单道扫描电感耦合等离子体发射光谱法测定地质样品中的微量稀土元素     

郭振华  张立英  杜百娟 《化工矿产地质》2003,25(1):57-60

采用Na_2O_2熔融矿样,水提取,加三乙醇胺、EGTA做掩蔽剂。经氢型阳离子交换树脂交换分离富集稀土元素,由于选择了合适的仪器条件及测定波长,有效地消除了电感耦合等离子体发射光谱法(ICP-AES)测定过程中的基体干扰和光谱干扰。应用于地质样品中的稀土元素分析,获得了满意的准确度、精密度及检出限。  相似文献   

桩承载力时效对桩土相互作用及沉降的影响分析   总被引：2，自引：2，他引：2  

郑刚  任彦华 《岩土力学》2003,24(1):65-69

对软土中两根47 m长灌注桩分别在成桩28 d和1 750 d后进行了承载力试验，其极限承载力提高幅度达到30％左右。分析了单桩承载力随时间提高(称为时效)的机理，提出了单桩承载力时效对桩筏基础桩土相互作用影响的分析方法，并结合工程实例进行了分析。  相似文献   

振动沉模大直径现浇薄壁管桩技术及其应用 (Ⅰ):开发研制与设计   总被引：54，自引：25，他引：54  

刘汉龙  费康  马晓辉  高玉峰 《岩土力学》2003,24(2):164-168

振动沉模现浇混凝土薄壁管桩（PCC桩）技术是河海大学自主开发研制的用于地基加固处理的专利技术，是一种适合于软土地区的新型高效优质桩型，可有效地提高地基承载力和减小地基沉降。笔者介绍了振动沉模现浇混凝土薄壁管桩的技术原理、加固机理、施工设备、施工工艺及其设计与质量检测方法。该桩型具有承载力高、质量可靠和工程造价低等优点，具有较大的推广应用价值。  相似文献   

A STUDY ON THE FLOOD STORAGE CAPACITY IN DONGTING LAKE     

Yitian LI  Jinyun DENG  Zhaohua SUN 《国际泥沙研究》2003,18(2)

1 INTRODUCTION Dongting Lake lies south of the middle reach of the Yangtze River in Hunan and Hubei provinces (Fig. 1). On the north side of Dongting Lake, there are the three diversion openings of the Yangtze River named Songzi, Taiping, and Ouchi, and, on the south and west sides, there are the four tributary streams named Xiang, Zi, Yuan, and Li Rivers. The flow of the three diversion openings and the four tributary streams runs into Dongting Lake, and runs out at Chenglingji a…  相似文献   

岩体变形模量的尺寸效应   总被引：2，自引：0，他引：2  

喻勇  肖国强  王法刚 《岩土力学》2003,(Z1)

岩土工程中,现场岩体的承压板试验和变形试验可看作是不同尺寸岩体的变形试验。在某工程的现场岩石力学试验中,对同一组试点的岩体先后进行了承压板变形试验和承载力试验,研究了岩体变形模量的尺寸效应,结果表明,岩体变形模量主要受岩体中的裂隙发育状况控制,当岩体质量较好时,可以由承载力试验曲线来确定岩体的变形特性,这一做法具有一举两得的效果。  相似文献   

An EFTEM/HRTEM high-resolution study of the near surface of labradorite feldspar altered at acid pH: evidence for interfacial dissolution-reprecipitation   总被引：1，自引：0，他引：1  

R. Hellmann  J.-M. Penisson  R. L. Hervig  J.-H. Thomassin  M.-F. Abrioux 《Physics and Chemistry of Minerals》2003,30(4):192-197

Using an approach combining high-resolution and energy-filtered transmission electron microscopy (HRTEM and EFTEM), we have studied with Å to nm-spatial resolution the interfacial region that delimits the near-surface altered zone and non-altered labradorite feldspar after dissolution under acid pH conditions. The interface is characterized by extremely sharp and spatially coincident changes in structure and chemistry. The 500-nm-thick altered zone is depleted in interstitial cations (Ca, Na, K) and Al, a framework element, whereas it is enriched in H, O, and Si. Modeling H⁺-alkali interdiffusion within a 500-nm-thick altered zone shows that volume interdiffusion cannot reproduce the sharp chemical interfaces measured by EFTEM. Based on these new data, we propose that the near-surface altered zone is a result of interfacial dissolution-reprecipitation, and not of preferential leaching of cations and interdiffusion with H⁺. This implies an intrinsic dissolution process that is stoichiometric, where the breaking of bonds and release of interstitial cations and framework elements (Al, Si, and O) to solution occur contemporaneously at equal relative rates from the original fluid–mineral interface.  相似文献   

环电流区中性原子观测特性模拟研究   总被引：2，自引：1，他引：2       下载免费PDF全文

沈超  刘振兴 《地球物理学报》2003,46(1):1-1

为了给双星计划中性原子(ENA)探测仪的研制提供可靠 的理论依据，并为未来中性原子探测数据的分析及研究做好准备，针对双星轨道初步模拟计 算了双星ENA探测仪对磁暴时中性原子的观测特性. 建立了磁暴主相期间环电流离子分布的 一 个近似理论模式，并模拟计算了极轨卫星在极区上空、赤道面以及其他位置上对不同强度磁 暴主相期间环电流区ENA空间角分布及能谱的观测结果. 研究表明，存在环电流区方向和南 北极区环电流粒子沉降带两个中性原子强度极大区域；磁暴越强烈，注入区高度越低，环电 流区观测到的ENA通量越高；处于有利位置的ENA探测器可分辨注入区内边界或注入前沿；EN A探测器能够分辨环电流带离子分布的不均匀性；由于离子交换截面的差异，H，O，He 3种E NA的能谱分布不同；在10～80keV能谱范围内通量较强，易于观测；环电流区H，O两种ENA 通 量较强，有利于观测；而环电流区He ENA通量很弱，不易于观测. 模拟计算研究表明，双星 极轨卫星能够对环电流区ENA进行有效探测；低纬轨道上的ENA探测器也能够对环电流区ENA 进行一些观测；ENA探测器的研制应重视低、中能量范围ENA的探测.  相似文献   

往复荷载作用下矩形钢管混凝土压弯构件承载力计算     

杨有福  韩林海 《地震工程与工程振动》2003,23(5):125-129

本文基于往复荷载作用下矩形钢管混凝土压弯构件的实验结果，比较了国内外比较典型的设计规范(程)，包括英国BS5400(1979)、美国ACI318—99(1999)和AISC-LRFD(1999)、日本AIJ(1997)、欧洲EC4(1994)、中国GJB4142-2000(2001)和福建省地方标准(送审稿)，及本文数值方法在计算往复荷载作用下矩形钢管混凝土压弯构件承载力的差异。结果表明，在进行往复荷载作用下矩形钢管混凝土压弯构件承载力计算时，各种计算方法获得的承载力都偏于安全，其中，数值计算结果与实验结果最接近，GJB4142—2000(2001)的计算结果与实验结果吻合程度稍差，ACI318—99(1999)，EC4(1994)和福建省地方标准(送审稿)的计算结果比实验结果约低20％，而BS5400(1979)、AISC—LRFD(1999)和AIJ(1997)的计算结果比实验结果总体上低30％以上。本文结果可供进行矩形钢管混凝土结构设计时参考。  相似文献   

Atmospheric Methyl Iodide at Cape Grim, Tasmania, from AGAGE Observations     

D. S. Cohan  G. A. Sturrock  A. P. Biazar  P. J. Fraser 《Journal of Atmospheric Chemistry》2003,44(2):131-150

Atmospheric mixing ratios of methyl iodide (CH₃I) and other methyl halides have been measured at Cape Grim, Tasmania (41°S, 145°E), since early 1998 as part of the Advanced Global Atmospheric Gases Experiment (AGAGE). This paper analyses about 1700 ambient air CH₃I measurements from the 14-month period (March 1998–April 1999). Mixing ratios peaked during the summer, despite faster photolytic loss, suggesting local oceanic emissions were about 2.2–3.6 times stronger in summer than in winter. Back trajectories show that CH₃I levels are strongly dependent on air mass origin, with highest mixing ratios in air from the Tasman Sea/Bass Strait region and lowest levels in air originating from the Southern Ocean at higher latitudes. CH₃I mixing ratios were not well correlated with other methyl halides in unpolluted marine air. The large variations with season and air mass origin suggest that high frequency, continuous data from key locations will make a significant contribution to the understanding of sources and sinks of this important short-lived atmospheric species.  相似文献   

A STUDY ON TYPHOON MOVEMENT PART Ⅲ:EFFECT OF THE HORIZONTAL MOMENTUM EXCHANGE BETWEEN TYPHOONS AND ENVIRONMENT     

贺海晏  董惠菁 《热带气象学报(英文版)》1997,3(1):1-10

Two semi-asymmetric flow patterns of typhoons are chosen to qualitatively determine the effect of exchange of horizontal momentum between inflow and outflow layers and the environment on the motion of typhoons. The results show that only the asymmetric flow component (residual after azimuthal mean flow has been removed) could cause a net momentum input into or output from a typhoon and therefore contribute to the changes in speed and direction of the typhoon movement. A typhoon with major inflow and/or outflow channels on its right (left) side would tend to accelerate and turn left (decelerate and turn right); On the other hand, a typhoon with major inflow and/or outflow channels in the rear (front) semicircle would tend to accelerate and turn right (decelerate and turn left).  相似文献