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11.
 Thermodynamic properties of the barite–celestite solid solution were calculated using molecular principles. Cation–cation (Ba–Ba, Sr–Sr, and Ba–Sr) interaction energies were derived from a number of random and ordered cation distributions which were energy-optimized using force potentials as incorporated in the program package GULP. With these interaction energies, diagrams for the enthalpy and free energy of mixing could be computed for the entire range of the solid solution between the barite and celestite end members and for a number of annealing temperatures. These thermodynamic data show that the solid solution is nonideal. The system has a tendency for Ba2+ and Sr2+ cations to order onto alternating layers ||(100). However, this ordering scheme is thermodynamically only relevant for annealing temperatures below approximately 500 K and systems that are kinetically inhibited during crystal growth. For sufficiently long annealing times at room temperature, the solid solution tends to exsolve with barite–celestite interfaces ||(100). The cell parameters a and c were calculated to have almost linear behavior for the whole solid solution, suggesting close to ideal behavior according to Vegard's law. In contrast, b tends to deviate positively from linearity, in agreement with experimental values. Received: 6 April 1999 / Revised, accepted: 29 September 1999  相似文献   
12.
颜佳新  伍明 《古地理学报》2004,6(2):191-195
菊花状天青石是华南地区栖霞组内一种特殊的矿物集合体,形成于早期成岩作用阶段。在研究其成因过程中,系统分析了湖北黄石和湖南浏阳栖霞组内菊花状天青石的Sr同位素组成以及湖南浏阳、湖北黄石、江西永丰和广西来宾四处天青石假象、天青石围岩(泥晶灰岩)和围岩中方解石脉的Sr同位素组成。Sr同位素分析结果表明,天青石中的87Sr/ 86Sr最高值为0.707525,最低值为0.706981,平均值为0.707215。与天青石相比,天青石假象、天青石围岩和方解石脉的87Sr/ 86Sr值整体相对富含87Sr。由于天青石假象和方解石脉明显为晚期成岩作用成因,它们相对富含87Sr的锶同位素特征应是晚期成岩作用叠加的结果,与其类似的泥晶灰岩的87Sr/ 86Sr值也可能同样受到了晚期成岩作用的影响。栖霞组菊花状天青石比同组泥晶灰岩更好地记录了栖霞期海水的Sr同位素组成。  相似文献   
13.
Strontium speciation transferring in strontium residue and mixing strontium ore are investigated with extracting experiment, X-ray powder diffraction (XRD), X-ray fluorescence spectrometer (XRF) and Atomic Absorption Spectroscopy (AAS). The results show that there are strontium carbonate, strontium sulfate, strontium sulfide, and a little amount of strontium silicate and strontium ferrite in strontium residue. Impurities in strontium residue mainly contain carbonate and oxide of calcium, iron, magnesium and aluminum etc. The amount of strontium sulfide in strontium residue is larger than that in strontium ore. And a little strontium silicate and strontium ferrite are found in strontium ore. It is concluded that acid soluble method is used firstly in the process of producing strontium carbonate from mixing strontium ore. In addition, mechanical smash method and surface active treatment to strontium samples are beneficial to the ratio-leaching increase of strontium. The research achievement helps to save energy and decrease pollutants emission in strontium processing industry.  相似文献   
14.
Mississippian nodular anhydrites beneath an unconformity in the subsurface of southern Saskatchewan are locally replaced by calcite, pyrite and celestite. Triassic clastics above the unconformity are green, rather than red, and a usually developed subunconformity alteration zone (where carbonates are dolomitized, and porosity is filled with anhydrite) is absent. The unconformity lacks karstic features (unlike in the USA), and probably formed in a hyperarid climate. Mississippian anhydrites near the unconformity are not preferentially dissolved, nor were they extensively hydrated. Anhydrite calcitization occurred only after the unconformity was shallowly buried by redbeds, and it probably involved sulphate-reducing bacteria. Hydrogen sulphide, generated by bacteria, reduced redbed pigments. The replacement calcite contains pseudomorphs and relicts of anhydrite, and pseudomorphs of secondary gypsum. These indicate calcitization occurred only after original Mississippian gypsum was altered to anhydrite and this, in turn, was partially converted back to secondary gypsum beneath the unconformity. Replacement occurred concurrently with the formation elsewhere of the dolomitized zone beneath the unconformity. Sulphur isotopic ratios of replacement pyrite are depleted relative to Mississippian sulphate values, consistent with the activities of sulphate-reducing bacteria. Carbon isotopic ratios of replacive calcites, however, do not support this interpretation, and are identical to those of Mississippian limestones. Simple replacement of sulphate by pore-water bicarbonate (in equilibrium with host limestones) is unlikely because protons generated during the reaction should have created acidic conditions in which calcite would have dissolved. A full explanation of the calcitization remains elusive, but may involve replacement occurring in an active groundwater system and/or bacterial sulphate reduction occurring upstream of the site of calcitization.  相似文献   
15.
火焰原子吸收光谱法测定天青石中锶   总被引:1,自引:0,他引:1  
邢谦  谢海东  董迈青 《岩矿测试》2008,27(4):313-315
将天青石试样经混合熔剂熔融,使锶转化为碳酸盐,水提取,过滤分离硫酸根离子,沉淀用盐酸溶解,加入聚乙醇,加热煮沸,稀释至一定体积。分取部分溶液于0.4mol/L硝酸介质中,加镧盐为释放剂,原子吸收光谱法(空气-乙炔火焰方式)测定氧化锶。方法适用于天青石中w(SrO)≤50%氧化锶的测定。  相似文献   
16.
黄钢  宋玉财  庄亮亮  田力丹  吴畏  张滢 《矿床地质》2021,40(5):1100-1118
沉积岩容矿的天青石矿床是锶最主要的来源.文章对全球该类矿床的资料进行了系统梳理,对矿床的发育特征和成因进行了综述和探讨.研究显示:①该类矿床的产出与含石膏或硬石膏的蒸发盐密切相关,或赋存在碳酸盐岩-蒸发岩沉积建造中,或出现在蒸发岩底辟环境;②多数为后生成因,表现为富锶流体交代石膏或硬石膏,或富锶流体与富硫酸盐流体混合、充填开放空间;少数矿床为同生成因,天青石直接从蒸发环境的水体中沉淀出;③后生天青石矿床中的锶可以来自不同途径,包括盆地流体与富钙矿物相互作用萃取的锶、碳酸盐岩重结晶过程文石转变为方解石或硬石膏转变为石膏释放的锶;同生天青石矿床中的锶来自沉积水体本身,沉积源区岩石提供了锶;④天青石中的硫来源于围岩地层中的石膏或硬石膏,有些矿床中的硫来自发生过硫酸盐还原作用后的(溶解的)石膏/硬石膏,而在个别矿床中,还原硫氧化成硫酸盐提供了部分硫;⑤一些天青石矿床中出现有铅锌硫化物,两者可以有成因关系,也可以无成因关系;⑥少数天青石矿床中重晶石含量较高,与高Ba/Sr流体与富硫酸盐流体混合有关.天青石从低钡流体中结晶时,钡在流体中含量的震荡变化会导致SrSO4-BaSO4固溶体的形成,从而使天青石出现环带或出溶结构.  相似文献   
17.
柴达木盆地西北部锶矿成矿系统研究   总被引:4,自引:0,他引:4  
葛文胜  蔡克勤 《现代地质》2001,15(1):53-58,T001
柴达木盆地西北部锶矿床是已知的世界上成矿时代最年轻的大陆热水沉积层控型锶矿床。区内锶矿成矿系统位于印度板块与欧亚板块碰撞带的前陆盆地内 ,其成矿作用发生在陆 -陆碰撞造山带的前缘 ;成矿构造和成矿流体对锶矿床的形成起着重要的控制作用 ;这些锶矿床是矿源场、流体场、能量场在一定时空条件下耦合的产物  相似文献   
18.
本文探讨了开放构造系中锶矿床成矿流体的低温地球化学特征。通过对流体包裹体的成分、盐度、温度、压力、氢氧同位素及流体性质等地球化学特征进行研究,提出开放构造系中低温矿床形成于浅成环境,成矿流体为下渗大气降水和盆地建造水的混合流体。这两种流体的混合不仅导致了低温条件下成矿流体中矿质的沉淀,同时也造成了成矿流体物化性质在垂向上的变化。  相似文献   
19.
论华蓥山地区天青石矿石的两种成因   总被引:3,自引:0,他引:3  
王吉平  胡墨田 《地质学报》2000,74(4):325-332
本文分析了四川-重庆华蓥山地区天青石矿床的野外宏观特征和微观特征,对三种主要类型的天青石矿石:层状天青石矿石、巨晶天青石矿石和条带状天青石矿石中的暗色条带天青石和白色条带天青石进行了野外产状、结构构造特征、稀土元素含量特征、天青石包裹体成分和包裹体盐度的比较分析,结果表明,层状矿石和条带状矿石中的暗色条带天青石是沉积形成的,巨晶矿石和条带状矿石中的白色条带天青石属热卤水成因。  相似文献   
20.
华蓥山地区天青石矿各类型天青石的稀土总量(∑REE)均较低,为轻稀土富集型。巨晶天青石和条带状矿石之白色条带状天青石具铕的正异常,为热卤水成因,层状和条带状矿石之暗色条带天青石具δ Eu的负异常,与碳酸盐岩围岩一致,为沉积成因。区内天青石、碳酸盐岩表现为δ Ce的轻度负异常或无异常,与该区早三叠世嘉陵江组沉积时期所处的含膏泻湖相沉积环境有关。  相似文献   
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