Geological and geochemical constraints on genesis of the Liziyuan gold-dominated polymetal deposit,western Qinling orogen,central China     

《International Geology Review》2012,54(16):1944-1966

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Chemical composition of rock-forming minerals in granitoids associated with Au–Bi–Cu,Cu–Mo,and Au–Ag mineralization at the Freegold Mountain,Yukon, Canada: magmatic and hydrothermal fluid chemistry and petrogenetic implications     

《International Geology Review》2012,54(6):657-691

The chemical compositions of rock-forming minerals have been determined for both altered and least-altered igneous rocks spatially associated with numerous mineralized zones (Nucleus Au–Bi–Cu–As deposit, Revenue Au ± Cu and Stoddart Cu–Mo ± W mineral occurrences, and Laforma Au–Ag deposit) across the Freegold Mountain area, Yukon, Canada. Within the study area, K-feldspar has a narrow compositional range (89.4–91% Or), whereas plagioclase spans a wide range (4.4–70.07% An). In all of the investigated samples, T _Ab = T _An = T _Or, suggesting that magmatic equilibrium between the coexisting plagioclase and K-feldspar was maintained. Igneous amphibole phenocrysts from hypabyssal dikes are typically calcic, whereas the Stoddart Cu–Mo ± W, Laforma Au–Ag, and Goldy Au mineralization are associated with Mg-enriched primary amphibole of edenite composition, and Au–Bi–Cu–As mineralization from Nucleus is related to Al-enriched primary amphibole of ferropargasite composition. Primary biotite phenocrysts across the Freegold Mountain area re-equilibrated with oxidized magma (f(O₂) values between 10–13 and 10–11.5 bars, lying between the Ni/NiO and the magnetite/haematite buffers). However, biotite and amphibole phenocrysts from Stoddart, Goldy, Laforma, and the Highway zones crystallized from a more oxidized magma, as indicated by their elevated X _Mg up to 0.65, relative to biotite and hornblende from Nucleus and Revenue characterized by a lower X _Mg (typically < 0.50). This suggests that various sources and (or) rapid emplacement were involved in magma genesis, as further supported by the considerable variation of pressure (1.8–7.3 kb) of amphibole crystallization and of the total Al content in least-altered biotite (2.6–2.9 afu) within the Freegold Mountain area. Biotite and apatite equilibrated within the T range of 520–780°C, consistent with temperatures of equilibration between ilmenite and magnetite, and their compositions indicate that they formed from an oxidized I-type magma. Magma differentiated by fractional crystallization (indicated by the presence of normally zoned plagioclase with Ca-rich cores and Na-enriched outer rims) and multiple magma mixing (supported by the presence of reversed zoned plagioclase and coexistence of normally and reversely zoned plagioclase). Lower X _Mg biotite associated with the mineralized (Cu–Mo ± W) potassic alteration incorporated more F and Cl relative to least-altered biotite with higher X _Mg. In both Nucleus and Revenue Au–Cu mineralizations, secondary biotite composition varies with respect to the associated alteration mineral assemblages. Although secondary biotite in the skarn re-equilibrated with F-poor fluids, secondary biotite from the pervasive biotitization is related to F- and Cl-enriched fluids, and secondary biotite from the phyllitic zone is related to F-, Cl-, and Mg-depleted fluids, thus consistent with a change in mineralizing fluid composition during mineralization.  相似文献   

Hydration and dehydration in the lower margin of a cold mantle wedge: implications for crust–mantle interactions and petrogeneses of arc magmas     

《International Geology Review》2012,54(12):1506-1522

Garnet orthopyroxenites from Maowu (Dabieshan orogen, eastern China) were formed from a refractory harzburgite/dunite protolith. They preserve mineralogical and geochemical evidence of hydration/metasomatism and dehydration at the lower edge of a cold mantle wedge. Abundant polyphase inclusions in the cores of garnet porphyroblasts record the earliest metamorphism and metasomatism in garnet orthopyroxenites. They are mainly composed of pargasitic amphibole, gedrite, chlorite, talc, phlogopite, and Cl-apatite, with minor anhydrous minerals such as orthopyroxene, sapphirine, spinel, and rutile. Most of these phases have high X_Mg, NiO, and Ni/Mg values, implying that they probably inherited the chemistry of pre-existing olivine. Trace element analyses indicate that polyphase inclusions are enriched in large ion lithophile elements (LILE), light rare earth elements (LREE), and high field strength elements (HFSE), with spikes of Ba, Pb, U, and high U/Th. Based on the P–T conditions of formation for the polyphase inclusions (?1.4 GPa, 720–850°C), we suggest that the protolith likely underwent significant hydration/metasomatism by slab-derived fluid under shallow–wet–cold mantle wedge corner conditions beneath the forearc. When the hydrated rocks were subducted into a deep–cold mantle wedge zone and underwent high-pressure–ultrahigh-pressure (HP–UHP) metamorphism, amphibole, talc, and chlorite dehydrated and garnet, orthopyroxene, Ti-chondrodite, and Ti-clinohumite formed during prograde metamorphism. The majority of LILE (e.g. Ba, U, Pb, Sr, and Th) and LREE were released into the fluid formed by dehydration reactions, whereas HFSE (e.g. Ti, Nb, and Ta) remained in the cold mantle wedge lower margin. Such fluid resembling the trace element characteristics of arc magmas evidently migrates into the overlying, internal, hotter part of the mantle wedge, thus resulting in a high degree of partial melting and the formation of arc magmas.  相似文献   

水平定向钻进管道敷设地层响应实验分析   总被引：1，自引：0，他引：1  

孙平贺  曹函  乌效鸣  安传德 《地质科技情报》2012,31(3):135-138

在应用水平定向钻进非开挖技术进行近地表管道敷设时,由于上覆地层厚度(C)、钻孔直径(D)和钻井液压力(p)三者无法准确设计,往往会导致地表的变形,进而形成裂缝通道致使地表发生钻井液的溢流.分析了非黏聚力地层的溢流通道形式,同时推导了极限钻井液压力的计算公式.结合室内外实验及应用情况,得出了实测钻井液压力和计算钻井液压力同C/D值的变化规律,即C/D越大,极限钻井液的压力值也就越高.在同一地层中,一般钻井液压力的峰值出现在水平孔段的中间位置.根据C/D值,在保证钻井液不发生溢流的情况下,得出了不同水平孔径范围所对应的上覆地层最小厚度.  相似文献   

盆地动力学研究综述及展望   总被引：1，自引：0，他引：1  

解习农  任建业  雷超 《地质科技情报》2012,(5):76-84

沉积盆地是地球系统的浅层组成部分,是壳-幔、岩石圈-软流圈两级圈层相互作用的浅部表现形式。沉积盆地分析不仅可以揭示不同类型化石能源、沉积型层控矿产、砂岩型铀矿等资源的分布规律,为矿产勘探提供直接依据,而且可以为大地构造演化过程、重大构造事件、全球环境变迁及气候演变提供丰富资料和详细证据。当代盆地分析不断从单一沉积学分析拓展到综合分析,从静态要素分析拓展到过程和动力机制分析。盆地动力学研究内容包括3部分,即以沉积学分析为主的盆地充填动力学、以构造地质学分析为主的盆地形成演化动力学和多学科交叉的盆地流体动力学研究。近10多年来,盆地动力学研究在深水沉积学、高精度层序地层学、源-汇系统、源区剥蚀过程及其深部响应、大陆边缘盆地动力学及盆地流体动力学等方面取得了长足的进展。  相似文献   

中国近海富烃凹陷油气成藏特征     

叶加仁  吴景富  舒誉  吴娟  王卓超 《地质科技情报》2012,(5):105-111

富烃凹陷是当今油气勘探的主战场,中国近海已发现的油气储量主要集中在14个富烃凹陷中。利用钻井、测井、地震及化验测试等资料,结合最新油气勘探成果,从温压系统、储盖组合、热流体活动及油气输导与聚集等方面分析、总结了中国近海典型已证实富烃凹陷的油气成藏特征。研究表明:中国近海富烃凹陷深层超压普遍发育,地温梯度高,复合型温压系统构成,为油气成藏提供了充足的动力;主力储层物性好,发育1～2套优质的区域性盖层,至少存在2套有利的储盖组合;发育多种类型的烃类包裹体,油气主成藏期集中,并存在快速幕式充注现象;发育高效优势输导体系、多种圈闭与油气藏类型,存在多种油气成藏模式,油气呈带状差异富集与分布。  相似文献   

金矿焙烧工艺生产处理液中汞测量不确定度的评定     

胡明  赵东阳  王忠伟 《吉林地质》2012,(3):98-100

本文针对原子荧光对金矿焙烧工艺生产中汞处理液的测定,找出了影响其测量不确定度的因素,建立了数学模型,计算出各不确定度的分量,求出合成标准不确定度及扩展不确定度。  相似文献   

Fluid Inclusions and Hydrogen,Oxygen, Sulfur Isotopes of Nuri Cu‐W‐Mo Deposit in the Southern Gangdese,Tibet     

Lei CHEN  Kezhang QIN  Jinxiang LI  Bo XIAO  Guangming LI  Junxing ZHAO  Xin FAN 《Resource Geology》2012,62(1):42-62

The Nuri Cu‐W‐Mo deposit is located in the southern subzone of the Cenozoic Gangdese Cu‐Mo metallogenic belt. The intrusive rocks exposed in the Nuri ore district consist of quartz diorite, granodiorite, monzogranite, granite porphyry, quartz diorite porphyrite and granodiorite porphyry, all of which intrude in the Cretaceous strata of the Bima Group. Owing to the intense metasomatism and hydrothermal alteration, carbonate rocks of the Bima Group form stratiform skarn and hornfels. The mineralization at the Nuri deposit is dominated by skarn, quartz vein and porphyry type. Ore minerals are chalcopyrite, pyrite, molybdenite, scheelite, bornite and tetrahedrite, etc. The oxidized orebodies contain malachite and covellite on the surface. The mineralization of the Nuri deposit is divided into skarn stage, retrograde stage, oxide stage, quartz‐polymetallic sulfide stage and quartz‐carbonate stage. Detailed petrographic observation on the fluid inclusions in garnet, scheelite and quartz from the different stages shows that there are four types of primary fluid inclusions: two‐phase aqueous inclusions, daughter mineral‐bearing multiphase inclusions, CO₂‐rich inclusions and single‐phase inclusions. The homogenization temperature of the fluid inclusions are 280°C–386°C (skarn stage), 200°C–340°C (oxide stage), 140°C–375°C (quartz‐polymetallic sulfide stage) and 160°C–280°C (quartz‐carbonate stage), showing a temperature decreasing trend from the skarn stage to the quartz‐carbonate stage. The salinity of the corresponding stages are 2.9%–49.7 wt% (NaCl) equiv., 2.1%–7.2 wt% (NaCl) equiv._, 2.6%–55.8 wt% (NaCl) equiv. and 1.2%–15.3 wt% (NaCl) equiv., respectively. The analyses of CO₂‐rich inclusions suggest that the ore‐forming pressures are 22.1 M Pa–50.4 M Pa, corresponding to the depth of 0.9 km–2.2 km. The Laser Raman spectrum of the inclusions shows the fluid compositions are dominated in H₂O, with some CO₂ and very little CH₄, N₂, etc. δD values of garnet are between ?114.4‰ and ?108.7‰ and δ¹⁸O_H2O between 5.9‰ and 6.7‰; δD of scheelite range from ?103.2‰ to ?101.29‰ and δ¹⁸O_H2O values between 2.17‰ and 4.09‰; δD of quartz between ?110.2‰ and ?92.5‰ and δ¹⁸O_H2O between ?3.5‰ and 4.3‰. The results indicate that the fluid came from a deep magmatic hydrothermal system, and the proportion of meteoric water increased during the migration of original fluid. The δ³⁴S values of sulfides, concentrated in a rage between ?0.32‰ to 2.5‰, show that the sulfur has a homogeneous source with characteristics of magmatic sulfur. The characters of fluid inclusions, combined with hydrogen‐oxygen and sulfur isotopes data, show that the ore‐forming fluids of the Nuri deposit formed by a relatively high temperature, high salinity fluid originated from magma, which mixed with low temperature, low salinity meteoric water during the evolution. The fluid flow through wall carbonate rocks resulted in the formation of layered skarn and generated CO₂ or other gases. During the reaction, the ore‐forming fluid boiled and produced fractures when the pressure exceeded the overburden pressure. Themeteoric water mixed with the ore‐forming fluid along the fractures. The boiling changed the pressure and temperature, oxygen fugacity, physical and chemical conditions of the whole mineralization system. The escape of CO₂ from the fluid by boiling resulted in scheelite precipitation. The fluid mixing and boiling reduced the solubility of metal sulfides and led the precipitation of chalcopyrite, molybdenite, pyrite and other sulfide.  相似文献   

Highly Oxidized Magma and Fluid Evolution of Miocene Qulong Giant Porphyry Cu‐Mo Deposit,Southern Tibet,China     

Bo XIAO  Kezhang QIN  Guangming LI  Jinxiang LI  Daixiang XIA  Lei CHEN  Junxing ZHAO 《Resource Geology》2012,62(1):4-18

The Miocene Qulong porphyry Cu‐Mo deposit, which is located at the Gangdese orogenic belt of Southern Tibet, is the largest porphyry‐type deposit in China, with confirmed Cu ～10 Mt and Mo ～0.5 Mt. It is spatially and temporally associated with multiphase granitic intrusions, which is accompanied by large‐scale hydrothermal alteration and mineralization zones, including abundant hydrothermal anhydrite. In addition to hydrothermal anhydrite, magmatic anhydrite is present as inclusions in plagioclase, interstitial minerals between plagioclase and quartz, and phenocrysts in unaltered granodiorite porphyry, usually in association with clusters of sulfur‐rich apatite in the Qulong deposit. These observations indicate that the Qulong magma‐hydrothermal system was highly oxidized and sulfur‐rich. Three main types of fluid inclusions are observed in the quartz phenocrysts and veins in the porphyry: (i) liquid‐rich; (ii) polyphase high‐salinity; and (iii) vapor‐rich inclusions. Homogenization temperatures and salinities of all type inclusions decrease from the quartz phenocrysts in the porphyry to hydrothermal veins (A, B, D veins). Microthermometric study suggests copper‐bearing sulfides precipitated at about 320–400°C in A and B veins. Fluid boiling is assumed for the early stage of mineralization, and these fluids may have been trapped at about 35–60 Mpa at 460–510°C and 28–42 Mpa at 400–450°C, corresponding to trapping depths of 1.4–2.4 km and 1.1–1.7 km, respectively.  相似文献   

内蒙古陈巴尔虎旗谢尔塔拉铁锌矿床成矿流体演化与成矿作用     

袁峰  翟德高  刘家军  毛晓冬  王建平  刘立东  马怀岭  王守光  李玉玺 《地质通报》2012,31(6):954-968

内蒙古谢尔塔拉铁锌矿床位于大兴安岭中段华力西期、燕山期成矿带上,是一个大中型的火山喷发沉积-热液富集型矿床。在对谢尔塔拉铁锌矿床的物质组成分析的基础上,着重对流体包裹体和稳定同位素进行分析,以此来研究该矿床的成矿流体演化和成矿作用。研究表明,从热液作用早期到中期,具有成矿温度递减、盐度升高的趋势,两者呈负相关变化,指示流体发生了沸腾作用;从热液作用中期到晚期,具有成矿温度递减、盐度降低的趋势,两者呈正相关变化,指示流体发生了混合作用。S、Pb、C、H、O同位素组成表明,金属物质主要来自赋矿岩石和下伏地层,同时还有深部岩浆物质的参与。成矿热液为大气降水补给加热的循环地下水和岩浆水组成的的混合流体,后期又有大量的大气降水补充,使得成矿流体与围岩发生了强烈的同位素交换。矿化和蚀变作用是在水/岩比值比较低的体系中进行的。谢尔塔拉铁锌矿床的成矿流体总体表现为中低温、低盐度、低密度的热液。构造热效应、地热梯度和多次的岩浆喷气热是驱动流体活化迁移的主要因素。构造体制转换使流体稳定体系发生改变,压力释放发生沸腾作用,造就铁、锌在有利位置富集成矿。  相似文献