拉拉铜矿黄铁矿微量元素地球化学特征及其成因意义   总被引：6，自引：0，他引：6  

周家云  郑荣才  朱志敏  陈家  沈冰  李潇雨  罗丽萍 《矿物岩石》2008,28(3)

四川会理拉拉铜矿床是我国著名大型富铜矿床,针对该矿床中黄铁矿的微量元素、稀土元素地球化学分析表明:拉拉铜矿经历了早期火山喷发成岩成矿和晚期变质成岩成矿作用.条带状矿石中的黄铁矿Co/Ni比值集中于4.92～79.2之间,落入火山成因黄铁矿区,稀土元素分布具有Eu正异常和轻稀土富集的特征,反映矿床具有伴随河口群火山喷流沉积成岩过程的同生沉积成矿作用.脉状矿石中的黄铁矿Co/Ni比值集中于1.10～3.45,落在热液成因黄铁矿区,稀土元素较河口群岩石及其他典型块状硫化物矿床矿石稀土元素更加富集轻稀土元素,稀土含量变化范围更大,显著的负Eu异常,则又说明,矿床形成的主要成矿作用是伴随新元古代晋宁运动而发生的大规模的变质作用.  相似文献   

湖北辽瓦店遗址地层记录的环境变迁与人类活动的关系研究   总被引：6，自引：4，他引：2       下载免费PDF全文

李中轩  朱诚  张广胜  欧阳杰  王然 《第四纪研究》2008,28(6):1145-1159

用XRF和ICP-AES方法分别测试了湖北辽瓦店遗址地层样品的氧化物含量和地球化学元素含量,恢复了遗址地层中夏代文化层、东周文化层和明清文化层记录的环境变化和人类活动特征。结果表明:1)夏代文化层时期,气候温暖湿润,生态环境良好,人类活动与自然环境和谐度高,有原始的手工业活动记录。2)东周时期气候开始进入干旱期,干旱程度在上东周文化层中部逐渐加深(LOI=6.98%),到了上东周文化层顶部气候进入暖湿期。该层Cu含量的异常高值(0.31mg/g)和出土的青铜器表明本文化层反映了青铜社会的繁荣期,而P含量的高值(22.73mg/g)和动物骨屑则反映了该期人们驯养、捕猎动物的普遍性。3)明清时期的气候趋于干凉,明代文化层中部有短暂暖湿期,后又进入冷干期。清代文化层中下部有暖湿特征,之后重新进入干冷期。该层Ca(均值101.5mg/g),Mg(均值60.27mg/g),Zn和Pb的高含量表明遗址曾有过制陶(瓷)业的历史。另外,Mg和Ca含量的高值与耕作区、墙壁灰浆、生活垃圾堆积等人类活动相关。Ca和Mg含量在近现代层逐步升高揭示了人类活动逐渐增强的事实。地层的平均粒径自上东周文化层(<142cm)开始出现振荡,暗示汉江洪水和季节性山洪发生的频率不断增加,表明恶劣环境条件虽然促进了人类生产力水平的提高,但原始生态系统却遭到破坏,人类活动对自然环境的正反馈效应日益凸显。  相似文献   

塔东地区古城4井上寒武统—中、上奥陶统流体地球化学示踪     

王东  王国芝  冉启贵  刘树根  胡九珍  张长俊 《现代地质》2008,22(4)

通过对塔东地区古城4井上寒武统和中、上奥陶统碳酸盐岩围岩及充填物的碳、氧、锶同位素地球化学和流体包裹体成分的对比研究表明,充填于中、上奥陶统和上寒武统的流体分属于2个不同来源的流体体系。充填于中、上奥陶统灰岩裂缝中方解石脉的w(87Sr)/w(86Sr)介于0.7084~0.7088,它与早奥陶世海水的w(87Sr)/w(86Sr)相近;流体体系为CH4-H2O体系;充填物与围岩间具有明显的碳、氧同位素差异,表明上部流体体系中的流体来自于奥陶系地层本身。上寒武统白云岩裂缝中方解石脉的w(87Sr)/w(86Sr)为0.7138,明显地高于同时代海水的锶同位素值;流体体系为CO2-H2O体系;下部流体体系中的流体为外来富锶流体。上、下流体体系间互不连通暗示着上寒武统地层具有相对较好的保存条件。  相似文献   

粤西云浮镇安-阳春罗阳地区 地球化学特征与找矿方向     

张忠进  方国辉  陈城利  叶伟何 《物探与化探》2008,32(3):252-255,260

分析云浮镇安—阳春罗阳地区元素的分布、分配特征和区域地质背景后,指出该地区有找矿潜力,提出Au、Ag、Cu、Pb、Zn是重要的找矿元素,找构造蚀变岩型金矿、火山岩型金矿、岩浆热液型银—多金属矿前景好,主要的找矿标志是断裂和蚀变。  相似文献   

黑龙江省中部森林沼泽区金在土壤A层中的富集规律     

胡忠贤  程志中  王学求 《物探与化探》2008,32(1):33-35

探讨了金在黑龙江省中部森林沼泽区A层土壤-10～+60目、-60～+100目、-100～+160目及-160目粒级中的含量分布特征和富集规律。经对比研究认为,-100目可以满足低密度深穿透地球化学详细测量采样要求,该粒级能够有效地发现异常。  相似文献   

川西新场气田地气测量试验   总被引：2，自引：0，他引：2  

鲁人齐  王多义  刘亚伟  左银辉  邓美洲  刘应汉 《物探与化探》2008,32(6)

通过对新场气田地气测量分析,发现地气测量的纳米微粒金属元素在新场气田上方有明显的异常显示。综合土壤地球化探结果对比分析,认为Ba、Cd、Cu、Mo、Zn、P、V、Ni等20多种纳米微粒金属元素在新场气田与相同的土壤微量元素都有着共同的响应。同时分析了有机地球化学指标在气田地表上方的表现模式,其特征和地气、土壤元素表现基本一致。地气测量方法在一定条件下对寻找天然气藏、确定气田范围具有一定的应用前景。  相似文献   

Geochemistry and environmental effect of cadmium in the super-large Jinding Pb-Zn deposit,Yunnan Province,China     

Hang Li  Dahua Li  Tangfu Xiao  Libin He  Zengping Ning  Jialong Sun  Changsheng Zhu  Yan Shuang 《中国地球化学学报》2008,27(1):21-27

The Jinding Pb-Zn deposit in Yunnan Province is the representative of a Cd-enriched area and mining activities lead to the release of Cd into the hypergenic ecosystem, resulting in Cd pollution. The concentrations of Cd vary greatly from one type to another type of rocks in the mining district. In the host rock, Cd concentrations range from 50×10^-6 to 650×10^-6 with an average of 310×10^-6. In primary ores, Cd concentrations range from 14×10^-6 to 2800×10^-6 with an average of 767×10^-6. However, in oxidized ores, Cd concentrations are highest, varying within the range of 110×10^-6 to 8200×10^-6 , averaging 1661×10^-6. It is shown that the oxidized ores are the main carder and environmental source of Cd. Leaching test showed that Pb/Zn ores are easy to oxidize and thereafter release Cd and other harmful elements. These leached elements in the leachate may be precipitated rapidly in the order of Zn〉Pb〉Cd. As for the concentration distribution of Cd in the Bijiang River, it is estimated to be 15.7 μg/L Cd in water, 49.3 mg/L in suspended substances, and 203.7 mg/L in sediments. The average value of Cd in soil from the polluted area is 83.0 mg/kg. Natural weathering of Cd-rich rocks and minerals imposes a potential environmental risk on the aquatic ecosystem of the Bijiang catchment.  相似文献   

Environmental Redox Changes of the Ancient Sea in the Yangtze Area during the Ordo-Silurian Transition     

YAN Detian  CHEN Daizhao  WANG Qingchen  WANG Jianguo  CHU Yang 《《地质学报》英文版》2008,82(3):679-689

Extensive organic-matter （OM） rich facies （black shales） occur in the Ordo-Silurian boundary successions in the Yangtze area, South China. To investigate the redox changes of the Yangtze Sea during the Ordo-Silurian transition, two OM sections （Wangjiawan in Yichang, Hubei Province, and Sanjiaguan in Zhangjiajie, Hunan Province） straddling the Ordo-Silurian boundary are studied. The measurements finished in this study include contents of the total organic carbon （TOC）, pyrite sulphur, and different species of Fe, including dithionite-extractable Fe （FED）, pyrite Fe （FeP）, HCl-extractable Fe （FeH）, and total Fe （FeT）, in black shales, as well as other redox proxies, such as the SIC ratio, the ratio between highly reactive Fe （FeHR = FeD ＋ FeP） and FeT, and the FeP/（FeP ＋ FeH） ratio, known as the degree of pyritization （DOP）. In the Wangjiawan section, the Middle Ashgill sediments have high FeHR/FeT ratios （0.20-0.77; avg. 0.45）, high DOP values （0.21-0.72; avg. 0.54）, and a relatively constant sulfur content independent of the organic carbon content. By the contrast, the mid-early Hirnantian deposits generally have low FeHR/FeT ratios （0.10-0.35; avg. 0.21）, low DOP values （0.11- 0.40; avg. 0.28）, and SIC values are clustering on the normal marine value （SIC = 0.36）. The late Hirnantian and early Rhuddanian deposits, similar to those of the Middle Ashgill deposits, are characterized by high FeHR/FeT ratios （0.32-0.49; avg. 0.41）, high DOP values （0.46-0.68; avg. 0.53） and fairly constant sulfur contents. These data suggest the occurrences of marine anoxia on the Yangtze Sea shelf during intervals of the Mid Ashgill, Late Hirnantian and Early Rhuddanian, and ventilated and oxygenated marine conditions during the mid-early Hirnantian time. The mid-early Hirnantian ventilated event was concomitant with the global glacial period, likely resulted from the glacio-eustatic sea-level fall and subsequent circulation of cold, dense oxygenated waters  相似文献   

Distribution Characteristics of Sulfur and the Main Harmful Trace Elements in China’s Coal     

TANG Shuheng  SUN Shenglin  QIN Yong  JIANG Yaof  WANG Wenfeng 《《地质学报》英文版》2008,82(3):722-730

To promote the rational development and use of clean coal resources in China, data on the regional and age distribution of sulfur, arsenic and other harmful elements in Chinese coal was broadly collected, tested for content, and analyzed. Coal in northwestern China is characterized by low to extremely low levels of sulfur; the coal of the Taiyuan Formation in northern China mainly has high-sulfur content; that of the Shanxi Formation is mainly characterized by low sulfur coal; and the Late Permian coal in southern China has overall higher sulfur content; other regions have low sulfur coal. The average content of harmful trace elements in the bulk of China＇s coal is similar to the corresponding content in the coal of the North America and the rest of the world, whereas the content of various elements （Hg, Sb and Se） is different in magnitude to the corresponding percentage in the crust. The average content of the elements Cr, Se, Co, Be, U, Br in Late Permian coal in S China ranks first in the country whereas the average content of Hg and CI in the coals of Late Carboniferous to Early Permian age in N China are the highest. The average content of Mn in Early and Middle Jurassic coal is higher in NW China. The high content of harmful elements in some coal should cause particular concern both in the development and utilization of coal.  相似文献   

神木北部矿区5-2煤层厚度及其底板高程趋势分析   总被引：1，自引：0，他引：1  

苗霖田  姚建明  吕婷婷  杜荣军 《煤田地质与勘探》2008,36(3):12-15

为了查清神木北部矿区5-2煤层赋存特征及成因,选取了该矿区172个典型钻孔数据,用趋势分析法研究了5-2煤层的厚度及其底板高程度变化特征。结果显示:该区煤层厚度总体为南北厚中部薄,东厚西薄;底板高程为南北高中部低,东高西低;煤层厚度和其底板高程间普遍存在正相关关系。在该区构造稳定的背景下,后期改造对煤层厚度及其底板的影响很小,煤层赋存特征主要受沉积与剥蚀的控制。  相似文献