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61.
Abstract The tectonic history of the Okcheon Metamorphic Belt (OMB) is a key to understanding the tectonic relationship between South Korea, China and Japan. The petrochemistry of 150 psammitic rocks in the OMB indicates that the depositional environment progressively deepened towards the northwest. These data, combined with the distribution pattern of oxide minerals and the abundance of carbonaceous material, support a half‐graben basin model for the OMB. Biotite and muscovite K–Ar dates from metasediments in the central OMB range from 102 to 277 Ma. K–Ar ages of 142–194 Ma are widespread throughout the area, whereas the older ages of 216–277 Ma are restricted to the metasediments of the middle part of the central OMB. The younger (Cretaceous) ages are only found in metasediments that are situated near the Cretaceous granite intrusions. The 216–277 Ma dates from weakly deformed areas represent cooling ages of M1 intermediate pressure/temperature (P/T) metamorphism. The relationship between age distribution and deformation pattern indicates that the Jurassic muscovite and biotite dates can be interpreted as complete resetting ages, caused by thermal and deformational activities associated with Jurassic granite plutonism. Well‐defined 40Ar/39Ar plateau ages of 155–169 Ma for micas from both metasediments and granitic rocks can be correlated with the main Jurassic K–Ar mica ages (149–194 Ma). U–Pb zircon dates for biotite granite from the southwest OMB are 167–169 Ma. On the basis of the predominantly Jurassic igneous and metamorphic ages and the uniformity of d002 values for carbonaceous materials in the study area, it is suggested that the OMB has undergone amphibolite facies M2 metamorphism after M1 metamorphism. This low P/T M2 regional thermal metamorphism may have been caused by the regional intrusion of Jurassic granites. The OMB may have undergone tectono‐metamorphic evolution as follows: (i) the OMB was initiated as an intraplate rift in the Neoproterozoic during break‐up of Rodinia, and may represent the extension of Huanan aulacogen within the South China block; (ii) sedimentation continued from the Neoproterozoic to the Ordovician, perhaps with several unconformities; (iii) M1 intermediate P/T metamorphism occurred during the Late Paleozoic due to compression caused by collision between the North and South China blocks in an area peripheral to the collision zone; and (iv) during the Early to Middle Jurassic, north‐westward subduction of the Farallon‐Izanagi Plate under the Asian Plate resulted in widespread intrusion of granites, which triggered M2 low P/T regional thermal metamorphism in the OMB. This event also formed the dextral Honam shear zone at the boundary between the OMB and Precambrian Yeongnam massif.  相似文献   
62.
An interdisciplinary approach based on high-resolution physical stratigraphy, biostratigraphy, organic matter analysis and clay mineralogy has been applied to the mixed siliciclastic/carbonate Kimmeridgian/Tithonian deposits of the Boulonnais (north-western France). These rocks are the age-equivalents of some of the offshore marine source rocks of the North Sea and were deposited in an overall storm-dominated homoclinal ramp setting which may represent one of the most shore-proximal sediments of this age cropping out in north-western Europe. Comparison with data from the Yorkshire, Dorset, Lorraine and Aquitaine areas allows the discrimination of three major transgressive-regressive sediment packages with disconformities of interregional extent: (1) from the Baylei Zone to top Eudoxus Zone; (2) from the Autissiodorensis Zone to base Scitulus Zone; (3) from the upper Scitulus Zone to the Pectinatus Zone. The lower two regionally correlative disconformities correspond to the sequence boundaries at the top of the Eudoxus Zone and the top of the Autissiodorensis Zone, formed by high-frequency relative sea-level variations during the periods of maximum transgression of the platform. The latter disconformity (the P1 nodule bed) reflects a major tectonically induced reorganization of the north-west European intrashelf sedimentary basin, characterized by a shift in both the location of the main depocentre and the sources of sediment production.  相似文献   
63.
During the FOS-DECAFE experiment at Lamto, Ivory Coast, in January 1991, various ground studies were undertaken simultaneously in order to investigate the physical and chemical characteristics of smoke emitted by savanna biomass burning. Here we present sunphotometer ground-based results which allow the measurements of the spectral optical depth between 450 and 850 nm, the atmospheric water vapour content and the particle size distribution spectrum. The carbonaceous content of the savanna biomass burning aerosols is also investigated. This is the first time that the physical characteristics of particles emitted by savanna plumes are obtained from ground-field studies. All the results suggest that a rapid aging of the smoke occurs first hundred metres from the savanna fire èmission source. They show a relationship between the optical properties of smoke and the chemical aging of the aerosols primarily due to particle growth and a loss of organic material relative to the black carbon content.  相似文献   
64.
The aluminum-rich (>10 wt% Al2O3) objects in the CH carbonaceous chondrite North West Africa (NWA) 739 include Ca,Al-rich inclusions (CAIs), Al-rich chondrules, and isolated mineral grains (spinel, plagioclase, glass). Based on the major mineralogy, 54 refractory inclusions found in about 1 cm2 polished section of NWA 739 can be divided into hibonite-rich (16%), grossite-rich (26%), melilite-rich (28%), spinel-pyroxene-rich (16%) CAIs, and amoeboid olivine aggregates, (AOA's, 17%). Most CAIs are rounded, 25–185 μm (average=70 μm) in apparent diameter, contain abundant, tiny perovskite grains, and typically surrounded by a single- or double-layered rim composed of melilite and/or Al-diopside; occasionally, layers of spinel+hibonite and forsterite are observed. The AOAs are irregularly shaped, 100–250 μm (average=175 μm) in size, and consist of forsterite, Fe,Ni-metal, and CAIs composed of Al-diopside, anorthite, and minor spinel. One AOA contains compact, rounded melilite-spinel-perovskite CAIs and low-Ca pyroxene replacing forsterite. The Al-rich (>10 wt% bulk Al2O3) chondrules are divided into Al-diopside-rich and plagioclase-rich. The Al-diopside-rich chondrules, 50–310 μm (average=165 μm) in apparent diameter, consist of Al-diopside, skeletal forsterite, spinel, ±Al-rich low-Ca pyroxene, and ±mesostasis. The plagioclase-rich chondrules, 120–455 μm (average=285 μm) in apparent diameter, are composed of low-Ca and high-Ca pyroxenes, forsterite, anorthitic plagioclase, Fe,Ni-metal nodules, and mesostasis. The isolated spinel occurs as coarse, 50–125 μm in size, subhedral grains, which are probably the fragments of Al-diopside chondrules. The isolated plagioclase grains are too coarse (60–120 μm) to have been produced by disintegration of chondrules or CAIs; they range in composition from nearly pure anorthite to nearly pure albite; their origin is unclear. The Al-rich objects show no evidence for Fe-alkali metasomatic or aqueous alteration; the only exception is an Al-rich chondrule fragment with anorthite replaced by nepheline. They are texturally and mineralogically similar to those in other CH chondrites studied (Acfer 182, ALH85085, PAT91467, NWA 770), but are distinct from the Al-rich objects in other chondrite groups (CM, CO, CR, CV). The CH CAIs are dominated by very refractory minerals, such as hibonite, grossite, perovskite and gehlenitic melilite, and appear to have experienced very low degrees of high-temperature alteration reactions. These include replacement of grossite by melilite, of melilite by anorthite, diopside, and spinel, and of forsterite by low-Ca pyroxene. Only a few CAIs show evidence for melting and multilayered Wark-Lovering rims. These observations may suggest that CH CAIs experienced rather simple formation history and escaped extensive recycling. In order to preserve the high-temperature mineral assemblages, they must have been efficiently isolated from the hot nebular region, like some chondrules and the zoned Fe,Ni-metal grains in CH chondrites.  相似文献   
65.
A combination of ‘bomb spike’ calibration and conventional calibration of AMS 14C dating has been used to determine a detailed age-depth model for a 1-m sediment section collected from a salt marsh in Poole Harbour, southern England. These data were compared with the chronology obtained from 210Pb analysis and 137Cs age markers. We report post bomb values of over 1.46 F14C (> 146% modern 14C), and both the rising and falling limbs of the atmospheric ‘bomb spike’ are identified. Five pre-bomb samples were analysed using multi-target high-precision 2‰ AMS analysis, and after the replicates were combined the one-sigma uncertainty was as low as ± 9 14C yr on some ages. These data, and an additional three normal-precision pre-bomb 14C samples, were calibrated using CALIB 5.0 and the chronology constrained using the ‘prior knowledge’ of independent age markers obtained from the analysis of pollen and spheroidal carbonaceous particle (SCPs). No agreement was found between the 14C ‘bomb spike’ dates and the CRS 210Pb chronology modelled for this sequence. In addition, poor agreement was found between the signal of the 1960s weapons test fallout indicated by the 14C ‘bomb spike’ dates and the timing suggested by the 137Cs data. This disagreement is attributed to the influence of the local discharge of 137Cs from the former UKAEA site at Winfrith. We use our new chronology to confirm the existence of an acceleration in sedimentation rates in Poole Harbour during the last 100 yr previously reported for this site by Long et al. (Long, A.J., Scaife, R.G., Edwards, R.J. 1999. Pine Pollen in intertidal sediments from Poole Harbour, UK; implications for late-Holocene sediment accretion rates and sea-level rise. Quaternary International, 55, 3–16.), and conclude that ‘bomb spike’ 14C calibration dating may offer a more robust alternative to the use of 210Pb chronologies for dating sediment deposition in salt-marsh environments. In addition, we demonstrate how the use of high-precision AMS analysis has the potential for reducing some of the uncertainties involved in the high-resolution dating of recent salt-marsh sediments.  相似文献   
66.
Sawanoike Pond, an artificial reservoir constructed ca. 150 yrs. ago, lies in an area geologically sensitive to acidification and contains water that is presently weakly acidic (pH 5.5; alkalinity 15 eq 1-1). Sediments from a core obtained from the northern part and a core from the central part of the pond were analyzed for organic matter, total organic carbon, total nitrogen, natural and artificial radionuclides, pollen, diatoms, metals and spheroidal carbonaceous particles. A peaty silt layer at the bottom of the central core was replaced by a silt layer initially rich in humic substances, but became more mineral-rich near the surface. Although most of the dominant diatoms throughout the cores were acidophilous taxa, some acidobiontic species increased moderately in abundance after the middle 1960's. Diatom-inferred pH values for the northern core are relatively low before about 1930, then increase, reaching a maximum level between the 1930's and the late 1940's. They then decrease to the surface and reach minimum level during the middle 1980's. Diatom-inferred pH declined by 0.4-0.5 units in the northern core and 0.2-0.3 units in the central core since ca. 1910, when vegetation around the shore changed to a community similar to that of recent years. An increase in labile Pb, Zn, Cd and spheroidal carbonaceous particles, indicative of atmospheric deposition of fossil fuel combustion by-products, preceded the decline in inferred pH. The inferred pH decline of the pond could be an acidification due to acidic precipitation caused by fossil fuel combustion.  相似文献   
67.
东西走向的北喜马拉雅片麻岩穹隆带位于喜马拉雅造山带核心,记录了造山演化和青藏高原隆升的变质与变形信息。对穹隆构造热结构及其变形历史的重建有助于揭示喜马拉雅造山过程。本次研究选取然巴片麻岩穹隆的各类构造岩开展微观构造解析、碳物质拉曼光谱温度估算(RSCM)和石英组构学(CPO)分析,对比该穹隆各构造层变质和变形温度及其变化。研究结果揭示然巴穹隆被上、下两条环形拆离断层分为三个构造层:下拆离断层以下为下构造层,其由核部淡色花岗岩和片麻岩组成;下拆离断层和上拆离断层之间为中构造层,由强烈韧性变形的低-中级变质的片岩和少量片麻岩组成;上拆离断层以上为上构造层,由板岩、千枚岩和少量片岩组成。碳物质拉曼光谱变质温度计估算结果显示下构造层和中构造层峰期变质温度为550~600℃,上构造层峰期变质温度400~550℃。各构造层韧性变形岩石内石英组构(CPOs)特征揭示:下构造层石英以柱面滑移为主,韧性剪切变形温度超过600℃;而从中构造层底部向上构造层,石英滑移系由柱面滑移逐渐转变为底面滑移为主,响应的变形温度由550℃逐渐降低为300~350℃。综合分析解释认为然巴穹隆新生代以来经历了四期构造变形,分别对应喜马拉雅造山演化四个阶段:始新世(约45Ma)地壳增厚,发生区域变质作用,变质峰期温度达600℃(如下构造层记录),由下构造层向幔部递减(500℃到300℃);在造山伸展阶段,伴随藏南拆离系北向韧性剪切作用以及晚期南北向裂谷的启动提供的东西向伸展环境导致晚中新世淡色花岗岩底辟就位(约8~7Ma),穹隆幔部岩石遭受接触变质作用改造,接触变质峰期温度为570℃。  相似文献   
68.
This study covers cosmic spherules derived from the Mesoproterozoic Dahongyu Formation in the Ming Tombs area, Beijing. The cosmic spherules include iron oxide cosmic spherules, carbonaceous chondrites, and atomic iron “steely bead”-shaped cosmic spherules. The mineral assemblage of silicon carbide, forsterite, zircon, and glass spherules and fragments were picked from melt-silicified carbonate of the Mesoproterozoic Dahongyu Formation (ca. 1625 Ma). Cosmic spherule assemblages are solely discovered from sedimentary rocks in China. Platinum group elements (PGE) were determined for the first time in cosmic spherules and associated minerals. PGE comparative observation between meteorite and cosmic spherules is presented in this study. It is recognized that an extraterrestrial meteorite impact event might have occurred in the Dahongyu Stage. The main evidence is a large number of iron cosmic spherules in silicified oncolitic limestone, and associated cosmic silicon carbide, glass spherules, and fragments, as well as the presence of forsterite. The impact-volcanic crater is characteristic of a big black shale block dropped into the bended silicified limestone.  相似文献   
69.
The organic matter of three different chronological major carbonaceous rock gold-bearing formations of South China (Middle Proterozoic Shangqiaoshan group of northeastern Jiangxi, Lower Cambrian Shuikou group of northern Guangxi and Devonian Shetianqiao group of eastern Hunan) and related carbonaceous stratabound gold deposits such as Jinshan, Longshui and Shixia deposits, respectively, has been characterized by organic geochemical techniques. These organic geochemical results show that the average total organic carbon (TOC) content of the three chronological carbonaceous rock gold-bearing formations of South China ranges from 0.15% to 1.56%. The thermal maturity of the organic matter of host rocks in the three gold-bearing formations is high. The micro-component of the organic matter of the host rocks consists primarily of solid bitumen and graphite. The organic carbon and gold of the host rocks appear to syndepositin situ during the formation of the gold-bearing formations. The organic carbon played a certain role in controlling the geochemical environment of the gold-bearing formations. The metallogenetic mechanism of the carbonaceous rock stratabound gold deposits of South China is closely associated in genesis with the sedimentation, diagenesis and thermal evolution history of the organic matter of host rocks in the gold-bearing formations.  相似文献   
70.
碳质球粒陨石是太阳系中最原始的物质之一.通过对碳质球粒陨石的光谱分析,可以建立其与母体小行星之间的联系,有助于探测小行星表面物质成分、研究太阳系早期的演化历史.研究了6个CM2型碳质球粒陨石和11个煤炭样品(碳质球粒陨石所含有机质的地球类比物)可见-远红外谱段反射光谱特征,并分析了它们与有机组分的关系.结果表明,对于不...  相似文献   
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