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81.
82.
Calculated Phase Relations in the System Na2O-CaO-K2O-FeO-MgO-Al2O3-SiO2-H2O with Applications to UHP Eclogites and Whiteschists 总被引:2,自引:0,他引:2
Pressuretemperature grids in the system Na2OCaOK2OFeOMgOAl2O3SiO2H2O and its subsystems have been calculatedin the range 1545 kbar and 550900°C, usingan internally consistent thermodynamic dataset and new thermodynamicmodels for amphibole, white mica, and clinopyroxene, with thesoftware THERMOCALC. Minerals considered for the grids includegarnet, omphacite, diopside, jadeite, hornblende, actinolite,glaucophane, zoisite, lawsonite, kyanite, coesite, quartz, talc,muscovite, paragonite, biotite, chlorite, and plagioclase. Compatibilitydiagrams are used to illustrate the phase relationships in thegrids. Coesite-bearing eclogites and a whiteschist from Chinaare used to demonstrate the ability of pseudosections to modelphase relationships in natural ultrahigh-pressure metamorphicrocks. Under water-saturated conditions, chlorite-bearing assemblagesin Mg- and Al-rich eclogites are stable at lower temperaturesthan in Fe-rich eclogites. The relative temperature stabilityof the three amphiboles is hornblende > actinolite > glaucophane(amphibole names used sensu lato). Talc-bearing assemblagesare stable only at low temperature and high pressure in Mg-and Al-rich eclogites. For most eclogite compositions, talccoexists with lawsonite, but not zoisite, in the stability fieldof coesite. Water content contouring of pressuretemperaturepseudosections, along with appropriate geotherms, provides newconstraints concerning dehydration of such rocks in subductingslabs. Chlorite and lawsonite are two important H2O-carriersin subducting slabs. Depending on bulk composition and pressuretemperaturepath, amphibole may or may not be a major H2O-carrier to depth.In most cases, dehydration to make ultrahigh-pressure eclogitestakes place gradually, with H2O content controlled by divariantor higher variance assemblages. Therefore, fluid fluxes in subductionzones are likely to be continuous, with the rate of dehydrationchanging with changing pressure and temperature. Further, eclogitesof different bulk compositions dehydrate differently. Dehydrationof Fe-rich eclogite is nearly complete at relatively shallowdepth, whereas Mg- and Al-rich eclogites dehydrate continuouslydown to greater depth. KEY WORDS: dehydration; eclogites; phase relations; THERMOCALC; UHP metamorphism; whiteschists 相似文献
83.
The Physico-Chemical Properties of a Subducted Slab from Garnet Zonation Patterns (Sesia Zone, Western Alps) 总被引:3,自引:0,他引:3
KONRAD-SCHMOLKE MATTHIAS; BABIST JOCHEN; HANDY MARK R.; O'BRIEN PATRICK J. 《Journal of Petrology》2006,47(11):2123-2148
Garnets in continentally derived high-pressure (HP) rocks ofthe Sesia Zone (Western Alps) exhibit three different chemicalzonation patterns, depending on sample locality. Comparisonof observed garnet zonation patterns with thermodynamicallymodelled patterns shows that the different patterns are causedby differences in the water content of the subducted protolithsduring prograde metamorphism. Zonation patterns of garnets inwater-saturated host rocks show typical prograde chemical zonationswith steadily increasing pyrope content and increasing XMg,together with bell-shaped spessartine patterns. In contrast,garnets in water-undersaturated rocks have more complex zonationpatterns with a characteristic decrease in pyrope and XMg betweencore and inner rim. In some cases, garnets show an abrupt compositionalchange in core-to-rim profiles, possibly due to water-undersaturationprior to HP metamorphism. Garnets from both water-saturatedand water-undersaturated rocks show signs of intervening growthinterruptions and core resorption. This growth interruptionresults from bulk-rock depletion caused by fractional garnetcrystallization. The water content during burial influences significantly thephysical properties of the subducted rocks. Due to enhancedgarnet crystallization, water-undersaturated rocks, i.e. thoselacking a free fluid phase, become denser than their water-saturatedequivalents, facilitating the subduction of continental material.Although water-bearing phases such as phengite and epidote arestable up to eclogite-facies conditions in these rocks, dehydrationreactions during subduction are lacking in water-undersaturatedrocks up to the transition to the eclogite facies, due to thethermodynamic stability of such hydrous phases at high PTconditions. Our calculations show that garnet zonation patternsstrongly depend on the mineral parageneses stable during garnetgrowth and that certain co-genetic mineral assemblages causedistinct garnet zonation patterns. This observation enablesinterpretation of complex garnet growth zonation patterns interms of garnet-forming reactions and water content during HPmetamorphism, as well determination of detailed PT paths. KEY WORDS: dehydration; high-pressure metamorphism; Sesia Zone; subduction; thermodynamic modelling 相似文献
84.
Ca-rich Garnet-Clinopyroxene Rocks at Hujialin in the Su-Lu Terrane (Eastern China): Deeply Subducted Arc Cumulates? 总被引:3,自引:0,他引:3
Layers of Ca-rich garnetclinopyroxene rocks enclosedin a serpentinite body at Hujialin, in the SuLu terraneof eastern China, preserve igneous textures, relict spinel ingarnet, and exsolution lamellae of Ca-rich garnet, ilmenite/magnetite,Fe-rich spinel, and also amphibole in clinopyroxene. In termsof their major and trace element compositions, the studied samplesform a trend from arc cumulates towards FeTi gabbros.Reconstructed augite compositions plot on the trend for clinopyroxenein arc cumulates. These data suggest that the rocks crystallizedfrom mantle-derived magmas differentiated to various extentsbeneath an arc. The Ca-rich garnet + diopside assemblage isinferred to have formed by compressing Ca-rich augite, whereasthe relatively Mg-rich cores of garnet porphyroblasts may haveformed at the expense of spinel. The protolith cumulates weresubducted from near the crustmantle boundary (c. 1 GPa)deep into the upper mantle (4·8 ± 0·6 GPaand 750 ± 50°C). Negatively sloped PT pathsfor the garnetclinopyroxene rocks and the corollary ofcorner flow induced subduction of mantle wedge peridotite arenot supported by the available data. Cooling with, or without,decompression of the cumulates after the igneous stage probablyoccurred prior to deep subduction. KEY WORDS: arc cumulates; Ca-rich garnet; garnetclinopyroxene rocks; SuLu terrane; UHP metamorphism 相似文献
85.
根据宋楼煤矿主斜井直流电法勘探资料及矿井地质及水文地质条件的分析,煤矿主斜井突水原因应该是来自第四系砂砾石含水层及深层地下岩溶水。通过电法勘探确定裂隙发育带、富水区域、涌水部位,对此处实施钻孔注浆堵水后,恢复生产。 相似文献
86.
煤矿水害多源信息预测方法研究 总被引:1,自引:0,他引:1
基于MAPGIS平台,用Visual C++对其进行二次开发,研制了煤矿水害多源信息预测系统.通过对地震、电法、水文地质等多源数据进行处理后,在MAPGIS系统下进行成图、配准和空间定量分析,建立了预测模型.用该系统对煤矿实际资料进行了处理,结果表明其预测结果较传统方法更为准确. 相似文献
87.
中国大陆科学钻探工程5000m主孔位于苏鲁超高压变质带南部。该钻孔0~2000m主要由榴辉岩、片麻岩、石榴石橄榄岩和少量片岩和石英岩组成。累积厚度达1000多米的榴辉岩具有不同的矿物组成、不同的矿物含量和不同的全岩化学成分,可划分成富Si的石英榴辉岩、富Ti的金红石榴辉岩、富Al的多硅白云母和蓝晶石榴辉岩、富Mg的双矿物榴辉岩和具有正常玄武岩成分的普通榴辉岩。榴辉岩的原岩包括基性层状侵入岩和变质表壳岩。榴辉岩全岩成分对石榴石和绿辉石中某些化学组分的含量有明显控制,而且直接影响到变质条件估算的准确性。扩散成分环带的广泛发育表明超高压矿物在早期退变质过程中发生了成分再平衡。这一事实以及具有成分生长环带石榴石变斑晶的存在,为榴辉岩形成在更高温度(>940℃)和更高压力(>4.5GPa)条件下提供了有力的证据。 相似文献
88.
注水煤体应力能 V-f 转化与释放机理研究 总被引:5,自引:0,他引:5
文章分析了在煤层注水湿润后煤体弹性能的转化与消耗过程,给出在湿润状态下能量由体变弹性能向形变弹性能转化进而自耗释放的理论模型。指出在坚硬干燥煤体中,注水后在水压力和毛细力的切割作用下,裂隙大量扩展,丰富了自由裂隙,产生更多的裂隙启发(裂隙切口),使原来近似的刚性煤体变成由裂隙分割的块体组成的组合体或半组合体。裂隙中水的粘滞作用及水分子吸附力使块体问粘性结合、刚度降低、形变增大。煤体形变弹性能自身消耗释放的形式有3种:产生剪应力导致自由裂隙问错动摩擦;强度降低,使裂隙启发被劈裂成自由裂隙;湿润煤体蠕变性增强,产生整体性移动作功。初步给出能量消耗的量化表达式。通过这一理论,能建立煤层注水湿润度与冲击地压灾害发生的更直接的关系,使进一步量化该关系成为可能。从更深层次解释煤层注水防治冲击地压的机理。 相似文献
89.
以1:5万地质填图和钻探验证为基础,经分析研究塔里木托云盆地的地层特征、聚煤期、古地理环境,从而建立起该区的沉积模式,总结出该盆地煤层发育于下侏罗统康苏组上段地层之中,含煤11层,煤层为不稳定发育,但分布具有一定的规律可寻,对进一步找煤具有一定的指导意义。 相似文献
90.
在初步估算永城煤矿区的环境成本的基础上,对该矿区某矿井经济环境综合价值进行了评价和分析。当考虑矿区煤炭环境成本时,煤炭资源开采的净现值变小,该矿井煤炭资源开采的经济环境综合价值变小。进一步计算了不同环境成本和贴现率时的净现值,为动态决策服务。 相似文献