Isoprene and Its Oxidation Products Methyl Vinyl Ketone, Methacrolein, and Isoprene Related Peroxides Measured Online over the Tropical Rain Forest of Surinam in March 1998   总被引：2，自引：0，他引：2  

C. Warneke  R. Holzinger  A. Hansel  A. Jordan  W. Lindinger  U. Pöschl  J. Williams  P. Hoor  H. Fischer  P. J. Crutzen  H. A. Scheeren  J. Lelieveld 《Journal of Atmospheric Chemistry》2001,38(2):167-185

Airborne measurements of volatile organic compounds (VOC) were performed overthe tropical rainforest in Surinam (0–12 km altitude,2°–7° N, 54°–58° W) using the proton transferreaction mass spectrometry (PTR-MS) technique, which allows online monitoringof compounds like isoprene, its oxidation products methyl vinyl ketone,methacrolein, tentatively identified hydroxy-isoprene-hydroperoxides, andseveral other organic compounds. Isoprene volume mixing ratios (VMR) variedfrom below the detection limit at the highest altitudes to about 7 nmol/molin the planetary boundary layer shortly before sunset. Correlations betweenisoprene and its product compounds were made for different times of day andaltitudes, with the isoprene-hydroperoxides showing the highest correlation.Model calculated mixing ratios of the isoprene oxidation products using adetailed hydrocarbon oxidation mechanism, as well as the intercomparisonmeasurement with air samples collected during the flights in canisters andlater analysed with a GC-FID, showed good agreement with the PTR-MSmeasurements, in particular at the higher mixing ratios.Low OH concentrations in the range of 1–3 × 10⁵molecules cm^-3 averaged over 24 hours were calculated due to lossof OH and HO₂ in the isoprene oxidation chain, thereby stronglyenhancing the lifetime of gases in the forest boundary layer.  相似文献   

Regional Fluxes Of Momentum And Sensible Heat Over A Sub-Arctic Landscape During Late Winter     

Ekaterine Batchvarova  Svan-Erik Gryning  Charlotte Bay Hasager 《Boundary-Layer Meteorology》2001,99(3):489-507

Based on measurements at Sodankylä Meteorological Observatory the regional (aggregated) momentum and sensible heat fluxes are estimated for two days over a site in Finnish Lapland during late winter. The forest covers 49% of the area. The study shows that the forest dominates and controls the regional fluxes of momentum and sensible heat in different ways. The regional momentum flux is found to be 10–20% smaller than the measured momentum flux over the forest, and the regional sensible heat flux is estimated to be 30–50% of the values measured over a coniferous forest.The regional momentum flux is determined in two ways, both based on blending height theory. One is a parameterised method, the other represents a numerical solution of an aggregation model. The regional sensible heat flux is determined from the theory of mixed-layer growth. At near neutral conditions the regional momentum flux can be determined independently of the regional sensible heat flux. At unstable conditions the two models become coupled.The information that is needed by the parameterised blending height method and by the mixed-layer evolution method in order to derive the regional fluxes of momentum and sensible heat can be obtained from radiosonde profiles of wind speed and temperature.  相似文献   

Temporal Surface Ozone Patterns in Urban Manitoba, Canada   总被引：1，自引：0，他引：1  

R. L. Raddatz  J. D. Cummine 《Boundary-Layer Meteorology》2001,99(3):411-428

This study examined temporal surface ozone patternsfor two urban centres in Manitoba,Canada by analyzing hourly concentrations at theWinnipeg downtown (1995–1999), Winnipegresidential (1995–1999) and Brandon industrial(1998–1999) monitoring sites. The characteristicannual ozone cycle and diurnalcycles for June and December were attributable to: (1) theannual and diurnal solar radiation cycles,(2) temporal variations in the emissions of precursorchemical compounds, in particular the source strength ofnitrogen oxides, (3) temporal variationsin the height of the mixed layer, which determinethe degree of dilution of these emissions byatmospheric dispersion, and (4) an in situvolatile organic compound sensitive photochemicalregime, which resulted in decreased concentrations ofozone in response to increasedconcentrations of nitrogen oxides. Onlyone exceedance of the maximum acceptable level of82 ppb was recorded in the study period; itoccurred at the Brandon monitoring site on June 6, 1999.The sequence of weather and the hourly concentrationsof ozone and nitrogen oxides indicatedthat: (1) ozone fumigation, with the transition fromthe nocturnal boundary layer to the daytime mixed layer, mayhave supplemented photochemical ozone formation duringthe morning hours, and (2) during theevening hours, the post cold-frontal downward flux ofozone rich air, which was in the region dueto atmospheric transport, stratosphere-troposphere-exchangeor, possibly, due to the multiplicityof thunderstorms in the area in lateafternoon – early evening, may have been the main cause ofthis rare exceedance event.  相似文献   

ON THE PHYSICS OF FLOW-DRIVEN SEDIMENTS (BED-LOAD)     

Ulrich C. E. ZANKE Prof  Institute of Hydraulic Engineering  University of Technology  Darmstadt  Germany 《国际泥沙研究》2001,16(1)

l PROBLEMS AND AlMSSediments may be transported close to the bed, rolling and sliding, as we1l as susPended in the flow. Forvarious reasons the theoretical treatment of the bed-load problem has been exceptionally difficult. Noanalytical solution had been fOund uP to now, beginning with Du Buat (l786), Huebbe (l86l) and DuBoys (I 879). Since the aPProach of Du Boys numerous new attemPts have been catried out, mostly of anempirical nature. Consequently they are not generally valid an…  相似文献   

MODELING OF THE HIGH CONCENTRATION LAYER OF COHESIVE SEDIMENT UNDER THE ACTION OF WAVES AND CURRENTS     

Qinghe ZHANG Yongsheng WU  Jijian LIANand Pingxing DING School of Civil Engineering  Tianjin University  Tianjin  China Dept. Hydraulic Engineering  Tsinghua University  Beijing  China State Key Lab. of Estuarine  Co 《国际泥沙研究》2001,16(2)

MODELING OF THE HIGH CONCENTRATION LAYEROF COIIESIVE SEDMNT UNDER Tus ACTIONOF WAVES AND CURRENTSQinghe ZHANG', Yongsheng WU', Jiian LIAN1 and Pingxing DING3Abstract:High concenhation layer of cohesive sediment frequenhy occurs in muddy estUaries and coastalzones, and causes raPid siltation of the waterways. A one dimensional vertical coupled modeldescribing the interactions betWeen waves, currentS and suspended cohesive sediment is develoPed inthe pre…  相似文献   

亚洲中东部岩浆岩网络状分布与塑性流动网络   总被引：3，自引：2，他引：3       下载免费PDF全文

王绳祖  张宗淳 《地震地质》1997,19(3):44-247

亚洲中东部的岩浆岩分布具有明显的网络状特征，共轭相交的岩浆岩带构成了晚古生代、中生代和新生代不同的岩浆岩网络系统。岩浆岩网络受岩石圈下层塑性流动网络的控制，是塑性流动带剪切变形、摩擦热效应及带内介质弱化、轻化，以至促成地幔上隆和岩浆上涌的结果。根据“塑性流动－岩浆岩”网络，推测了不同地质时期大陆构造变形的驱动边界、驱动力方向和古构造应力场，并探讨了网络构造的演变等问题  相似文献   

TURBULENCE CHARACTERISTICS OF THE ATMOSPHERIC SURFACE LAYER OVER AN OPEN GRASSLAND^*          下载免费PDF全文

Liu Shuhu  Liu Heping  Liang Fuming  Wu Fenglei  M. Y. Lecler  Xu Mei  Hong Zhongxiang  Li Jun  Liu Huizhi  Na Jingyang 《Acta Meteorologica Sinica》1997,11(3):328-337

Described in this paper is an experiment on atmosphere-surface turbulent exchange and boundary layer turbulence properties conducted in July 1994 over the Kerqin Grassland,Jilin,China.The characteristics of the turbulent spectrum,and the relationships of the standard deviation of the turbulent velocity components and sensible heat flux with the atmospheric stability are studied using data from a sonic anemometer and a fast-response platinum resistance thermometer mounted on a 100 m tower.The results show that in the surface layer over a flat,uniform and open grassland,for a broad stability range(-22.12≤Z_iL≤17.98),the velocity spectra obey the-2/3 power law in the inertial subrange,and 1 power law at low frequencies.Under near neutral stratification,σ_u/u_*=1.20,σ_v/u_*=1.23 and σ_w/u_*=1.02.For Z_i/L≤-0.2,the standard deviations of the turbulent velocity components follow a 1/3 power law.For Z_i/L≤-0.1,the standard deviation of the temperature fluctuations follows a-1/3 power law,and as Z_i/L≤-0.08,it exhibits nonlinear behavior.Sensible heat flux is well correlated to the stability parameter.  相似文献   

冠层内动量和物质吸收特征的数值研究     

雷孝恩  张时禹 《大气科学》1992,16(2):228-236

本文设计了一冠层(CL)和大气边界层(ABL)之间物质和动量交换的耦合模式,并对CL内风速、物质随高度分布和日变化作了数值模拟.结果表明,由大尺度扩散引起冠层低层的第二个风速极大和多极值的浓度分布,CL内湍流通量和物质浓度随高度减小而迅速降低,以及CL动量减小对浓度分布的重要影响,模式都能很好地描述,模拟结果与观测事实有好的一致性.利用浓度和温度廓线相似假设,导出了质量汇的经验关系.  相似文献   

TURBULENCE STRUCTURE AND TRANSFER CHARACTERISTICS IN THE SURFACE LAYER OF HEIFE GOBI AREA          下载免费PDF全文

王介民  刘晓虎  马耀明 《Acta Meteorologica Sinica》1992,(1)

Based on the HEIFE 1988 and 1990 pilot observations,an analysis on the turbulence structure of Gobi surfacelayer,mainly on the similarity formulations of wind and temperature variances,the spectra and cospectracharacteristics,is presented.The phenomenon of downward water vapor flux over Gobi desert in daytime is confirmedin both observations,this and the well-known‘oasis effect’are two sides of a local mesoscale circulation.  相似文献   

Tunable diode laser measurements of trace gases during the 1988 Polarstern cruise and intercomparisons with other methods     

G. W. Harris  D. Klemp  T. Zenker  J. P. Burrows  B. Mathieu 《Journal of Atmospheric Chemistry》1992,15(3-4):315-326

Measurements of NO₂, HCHO, and H₂O₂ were made by the highly specific method of mid infra-red absorption spectroscopy using tunable diode lasers (TDLAS) during the 1988 Polarstern expedition. The TDLAS data are compared to those obtained during the cruise using less direct methods. Southern Hemisphere NO₂ levels suggest nett photochemical destruction of O₃ in the boundary layer. Northern Hemisphere HCHO averaged 0.47±0.2 ppbv; the HCHO measurements are used in a simple calculation to estimate OH noontime maxima of 3–6×10⁶ cm^-3.  相似文献