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51.
文中较系统地介绍了国外近年来基于矿物合成和激光原位定量分析测试技术发展的副矿物,重点是锆石,其次是金红石、石榴石、榍石及磷灰石等微量元素地球化学特征在成岩成矿温度、氧逸度、源区物质等方面的研究成果。这些成果是在不同温度、压力及体系成分条件下合成的矿物,结合自然界岩石相关副矿物成分分析,获得了副矿物中微量元素含量与形成温度、压力、氧逸度等之间存在严格线性关系,建立了定量计算公式,并给出了这些温度计、氧逸度等计算公式的适用范围。根据广泛用于同位素定年的锆石受变质和热液蚀变而出现复杂年龄譜,文中还介绍了用锆石微量和稀土元素地球化学特点,结合近年来在这方面的研究成果,探讨了Th/U比值识别锆石成因存在的问题,介绍了稀土元素组成识别锆石成因的原理和应用。 相似文献
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界河金矿绿泥石化及其地质意义 总被引:1,自引:0,他引:1
界河金矿产于燕山期郭家岭花岗闪长岩中,围岩蚀变发育,并以较强的绿泥石化为特征,通过对绿泥石形态,成分,红外光谱,晶胞参数,热发光和穆斯堡尔谱等特征进行分析,进一步探讨了绿泥石化与金矿化的关系。 相似文献
54.
The smectite to chlorite transition in a fossil seamount hydrothermal system: the Basement Complex of La Palma, Canary Islands 总被引:3,自引:0,他引:3
Abstract The hydrothermal metamorphism of a sequence of Pliocene-aged seamount extrusive and volcanoclastic rocks on La Palma includes a relatively complete low-P-T facies series encompassing the zeolite, prehnite-pumpellyite, and greenschist facies. The observed mineral zonations imply metamorphic gradients of 200–300° C km-1. The transition from smectite to chlorite in the La Palma seamount series is characterized by discontinuous steps between discrete smectite, corrensite and chlorite, which occur ubiquitously as vesicles and, to a much lesser extent, vein in-fillings. Trioctahedral smectites [(Mg/(Fe + Mg) = 0.4–0.75] occur with palagonite and Na-Ca zeolites such as analcime and a thompsonite/natrolite solid solution. Corrensite [(Mg/(Fe + Mg) = 0.5–0.65] first appears at stratigraphic depths closely corresponding to the disappearance of analcime and first appearance of pumpellyite. Discrete chlorite [(Mg/(Fe + Mg) = 0.4–0.6] becomes the dominant layer silicate mineral coincident with the appearance of epidote and andraditic garnet. Within the stratigraphic section there is some overlap in the distribution of the three discrete layer silicate phases, although random interstratifications of these phases have not been observed. Although smectite occurs as both low- and high-charge forms, the La Palma corrensite is a compositionally restricted, 1:1 mixture of low-charge, trioctahedral smectite and chlorite. Electron microprobe analyses of coarse-grained corrensite yield structural formulae close to ideal values based on 50 negative charge recalculations. Calcium (average 0.20 cations/formula unit) is the dominant interlayer cation, with lesser Mg, K and Na. The absence of randomly interlayered chlorite/smectite in the La Palma seamount series may reflect high, time-integrated fluid fluxes through the seamount sequence. This is consistent with the ubiquity of high-variance metamorphic mineral assemblages and the general absence of relict igneous minerals in these samples. 相似文献
55.
Detailed textural and chemical data for mineral assemblages on a regional scale are presented for the metaandesitic Eocene-Oligocene Taveyanne greywacke of the Glarus Alps, Eastern Switzerland. Presented data indicate an increase of metamorphic grade from zeolite facies to prehnite-pumpellyite and pumpellyite-actinolite facies. Low-grade outcrops contain laumontite, minor corrensite and pumpellyite (assemblage type 1), whereas outcrops of higher metamorphic grade contain prehnite and two populations of pumpellyite (type 2), prehnite—pumpellyite-(Al)—white mica (type 3), a single outcrop shows pumpellyite-actinolite facies (type 4). From the zeolite to prehnite-pumpellyite/pumpellyite-actinolite facies there are indications for an increase of the chemical equilibrium domain size for the critical paragenesis from a single detrital grain ≤1 mm) in type 1, to a few millimetres in type 2, and to a whole thin section in type 3. Metamorphic P - T conditions were determined by a combination of chlorite thermometry, fluid inclusion and vitrinite reflectance data. Peak temperatures range from 170-190 C for zeolite facies to 270-310 C for prehnite-pumpellyite and pumpellyite-actinolite facies. For the higher temperature range, pressures of 2-3 kbar are derived indicating a geothermal gradient of 24-32 C km-1 . The well-constrained temperature estimations derived for the assemblages provide a useful test of the different empirical calibrations of chlorite thermometers recently proposed. The best correspondence to the temperatures determined here is for the Cathelineau calibration. In addition, in the lower grade samples differences in textures and calculated temperatures provide a mean to distinguish between detrital and newly formed chlorites. 相似文献
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安塞油田长2油层成岩作用及其对储层物性的影响 总被引:7,自引:7,他引:7
安塞地区长2油层储层以中细粒长石砂岩为主,主要成岩矿物为绿泥石环边、方解石胶结物、石英和长石加大生长、伊利石、伊一蒙混层、钠长石和高岭石等。绿泥石环边的发育对原生粒间孔的保存起到有利的作用。石英加大级别达Ⅲ级,加大边含有丰富的有机包体,均一温度范围48.1~76.5℃,烃类进入储层的时间为早白垩世中期至晚白垩世。储层发育多种孔隙类型,面孔率平均为11.60%.主要类型有粒间孔、骨架颗粒溶孔和微裂缝等。残余粒间孔和骨架颗粒溶孔是本区长2储层的主要孔隙类型。根据成岩作用的矿物岩石学标志、有机质成熟度及古温度,将长2油层砂岩的成岩作用划分为3个成岩阶段:早成岩阶段、晚成岩阶段和表生成岩阶段。储层性质明显地受到沉积微相和成岩作用的影响,沉积物粒度较粗、厚度较大的分流河道储集物性明显优于各种粒度较细、厚度较薄的分流间席状砂体。 相似文献
58.
相山铀矿田6122矿床凝灰岩铀矿石成因探讨 总被引:1,自引:0,他引:1
在相山铀矿田6122矿床4号带的主要含矿岩石英安岩和“碎斑熔岩”之外发现了新的含矿岩石凝灰岩。铀矿石中绿泥石含量较高.并且含铀达7.13%。经过对舍矿凝灰岩特征、矿化与构造的关系、与铀矿物共生矿物的特征进行研究,笔者认为成矿熟液来自于地壳深部,曾经经历过高温阶段。在矿化蚀变过程中形成大量绿泥石、水云母等粘土矿物.它们使铀酰络离子稳定性、溶解度降低而解体.使铀还原沉淀并被绿泥石、水云母等吸附。 相似文献
59.
本次区调工作在内蒙古苏尼特左旗必鲁图绢云母绿泥石片岩中发现了铁铝榴石矿层,并进行了岩石学和矿物学的研究。初步研究表明,矿化围岩属中元古代,相当于区域上的白乃庙群。铁铝榴石呈红褐色,菱形十二面体晶形,化学成分以铁、铝、硅为主,含钙、镁等微量元素。铁铝榴石属区域变质叠加热变质作用形成。 相似文献
60.