High-resolution sedimentary record of lead in the coastal mud of the East China Sea in the past one hundred and fifty years     

Yunchao HAO Zhigang GUO Dejiang FAN 《中国地球化学学报》2006,25(B08):13-13

In the East China Sea （ECS）, there are some mud areas, including the south coastal mud area, the north coastal mud area, and the mud area to the southwest of Cheju Island. X-ray fluorescence （XRF） techniques and Thermal Ionization Mass Spectrometry （TIMS） were used to study the high-resolution sedimentary record of Pb concentrations and Pb stable isotopic compositions in the past one hundred and fifty years in the coastal mud of the ECS. Pb concentrations of a ^210Pb dating S5 core in the study area have increased rapidly since 1980, and reached the maximal value with 65.08 μg/g in 2000, corresponding to the fast economic development of China since the implementation of the ＂Reform and Open Policy＂ in 1978; ^206Pb/^207Pb ratios generally had stabilized at 1.195 from 1860 to 1966, and decreased gradually from 1966 to 2000, indicating that the anthropogenic source Pb contribution to the ECS has increased gradually since 1966, especially since 1980. Pb concentrations decreased distinctly from 2000 to 2003 and ^206Pb/^207Pb ratios increased from 2001 to 2003, corresponding closely to the ban of lead gasoline from 2000 in China. From 1950 to 2003, there occurred four distinct decrease events of ^206Pb/^207Pb, possibly responding to the Changjiang River （Yangtze River） catastrophic floods in 1998, 1991, 1981 and 1954; from 1860 to 1966, there were two decrease periods of ^206Pb/^207Pb, which may respond to the catastrophic floods of Changjiang River in 1931 and 1935, and 1870. As a result of the erosion and drowning by the catastrophic floods, the anthropogenic lead accumulated in soil and water environments over a long period of time was brought into the Changjiang River, then part of them was finally transported into the ECS, which leads to changes in Pb stable isotopic composition.  相似文献   

XANES analysis of the mechanisms of arsenic removal in biological iron and manganese treatment unit     

Yoko Fujikawa Daisuke Yoneda Atushi Minami Hiroshi Yashima Toshio Tonokai Sotoji Tani Masami Fukui Tatuhide Hamasaki Masataka Sugahara 《中国地球化学学报》2006,25(B08):113-113

Biological iron and manganese removal utilizing indigenous iron and manganese oxidizing bacteria （IRB hereafter） in groundwater can also be applied to arsenic removal according to our pilot-scale test. The arsenic removal probably occurred through sorption and complexation of arsenic to iron and manganese oxides formed by enzymic action of IRB. We investigated the chemical properties of iron and manganese oxides in IRB floc and the valence state of arsenic sorbed to the floc to clarify the mechanisms of the arsenic [especially As （Ⅲ）] removal. The floc samples were collected from two drinking water plants using IRB （Jyoyo and Yamatokoriyama, Japan）, and our pilot - scale test site where arsenic and iron removal using IRB is under way （Mukoh, Japan）. The Jyoyo and Yamatokoriyama IRB floc samples were subjected to As （Ⅲ） and As（Ⅴ） sorption experiments. The elemental composition of the floc samples was measured. XANES spectra were collected on As, Fe and Mn K-edges at synchrotron radiation facility Spring 8 （Hyogo, Japan）. FT-IR and the X-ray diffraction spectra of the samples were also obtained. The IRB floc contained ca. 35 % Fe, 0.3%-3.5% Mn and 2%-6% P. The samples were highly amorphous and contained ferrihidrites and hydrated iron phosphate. According to XANES analyses of IRB, As associated with IRB was in ＋5 valence state when As （Ⅲ） （or As （Ⅴ）） was added in laboratory sorption test, Fe in ＋3 valence state, and Mn a mixture of＋3 and ＋4 valence states. Small shift was observed in the XANES spectra of IRB on As K-edge as the equilibration time of the sorption experiment was increased. Gradual oxidation of a small amount of As （Ⅲ） associated with IRB or change in arsenic binding with sorption site were the probable mechanism.  相似文献   

Treatment of high fluoride concentration wastewater by layered double hydroxides： Mechanism studies   总被引：1，自引：0，他引：1  

Liang LU Jing HE 《中国地球化学学报》2006,25(B08):160-161

An appropriate concentration of fluoride in drinking water is required to prevent dental cavities, but long-term ingestion of water that contains more than a suitable level of fluoride can cause bone disease and mottling of the teeth. Fluoride ions can be found in wastewater from the fluoride chemical industry, as well as the semiconductor, metal processing, fertilizer, and glass-manufacturing industries. The discharge standard for fluoride in industrial wastewater in China is 10 mg/L. Efficient treatment of fluoride-containing wastewater is therefore of major concern in China, following the rapid development of the fluoride chemical industry. Several methods have been used to remove fluoride from water, such as adsorption, chemical precipitation, electrodialysis, ion exchange and electrochemical processes. Layered double hydroxides （LDHs） are anionic clays with high anion exchange capacities which are effective adsorbents for removal of a variety of anionic pollutants. LDHs have been studied as potential adsorbents for removing toxic anionic species such as CrO4^2-, TcO4^-, SeO3^2-, pesticides, and anionic surfactants from aqueous systems. One of the main attractions of using LDHs for fluoride removal, is that unlike other chemical treatment methods, no chemical sludge should be produced. In the present study, an attempt was made to investigate the mechanism of fluoride removal by LDHs under different conditions using batch methods. In addition, the release of fluoride adsorbed on LDHs by treatment with an aqueous solution of Na2CO3 was studied. The residual fluoride was found to be 10 mg/L in a solution with an initial concentration of 1000 mg/L, which meets the discharge standard for fluoride in industrial wastewater in China.  相似文献   

Molar tooth structures of the Neoarchean Monteville Formation, Transvaal Supergroup, South Africa. I: Constraints on microcrystalline CaCO₃ precipitation     

JAMES W. BISHOP  DAWN Y. SUMNER 《Sedimentology》2006,53(5):1049-1068

Molar tooth (MT) structures are enigmatic, contorted millimetre‐ to decimetre‐long veins and spheroids of microcrystalline calcite that formed during very early diagenesis in Precambrian sediments. MT structures in the ca 2·6 Ga Monteville Formation are 600–800 Myr older than previously reported occurrences and establish that conditions necessary for MT genesis were met locally throughout much of the Precambrian. In the Monteville Formation, MT structures were formed shallow subtidally, extending to depths near storm wave base, in shale host sediments intercalated with storm‐generated carbonate sand lenses. They are filled with microcrystalline calcite and rare pyrite. Microcrystalline calcite identical to that in MT structures fills other pore space, including porosity between grains in carbonate sand lenses, moldic porosity in sand grains, sheet cracks in columnar stromatolites, and shallow cracks on sandy bedding planes. Relationships in the Monteville Formation demonstrate that microcrystalline CaCO₃ precipitated in fluid‐filled cracks and pores; microcrystalline calcite characteristics, as well as the paucity of carbonate mud in host rocks, are inconsistent with injection of lime mud as the origin of MT structures. Locally, MT cracks were filled by detrital sediment before or during precipitation. Precipitation occurred in stages, and MT CaCO₃ evolved from granular cores to a rigid mass of cores with overgrowths – allowing both plastic and brittle deformation of MT structures, as well as reworking of eroded MT structures as rigid clasts and lime mud. Crystal size distributions and morphology suggest that cores precipitated through nucleation, Ostwald ripening and size‐dependent crystal growth, whereas overgrowths formed during size‐independent crystal growth.  相似文献   

Flotation and depression control of arsenopyrite through pH and pulp redox potential using xanthate as the collector     

A. López Valdivieso  A.A. Sánchez López  C. Ojeda Escamilla  M.C. Fuerstenau 《International Journal of Mineral Processing》2006

The role of pH and pulp redox potential (E_H) to control the flotation and depression of arsenopyrite has been investigated through studies on microflotation of arsenopyrite crystals and batch flotation of an arsenopyritic ore using isopropyl xanthate as collector. The transition between flotation and depression of arsenopyrite is established by the reversible potential of the xanthate/dixanthogen couple. Adsorption of arsenate ions on ferric hydroxide has been studied through electrokinetics to delineate mechanisms involved in the depression of arsenopyrite using oxidants. Chemical binding between arsenate species and ferric hydroxide sites on arsenopyrite is suggested as the mechanism responsible for depression of arsenopyrite. E_H conditions are given for the flotation and depression of arsenopyite at various pH values for the arsenopyritic ore.  相似文献   

Chloride removal from wastewater by thermally treated hydrotalcite     

《中国地球化学学报》2006,25(B08):255-256

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地下水中硝基苯污染的防控技术—泥浆回灌法构筑阻截墙     

李绪谦  马莉  蒋惠忠  宗芳  李爽  刘利 《吉林大学学报(地球科学版)》2006,(Z1)

硝基苯污染可使地下水环境质量急剧恶化。利用阻截墙控制地下水中的硝基苯污染范围的扩大,是控制地下水环境继续恶化的经济、有效方法之一。以粘土、沸石、铁粉、硫酸钙等与水调配成泥浆,利用压力向井中回灌,将泥浆注入到含水层中,可有效地阻截地下水中硝基苯的扩散。  相似文献   

陆相油藏中砂泥岩互层时移地震遮掩效应及其对时移地震资料解释的影响     

WANG Da-wei 《现代地质》2006,(4)

从差异波形特征的角度出发,分析时移地震差异波形特征与砂泥岩互层油藏中油层速度变化的关系。通过建立由5层地层组成的楔形地质模型,运用褶积公式及时移地震求差公式,得到泥岩速度为2 400 m/s和砂岩速度为2 700m/s条件下,互层中砂岩速度变化±150 m/s的时移地震响应。研究结果表明:砂泥岩互层的差异波形是一个多峰复合波,泥岩夹层的厚度是决定差异波形特征的一个主要因素,并且存在一个临界值,即四分之一主波长;如果泥岩夹层的厚度小于这一临界值,就会发生遮掩效应,即顶部油层的时移地震响应可以掩盖中、下部油层的时移地震响应。  相似文献   

生物去除地下水中硫酸盐的实验研究   总被引：1，自引：0，他引：1  

张宏涛  翟辉 《地下水》2005,27(1):19-22

使用平皿夹层厌氧法分离得到纯化的硫酸盐还原菌,通过对比封口、敞口两种情况下细菌培养过程中产生的现象和细菌的生长曲线,表明SRB并非严格的厌氧菌,能耐受一定浓度的环境溶解氧.将该菌用于去除溶液中的SO42-,发现SRB在还原SO42-的过程中,随着SO42-去除率的增加,溶液的pH值会减小,而当SO42-去除率降低时,溶液的pH有增加的趋势;COD/SO42-比值对SO42-的去除率有很重要的影响,在封口情况下,COD/SO42-=0.75时SO42-的最大去除率约为48.60%,COD/SO42比值增加至2.5时,SO42-最大去除率可以达到89.72%,要达到SO42-高去除率,必须增加COD/SO42-比值.  相似文献   

一种基于核学习的储集层渗透率预测新方法   总被引：2，自引：1，他引：2  

杨斌  匡立春  施泽进  孙中春 《物探化探计算技术》2005,27(2):119-123

基于核学习的支持向量机,是一种采用结构风险最小化原则代替传统经验风险最小化原则的新型统计学习方法,具有完备的理论基础。这里提出了核学习技术在储集层非均质特性描述中渗透率参数预测的新用途。在复杂地层中,基于支持向量机的智能和自适应模式识别能力而建立了常规测井多参数信息输入的渗透率预测模型,然后对实际油田储集层渗透率进行了预测。与常规线性回归模型预测结果相对比,所提出的方法更易于使用,很少受不确定因素的影响,并具有较强的信息整合能力以及更高的预测准确性和可信度。  相似文献