沉积盆地深部流体的地球化学特征及油气成藏效应初探   总被引：34，自引：0，他引：34  

金之钧  张刘平等 《地球科学》2002,27(6):659-665

以济阳坳陷东营凹陷和塔里木盆地塔中地区为例，在前人深部流体研究的基础上，应用同位素地球化学、有机地球化学及热力学定量模型，对沉积盆地深部流体的活动特征及其油气成藏效应进行了初步的探讨。研究表明，在东营凹陷不仅存在着幔源富二氧化碳流体（H2O＋CO2）的活动，而且还存在着幔源富氢流体（H2O＋CH4＋H2）的活动。塔里木盆地塔中地区也发现了幔源富二氧化碳的活动。深部流体上升过程中热能传递的定量研究表明，幔源流体是良好的热能载体。东营凹陷和塔中地区的有机质异常热变现象证实了深部流体的热效应。有机质热演化生烃不仅需要热，而且是个缺氢的过程，富氢流体注入沉积盆地势必对油气的生成产生影响。加氢热模拟实验结果表明，加氢可大幅度提高烃源岩的产烃率；对腐泥型干酪根而言，加氢生烃效应最显著的阶段是在生烃高峰之后，产率可增加147％以上；腐植型干酪根的加氢生烃效应在各个阶段都较显著。在东营凹陷和塔中地区分别发现了深部流体促进烃源岩生烃的现象。因此，深部流体在能量上和物质上对油气的生成均可构成重要的影响。  相似文献   

柴北缘绿梁山地区辉长岩的锆石U-Pb年龄及意义   总被引：11，自引：0，他引：11  

袁桂邦  王惠初  李惠民  郝国杰  辛后田  张宝华  王青海  田琪 《华北地质》2002,25(1):36-40

柴达木盆地北缘绿梁山地区的辉长岩侵入到古生代滩间山群及超基性岩中 ,地球化学、微量元素、稀土元素显示出源幔特征。选自其中的锆石明显具岩浆型锆石特点 ,4个单颗粒锆石U -Pb同位素年龄均为谐和年龄 ,2 0 6 Pb 2 38U表面年龄统计权重平均值为 (496 .3± 6 .2 )Ma ,代表了该岩体的结晶年龄 ,从而间接地否定了本区滩间山群的时代为晚奥陶世 -志留纪的认识。辉长岩与滩间山群是柴北缘活动大陆边缘火山岛弧的组成部分。此类岩体同位素地质年龄的确定对柴北缘榴辉岩、滩间山群时代及大地构造性质的重新认识具有重要意义  相似文献   

Constraints on the application of carbon isotope thermometry in high- to ultrahigh-temperature metamorphic terranes   总被引：7，自引：0，他引：7  

M. Satish-Kumar  H. Wada  M. Santosh 《Journal of Metamorphic Geology》2002,20(3):335-350

Nine marble horizons from the granulite facies terrane of southern India were examined in detail for stable carbon and oxygen isotopes in calcite and carbon isotopes in graphite. The marbles in Trivandrum Block show coupled lowering of δ¹³C and δ¹⁸O values in calcite and heterogeneous single crystal δ¹³C values (? 1 to ? 10‰) for graphite indicating varying carbon isotope fractionation between calcite and graphite, despite the granulite facies regional metamorphic conditions. The stable isotope patterns suggest alteration of δ¹³C and δ¹⁸O values in marbles by infiltration of low δ¹³C–δ¹⁸O‐bearing fluids, the extent of alteration being a direct function of the fluid‐rock ratio. The carbon isotope zonation preserved in graphite suggests that the graphite crystals precipitated/recrystallized in the presence of an externally derived CO₂‐rich fluid, and that the infiltration had occurred under high temperature and low f_O2 conditions during metamorphism. The onset of graphite precipitation resulted in a depletion of the carbon isotope values of the remaining fluid+calcite carbon reservoir, following a Rayleigh‐type distillation process within fluid‐rich pockets/pathways in marbles resulting in the observed zonation. The results suggest that calcite–graphite thermometry cannot be applied in marbles that are affected by external carbonic fluid infiltration. However, marble horizons in the Madurai Block, where the effect of fluid infiltration is not detected, record clear imprints of ultrahigh temperature metamorphism (800–1000 °C), with fractionations reaching <2‰. Zonation studies on graphite show a nominal rimward lowering δ¹³C on the order of 1 to 2‰. The zonation carries the imprint of fluid deficient/absent UHT metamorphism. Commonly, calculated core temperatures are > 1000 °C and would be consistent with UHT metamorphism.  相似文献   

Analyzing CO2 emissions mitigation by technology improvement in Central and Eastern Europe     

Diana Ürge-Vorsatz  Adam Szeszler 《GeoJournal》2002,57(3):211-226

As a legacy of the centrally planned economy, the economies in transition of Central and Eastern Europe (CEE) have a unique potential to reduce their greenhouse gas emissions through the improvement in their high energy intensities. Since much of this `low-hanging fruit' in energy-efficiency improvements can be highly cost-effective, many developed countries facing difficulties in meeting their greenhouse gas (GHG) emission targets domestically are eager to find such opportunities in the CEE region. Therefore, studies analysing the potentials and costs of carbon dioxide reduction through technology improvement in the region have come into the limelight. While there are a few excellent studies in the region aimed at analysing climate change abatement potentials, they all embark on different assumptions, methodologies and boundary conditions. It is hence difficult, if not impossible, to compare and analyse the results of these studies across different authors, countries or time horizons. Consequently, the purpose of this paper is to place four leading studies on GHG mitigation through technology improvement from the CEE region into an internationally comparable framework. Four studies were selected from three countries, Poland, Hungary and Estonia, which are all the results of major national and international efforts to assess costs and potentials of GHG reduction. The paper places their assumptions, methods and final results into a framework which enables policy-makers and project designers to compare these across geographical and technological boundaries. Since other studies from around the globe have been analysed in this framework in the literature, this paper provides a vehicle for the findings of these four studies to be compared to others worldwide. In addition, the paper highlights a few areas where similar studies to be completed in the future in the region may be enhanced by incorporating features used in GHG mitigation research in other parts of the world. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

云南腾冲地块北部空树河组一个菱铁矿结核中的C、O同位素变化特征     

金小赤 《地球学报》2002,23(1):37-41

空树河组是滇西腾冲地块北部的石碳－二叠纪冈瓦纳相沉积。菱铁矿结核见于该组顶部的黑色泥岩中。将一个结核通过中心切开，在切面上由中心向边缘用牙钻等间隔提取10个样品。同位素测试结果显示，δ^13C自中心向边缘逐渐由－8．09％减为－16．12％，最外一个样例外（－15．39‰），而δ^18O自中心向边缘逐渐由－10．64‰增加为0‰左右。δ^13C的变化情况表明，菱铁矿结核可能形成于硫酸盐还原带。在解释δ^18o的变化情况时，推测在结核开始生长时可能有δ^18O亏损的大气降水掺入，随着埋藏深度的逐渐加大，孔隙水的O同位素逐渐趋近正常海水的值（0‰）。  相似文献   

Study on Paleoenvironment since Late Glacial Eooch in Lanzhou Area, China     

Yang Guifang  Yin Hongfu  Li ChangAn 《中国地质大学学报(英文版)》2002,13(1)

The Hongzuisi Section in Lanzhou area is used to infer the paleoclimate since the late glacial epoch. Through combined analysis of organic carbon isotope and CaCO3 content, paleoenvironment evolution of Hongzuisi Section since the late glacial epoch is discussed. There were changes in both drymoist and warm-cold. Especially the climate changes can be compared with synchronous sections of other areas, which provides useful information for our future forecast.  相似文献   

近20年海南岛森林生态系统碳储量变化   总被引：49，自引：2，他引：49  

曹军  张镱锂  刘燕华 《地理研究》2002,21(5):551-560

热带森林在碳循环研究中有重要作用。根据目前森林碳储量的计算方法和海南森林资源二类调查数据 ,估算了不同时段的碳储量 ,并分析其动态变化特点。结果表明 :海南森林碳储量从 1979年的 30 4 5TgC增加到 1998年的 37 74TgC ,年均增加 0 36 4 5TgC ,增长率为1 19% ,是全国平均增长率的 2 5倍 ;海南森林在碳循环中起不断增强的碳汇作用 ;森林碳密度呈加速减少趋势 ,储碳潜力将很大 ;随着海南全面禁止采伐和封育等林业措施的实施 ,森林面积扩大 ,林龄结构改善 ,储碳能力将进一步提高 ,海南森林在全国或全球碳循环中的作用和社会价值与意义将日渐突出。通过对碳储量计算不确定性的分析和讨论 ,提出应加强对森林群落各层次生物量的实测与实地监测研究 ,统一计算方法 ,以提高碳储量计算的精度  相似文献   

Floodplain–river ecosystems: lateral connections and the implications of human interference     

Martin C. Thoms   《Geomorphology》2003,56(3-4):335

Floodplains are ecotones that form a transition between aquatic and terrestrial environments. These important ecosystems can be described as dynamic spatial mosaics in which water plays an important role in connecting various patches on the floodplain surface. Hydrological connections facilitate the exchange of carbon and nutrients between the river channel and the floodplain and therefore influence the productivity of the entire river system. This paper examines the influence of hydrological connections on the potential exchange of dissolved organic carbon between a large Australian floodplain to a river channel, and the effects of land and water developments on these exchanges. The paper proposes that an understanding of floodplain ecosystems requires an interdisciplinary approach—a recognition of the importance of the three disciplines hydrology, geomorphology and ecology. Large-scale water-resources and floodplain development has significantly altered the spatial and temporal patterns of hydrological characteristics in the Lower Balonne floodplain, Australia. The magnitude, frequency and duration of flooding events have all been reduced. The construction of levees and water storages has also reduced the reactive floodplain surface area. The presented data show the impacts of these changes on the potential supply of dissolved organic carbon from the floodplain surface during periods of inundation. Annual reductions of up to 1293 tonnes of dissolved organic carbon supply were noted and reductions were especially significant for floods with an average recurrence interval of 2 years or less. Some small flood events no longer facilitate the potential supply of dissolved organic carbon from the floodplain to the river channel because of water-resources and floodplain developments.  相似文献   

油气化探中甲烷碳同位素应用、存在问题与对策研究   总被引：5，自引：2，他引：5  

黎绍杰 《矿产与地质》2003,17(1):54-58

阐述了在地表油气化探实践当中甲烷碳同位素对地表土壤烃气成因判别的有效性，但有时也会遇到判断错误的情况。通过对应用实例的分析，指出因忽略了土壤中异常甲烷是一种混合成因甲烷，从而导致判断失误。为全面解决这一问题，提出了同时选送数量相当的背景土壤样品和异常样品进行甲烷同位素测定，然后通过教学方法计算出真实反映来源于油气藏中的甲烷的碳同位素值的对策方案。  相似文献   

南秦岭下地壳组成及岩石圈的拆离俯冲作用   总被引：3，自引：3，他引：3       下载免费PDF全文

路凤香王春阳胡宝群吴其反  郑建平 《中国地质》2003,30(2):113-119

根据新提供的Pb同位素组成及岩石地球化学研究成果，本文进一步证实了位于北秦岭北界的明港地区发育的早中生代安山玄武质火山角砾岩岩筒所携带的下地壳捕虏体属于南秦岭。所恢复的南秦岭下地壳剖面自下而上为：底侵成因的变辉长岩-基性麻粒岩(其中含有榴辉岩及辉石岩的透镜体)-酸性麻粒岩。秦岭造山带总体的岩石因模型为：南秦岭(扬子块体)向北拆离俯冲，北秦岭地壳向华北仰冲，华北岩石因呈楔状插入秦岭造山带，拆离面约在中、下地壳之间。南秦岭俯冲岩片延伸的范围在平面上有可能达到400km。  相似文献