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U. Becker A. Fernández-González M. Prieto R. Harrison A. Putnis 《Physics and Chemistry of Minerals》2000,27(4):291-300
Thermodynamic properties of the barite–celestite solid solution were calculated using molecular principles. Cation–cation
(Ba–Ba, Sr–Sr, and Ba–Sr) interaction energies were derived from a number of random and ordered cation distributions which
were energy-optimized using force potentials as incorporated in the program package GULP. With these interaction energies,
diagrams for the enthalpy and free energy of mixing could be computed for the entire range of the solid solution between the
barite and celestite end members and for a number of annealing temperatures. These thermodynamic data show that the solid
solution is nonideal. The system has a tendency for Ba2+ and Sr2+ cations to order onto alternating layers ||(100). However, this ordering scheme is thermodynamically only relevant for annealing
temperatures below approximately 500 K and systems that are kinetically inhibited during crystal growth. For sufficiently
long annealing times at room temperature, the solid solution tends to exsolve with barite–celestite interfaces ||(100). The
cell parameters a and c were calculated to have almost linear behavior for the whole solid solution, suggesting close to ideal behavior according
to Vegard's law. In contrast, b tends to deviate positively from linearity, in agreement with experimental values.
Received: 6 April 1999 / Revised, accepted: 29 September 1999 相似文献
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Strontium speciation transferring in strontium residue and mixing strontium ore are investigated with extracting experiment, X-ray powder diffraction （XRD）, X-ray fluorescence spectrometer （XRF） and Atomic Absorption Spectroscopy （AAS）. The results show that there are strontium carbonate, strontium sulfate, strontium sulfide, and a little amount of strontium silicate and strontium ferrite in strontium residue. Impurities in strontium residue mainly contain carbonate and oxide of calcium, iron, magnesium and aluminum etc. The amount of strontium sulfide in strontium residue is larger than that in strontium ore. And a little strontium silicate and strontium ferrite are found in strontium ore. It is concluded that acid soluble method is used firstly in the process of producing strontium carbonate from mixing strontium ore. In addition, mechanical smash method and surface active treatment to strontium samples are beneficial to the ratio-leaching increase of strontium. The research achievement helps to save energy and decrease pollutants emission in strontium processing industry. 相似文献
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菊花状天青石是华南地区栖霞组内一种特殊的矿物集合体,形成于早期成岩作用阶段。在研究其成因过程中,系统分析了湖北黄石和湖南浏阳栖霞组内菊花状天青石的Sr同位素组成以及湖南浏阳、湖北黄石、江西永丰和广西来宾四处天青石假象、天青石围岩（泥晶灰岩）和围岩中方解石脉的Sr同位素组成。Sr同位素分析结果表明,天青石中的87Sr/ 86Sr最高值为0.707525,最低值为0.706981,平均值为0.707215。与天青石相比,天青石假象、天青石围岩和方解石脉的87Sr/ 86Sr值整体相对富含87Sr。由于天青石假象和方解石脉明显为晚期成岩作用成因,它们相对富含87Sr的锶同位素特征应是晚期成岩作用叠加的结果,与其类似的泥晶灰岩的87Sr/ 86Sr值也可能同样受到了晚期成岩作用的影响。栖霞组菊花状天青石比同组泥晶灰岩更好地记录了栖霞期海水的Sr同位素组成。 相似文献
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Alan C. Kendall 《Sedimentology》2001,48(1):29-55
Mississippian nodular anhydrites beneath an unconformity in the subsurface of southern Saskatchewan are locally replaced by calcite, pyrite and celestite. Triassic clastics above the unconformity are green, rather than red, and a usually developed subunconformity alteration zone (where carbonates are dolomitized, and porosity is filled with anhydrite) is absent. The unconformity lacks karstic features (unlike in the USA), and probably formed in a hyperarid climate. Mississippian anhydrites near the unconformity are not preferentially dissolved, nor were they extensively hydrated. Anhydrite calcitization occurred only after the unconformity was shallowly buried by redbeds, and it probably involved sulphate-reducing bacteria. Hydrogen sulphide, generated by bacteria, reduced redbed pigments. The replacement calcite contains pseudomorphs and relicts of anhydrite, and pseudomorphs of secondary gypsum. These indicate calcitization occurred only after original Mississippian gypsum was altered to anhydrite and this, in turn, was partially converted back to secondary gypsum beneath the unconformity. Replacement occurred concurrently with the formation elsewhere of the dolomitized zone beneath the unconformity. Sulphur isotopic ratios of replacement pyrite are depleted relative to Mississippian sulphate values, consistent with the activities of sulphate-reducing bacteria. Carbon isotopic ratios of replacive calcites, however, do not support this interpretation, and are identical to those of Mississippian limestones. Simple replacement of sulphate by pore-water bicarbonate (in equilibrium with host limestones) is unlikely because protons generated during the reaction should have created acidic conditions in which calcite would have dissolved. A full explanation of the calcitization remains elusive, but may involve replacement occurring in an active groundwater system and/or bacterial sulphate reduction occurring upstream of the site of calcitization. 相似文献
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沉积岩容矿的天青石矿床是锶最主要的来源.文章对全球该类矿床的资料进行了系统梳理,对矿床的发育特征和成因进行了综述和探讨.研究显示:①该类矿床的产出与含石膏或硬石膏的蒸发盐密切相关,或赋存在碳酸盐岩-蒸发岩沉积建造中,或出现在蒸发岩底辟环境;②多数为后生成因,表现为富锶流体交代石膏或硬石膏,或富锶流体与富硫酸盐流体混合、充填开放空间;少数矿床为同生成因,天青石直接从蒸发环境的水体中沉淀出;③后生天青石矿床中的锶可以来自不同途径,包括盆地流体与富钙矿物相互作用萃取的锶、碳酸盐岩重结晶过程文石转变为方解石或硬石膏转变为石膏释放的锶;同生天青石矿床中的锶来自沉积水体本身,沉积源区岩石提供了锶;④天青石中的硫来源于围岩地层中的石膏或硬石膏,有些矿床中的硫来自发生过硫酸盐还原作用后的(溶解的)石膏/硬石膏,而在个别矿床中,还原硫氧化成硫酸盐提供了部分硫;⑤一些天青石矿床中出现有铅锌硫化物,两者可以有成因关系,也可以无成因关系;⑥少数天青石矿床中重晶石含量较高,与高Ba/Sr流体与富硫酸盐流体混合有关.天青石从低钡流体中结晶时,钡在流体中含量的震荡变化会导致SrSO4-BaSO4固溶体的形成,从而使天青石出现环带或出溶结构. 相似文献
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柴达木盆地西北部锶矿成矿系统研究 总被引：4，自引：0，他引：4
柴达木盆地西北部锶矿床是已知的世界上成矿时代最年轻的大陆热水沉积层控型锶矿床。区内锶矿成矿系统位于印度板块与欧亚板块碰撞带的前陆盆地内 ,其成矿作用发生在陆 -陆碰撞造山带的前缘 ;成矿构造和成矿流体对锶矿床的形成起着重要的控制作用 ;这些锶矿床是矿源场、流体场、能量场在一定时空条件下耦合的产物 相似文献
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论华蓥山地区天青石矿石的两种成因 总被引：3，自引：0，他引：3
本文分析了四川－重庆华蓥山地区天青石矿床的野外宏观特征和微观特征,对三种主要类型的天青石矿石：层状天青石矿石、巨晶天青石矿石和条带状天青石矿石中的暗色条带天青石和白色条带天青石进行了野外产状、结构构造特征、稀土元素含量特征、天青石包裹体成分和包裹体盐度的比较分析,结果表明,层状矿石和条带状矿石中的暗色条带天青石是沉积形成的,巨晶矿石和条带状矿石中的白色条带天青石属热卤水成因。 相似文献