbonates in the Changning-Menglian Belt, western Yunnan, Southwest China     

Tin Tin LATT  Tsutomu NAKAZAWA  WANG Xiang-dong  Katsumi UENO 《地球学报》2009,30(Z1):35-36

The Changning-Menglian Belt in West Yunnan, Southwest China is well-known as a closed remnant of the Paleo-Tethys Ocean in East Asia (Wu et al., 1995; Liu et al., 1996). It is delineated to the east with the Lincang Massif by the Changning-Shuangjiang Fault and to the west with the Baoshan Block by the Kejie-Nandinghe Fault, and is generally subdivided into three zones: east, central, and west zones. In the central zone, various kinds of oceanic rocks such as harzburgite, cumulate websterite, gabbro, both mid-oceanic ridge basalt and oceanic island basalt, Devonian-Triassic radiolarian chert, and Carbonifer-ous-Permian massive and huge carbonates with basaltic effusives as their pedestal are exposed (Liu et al., 1991, 1996; Wu et al., 1995; Ueno et al., 2003). These Central zone rocks are now interpreted to have been emplaced as nappes structurally overlying the East and West zones, which are considered as consisting mainly of passive margin sediments of the Baoshan Block (Wu, 1991; Ueno et al., 2003).  相似文献   

Authigenic carbonate precipitates from the NE Black Sea: a mineralogical,geochemical, and lipid biomarker study   总被引：1，自引：0，他引：1  

A. Bahr  T. Pape  G. Bohrmann  A. Mazzini  M. Haeckel  A. Reitz  M. Ivanov 《International Journal of Earth Sciences》2009,98(3):677-695

Carbonate precipitates recovered from 2,000 m water depth at the Dolgovskoy Mound (Shatsky Ridge, north eastern Black Sea) were studied using mineralogical, geochemical and lipid biomarker analyses. The carbonates differ in shape from simple pavements to cavernous structures with thick microbial mats attached to their lower side and within cavities. Low δ¹³C values measured on carbonates (−41 to −32‰ V-PDB) and extracted lipid biomarkers indicate that anaerobic oxidation of methane (AOM) played a crucial role in precipitating these carbonates. The internal structure of the carbonates is dominated by finely laminated coccolith ooze and homogeneous clay layers, both cemented by micritic high-magnesium calcite (HMC), and pure, botryoidal, yellowish low-magnesium calcite (LMC) grown in direct contact to microbial mats. δ¹⁸O measurements suggest that the authigenic HMC precipitated in equilibrium with the Black Sea bottom water while the yellowish LMC rims have been growing in slightly ¹⁸O-depleted interstitial water. Although precipitated under significantly different environmental conditions, especially with respect to methane availability, all analysed carbonate samples show lipid patterns that are typical for ANME-1 dominated AOM consortia, in the case of the HMC samples with significant contributions of allochthonous components of marine and terrestrial origin, reflecting the hemipelagic nature of the primary sediment.  相似文献   

Oligo–Miocene seagrass‐influenced carbonate sedimentation along a temperate marine palaeoarchipelago,Padthaway Ridge,South Australia     

NICHOLAS K. RIORDAN  NOEL P. JAMES  YVONNE BONE 《Sedimentology》2012,59(2):393-418

Oligo–Miocene carbonates associated with the Padthaway Ridge form the southern margin of the Murray Basin, South Australia. The carbonates are a thin, somewhat condensed succession of echinoid and bryozoan‐rich limestones that record accumulation in the complex of islands and seaways and progressive burial of the Ridge through time. The rocks are grainy to muddy bioclastic packstones, grainstones and floatstones, composed of infaunal echinoderms, bryozoans, coralline algae and benthic foraminifera, with lesser contributions from molluscs and serpulid worms. Locally as much as half of these skeletal components are Fe‐stained, relict grains that imbue the lithologies with a conspicuous yellow to orange hue. This variably lithified succession is partitioned into metre‐scale, firmground‐bounded and hardground‐bounded beds textured by extensive Thalassinoides burrows. Dominant lithologies are interpreted as temperate seagrass facies. Limestones contain attributes indicative of both seagrass‐dominated palaeoenvironments and carbonate production and accumulation on unconsolidated, barren sandflat palaeoenvironments. Together these two depositional systems are thought to have generated a single multigenerational, amalgamated facies recording sedimentation within a complex temperate seagrass environment. Limestones overlying the Padthaway Ridge reflect a gradually warming climate, increasing water temperature and decreasing nutrient content, within the framework of a ridge gradually being buried in sediment. This succession from cool–temperate to warm–temperate to subtropical through time permits recognition of the relative influence of changing oceanography on a seagrass‐dominated shallow inter‐island sea floor. Criteria are proposed herein to enable future recognition of similar temperate seagrass facies in Cenozoic limestones elsewhere.  相似文献   

皖南新元古代冰期地层再认识     

关成国  万斌  陈哲  傅强 《地层学杂志》2012,(3):611-619

前人认为皖南地区新元古代冰期地层存在两套冰碛岩。通过对皖南蓝田新元古界剖面和皖南地区的另外3条新元古界剖面的重新观察,发现该剖面只存在一套冰碛层和一套盖帽白云岩,均未发现间冰期地层。植被覆盖和地层错断是造成前人认为本地区新元古代冰期地层存在两套冰碛层和两套盖帽白云岩的主要原因。这一套冰碛层与中国南方扬子区南华系南沱组相当。  相似文献   

莺歌海盆地莺歌海组二段泥岩盖层封闭性综合评价   总被引：2，自引：0，他引：2  

冯冲  黄志龙  童传新  朱建成  范泓澈  刘江涛 《地球科学与环境学报》2011,33(4):373-377

通过实测莺歌海盆地莺歌海组二段泥岩盖层的排替压力,建立了盖层排替压力与声波时差的线性关系,进而提出了利用声波时差及地震速度资料求取排替压力的方法.接着,利用测井声波时差和地震速度资料,按等效深度法确定莺歌海组二段下部泥岩盖层的超压分布.综合考虑盖层累计厚度、排替压力、剩余压力、气藏内部压力、断裂对盖层破坏程度和天然气本...  相似文献   

Oxygen and carbon isotope composition of Gordon Group carbonates (Ordovician), Florentine Valley,Tasmania, Australia     

C. Prasada Rao  B. Wang 《Australian Journal of Earth Sciences》2013,60(3):305-316

The Gordon Group carbonates consist of biota of the Chlorozoan assemblage, diverse non‐skeletal grains and abundant micrite and dolomite, similar to those of modern warm water carbonates. Cathodoluminescence studies indicate marine, meteoric and some burial cements. Dolomites replacing burrows, mudcracks and micrite formed during early diagenesis.

δ¹⁸O values (‐5 to ‐7%ō PDB) of the non‐luminescent fauna and marine cement are lighter than those of modern counterparts but are similar to those existing within low latitudes during the Ordovician because of the light δ¹⁸O values of Ordovician seawater (‐3 to ‐5%o SMOW). The δ¹⁸O difference (2%o) between marine and meteoric calcite indicates that Ordovician meteoric water was similar to that in modern subtropics. Values of δ¹³C relative to δ¹⁸O indicate that during the Early Ordovician there were higher atmospheric CO₂ levels than at present but during the Middle and Late Ordovician they became comparable with the present because of a change from ‘Greenhouse’ to glacial conditions. δ¹⁸O values of Late Ordovician seawater were heavier than in the Middle Ordovician mainly because of glaciation.

Dolomitization took place in marine to mixed‐marine waters while the original calcium carbonate was undergoing marine to meteoric diagenesis.  相似文献