水资源中氯代烃污染物的去除方法   总被引：3，自引：0，他引：3  

李琳  刘菲 《黄金地质》2002,8(2):74-76

随着工业化的发展。氯代有机溶剂使用越来越广泛。并且难于去除。在20世纪90年代初期，人们就已认识到用Fe^0恢复污染的地下水的潜力。国外正在研究帮使用扔几种还原挥发性氯代烃的还原反应介质，尤其要提高的是双金属反应系统，反应速度快，而且脱Cl中国难解产物少，目前国也只停留在实验室研究阶段，个别做了地上反应器的验证实验，它的脱Cl机理、介质钝化和完全脱Cl问题还有待于进一步研究。  相似文献   

沉积有机质激光热裂解色谱质谱探针分析技术的尝试及其前景探讨   总被引：1，自引：1，他引：1  

钟宁宁  Paul Greenwood 《地球化学》2001,30(6):605-611

激光热裂解－色谱－质谱分析方法具有从技术层面上融合分子地球化学方法和有机岩石学方法的潜能。通过抚顺煤镜质组分和树脂体的研究实例，介绍了激光热裂解－色谱－质谱探针分析的基本原理及测试方法。抚顺煤显微组分的微区热裂解产物特征中，镜质组和树脂体热解产物的正烷烃、烷基萘和四氢化萘的总体面貌相似，但树脂体中正烷烃含量较低，而烷基四氢化萘明显较高，这可能反映显微组分形成过程中发生过低分子烃类在各显微组分之间的混合作用。除此之外，还把激光热裂解－色谱－质谱探针技术与传统的分子地球化学方法、有机岩石学方法进行比较。探讨了激光热裂解－色谱－质谱探针技术的应用前景以及尚待解决的技术问题。落射到样品表面的激光束能量（温度）和控制和激光辐射时间的，激光束斑大小、热解产物量、色谱－质谱检验灵敏度极限三者关系等，都是限制新技术应用的技术问题。  相似文献   

鼎湖山自然保护区大气气溶胶中的PAHs   总被引：6，自引：2，他引：6  

祁士华  叶兆贤等 《地球科学》2001,26(1):83-87

多环芳烃（PAHs)是环境中分布广泛、危害人类健康的有机化合物，通过对鼎湖山自然保护区自然地理和大气气溶胶中苯并（a)芘分析认为，春季样品中大气气溶胶中PAHs主要来源于高等植物排放，夏季来源于珠江三角洲经济区化石燃烧排放。  相似文献   

Overview of US Minerals Management Service Activities in Deepwater Research     

Robert LaBelle   《Marine pollution bulletin》2001,43(7-12):256-261

The US Minerals Management Service (MMS) is responsible for safe and environmentally sound management of offshore oil and gas resources. In recent years, there has been a tremendous increase in both activities and plans for deepwater development of these resources in the Gulf of Mexico (GOM). As the industry meets the enormous technical challenges involved, there is a concomitant effort to assure environmental protection of deep-ocean and coastal resources. This paper will outline the research planning and program currently underway to assess impacts, identify potential problems, and discover more about unknown resources of the deep ocean.  相似文献   

临南地区石油运移方向与成藏期次研究   总被引：11，自引：0，他引：11  

陈庆春  林玉祥  唐洪三 《沉积学报》2001,19(4):611-616

根据原油及油砂抽提物中含氮化合物分析、原油生物标志成熟度参数及储层流体包裹体烃类成分分析,研究了临南地区石油运移的方向、距离、成藏期次。结果表明临南油田仅有一期油气运聚成藏过程,属中新世末形成的成熟原油,4 甲基甾烷含量较高。曲堤油田存在两期油气运聚成藏过程,早期原油成熟度低,4 甲基甾烷含量低,运移距离较远,成藏后大部分散失 ;晚期充注的原油成熟度较高,4 甲基甾烷含量也较高,并保存至今。  相似文献   

Palynostratigraphy and palynofacies indications of depositional environments and source potential for hydrocarbons: the mid Cretaceous Nahr Umr and lower Mauddud formations, Iraq   总被引：1，自引：0，他引：1  

T. K. Al-Ameri  T. K. Al-Najar  D. J. Batten 《Cretaceous Research》2001,22(6):735

Palynomorphs recovered from core and cuttings samples from five boreholes in the East Baghdad Oilfield indicate a mid Albian–early Cenomanian age-range for the Nahr Umr Formation and the lower part of the overlying Mauddud Formation. Two palynomorph zones and four types of palynofacies have been identified. The latter are interpreted to indicate delta-top swamp and marsh, silty–muddy deltaic, inner silty and carbonate-rich platform, and limestone-platform environments. The palynofacies of the two types of platform accumulations suggest that these are potential sources of biogenic methane and condensates, and may yield more liquid hydrocarbons in areas where the formations are at greater depths than within the region studied.  相似文献   

Natural and anthropogenic C2 to C6 hydrocarbons in the central-eastern Venezuelan atmosphere during the rainy season     

Loreto Donoso  Rodrigo Romero  Alberto Rondón  Emmanuel Fernandez  Pedro Oyola  Eugenio Sanhueza 《Journal of Atmospheric Chemistry》1996,25(2):201-214

The levels of low molecular weight hydrocarbons were measured at pristine sites and rural locations affected by hydrocarbon emissions from oil and gas producing fields in Venezuela. At the clean sites, lower concentrations of C₂ to C₆ alkanes were observed, whereas, in comparison with remotes sites, very much higher levels were measured at the polluted sites. Alkenes present relatively high concentrations, with isoprene being the most abundant, all over the study region. The main sources of alkenes are likely to be natural, mainly from vegetation. The levels of alkanes recorded at the clean sites and the alkene levels found everywhere in the region are in agreement with the values reported for other clean sites in the tropics. The increase of ozone production capacity due to the anthropogenic emissions of alkanes from oil and gas fields was estimated. Due to the presence in the atmosphere of important amounts of naturally emitted isoprene, ethene and propene, which makes a substantial contribution to the reactivity of the hydrocarbon mixture, a small increase (<5%) was estimated to occur in the capacity of the ozone production at a regional scale during the rainy season.  相似文献   

Boundary-layer ozone depletion as seen in the Norwegian Arctic in spring     

Sverre Solberg  Norbert Schmidbauer  Arne Semb  Frode Stordal  Øystein Hov 《Journal of Atmospheric Chemistry》1996,23(3):301-332

Several years of measurements of ozone, hydrocarbons, sulphate and meteorological parameters from Spitsbergen in the Norwegian Arctic are presented. Most of the measurements were taken on the Zeppelin Mountain at an altitude of 474 m a.s.l. The focus is the episodes of ozone depletion in the lower troposphere in spring, which are studied in a climatological way. Episodes of very low ozone concentrations are a common feature on the Zeppelin Mountain in spring. The low ozone episodes were observed from late March to the beginning of June. When the effect of transport direction was subtracted, the frequenty of the low ozone episodes was found to peak in the beginning of May, possibly reflecting the seasonal cycle in the actual depletion process. Analyses based on trajectory calculations show that most of the episodes occurred when the air masses were transported from W-N. Ozone soundings show that the ozone depletion may extend from the surface and up to 3–4 km altitude. The episodes were associated with a cold boundary layer beneath a thermally stable layer, suppressing mixing with the free troposphere. The concentration of several individual hydrocarbons was much lower during episodes of low ozone than for the average conditions. The change in concentration ratio between the hydrocarbons was in qualitative agreement with oxidation of hydrocarbons by Br and Cl atoms rather than by OH radicals.  相似文献   

Atmospheric concentrations of nonmethane hydrocarbons at a North European coastal site     

Øystein Hov  Norbert Schmidbauer 《Journal of Atmospheric Chemistry》1992,14(1-4):515-526

Two years of individual nonmethane hydrocarbon (NMHC) measurements at a rural site close to the south coast of Norway show that there was a distinct annual cycle with a late winter maximum and late summer minimum in the slowly reacting NMHCs acetylene, ethane, propane and i- and n-butane. The average January—March concentrations were a factor 2–4 higher than the July-September concentrations. Also ethene, propene and the pentanes show a similar annual cycle, but the individual scatter in the measurements in particular of propene, is large. The highest concentrations of NMHC were found in winter for easterly transport on a regional scale (out to 1500 km from the site), and for southeasterly transport in the summer.  相似文献   

EROD activity, serum SDH and PAH biliary metabolites in sand flathead (Platycephalus bassensis) collected in Port Phillip Bay, Australia     

Gagnon MM  Holdway DA 《Marine pollution bulletin》2002,44(3):230-237

In order to evaluate the health status of fish inhabiting Port Phillip Bay, Australia, southern sand flathead (Platycephalus hassensis, N = 133) were collected at six stations throughout the Bay. Fish had a similar serum sorbitol dehydrogenase (SDH) activity level (p = 0.12), indicating that they were not experiencing hepatocellular injuries. Ethoxyresorufin-O-deethylase (EROD) activity was generally lower in the non-urbanized and non-industrialized southern part of the Bay. The highest EROD activity was observed in Hobson Bay, the closest station from Melbourne city. Naphthalene-type biliary metabolites were also highest in Hobson Bay with intermediate levels found in Corio Bay where refineries are present. An opposite trend was observed with the pyrene-type bile metabolites, the highest levels being observed in Corio Bay while intermediate levels were found in Hobson Bay. The ratio of naphthalene-type to benzo(a)pyrene (B(a)P)-type metabolites indicate that relatively to other sites sampled in Port Phillip Bay, Corio Bay is subjected to enriched petroleum hydrocarbons of pyrolytic origin. Temporal trends indicate that the availability of xenobiotics to fish remained unchanged over the 1990s.  相似文献