阻燃级氢氧化镁制备过程中表面有机化改性   总被引：7，自引：0，他引：7       下载免费PDF全文

李晓崑  陈建军  孙海霞  关云山  王爱丽 《盐湖研究》2006,14(1):60-65

文章通过论述阻燃剂型氢氧化镁制备过程中的表面有机化改性,对改性剂、作用机理和改性工艺等进行了探讨,说明了对阻燃剂型氢氧化镁表面有机化改性的重要性,及在氢氧化镁制备过程中综合分析、系统研究的必要性。  相似文献   

Attenuation of aqueous metal transport at two natural acid rock drainage occurrences in the Yukon Territory, Canada     

Y.T. John Kwong 《中国地球化学学报》2006,25(B08):229-230

Naturally acidic drainage associated with pyritic black shale has been observed in many locations in the Yukon Territory. While not necessarily linked to known mineral deposits, most of these natural acid rock drainage occurrences show elevated dissolved concentrations of trace elements, especially zinc, nickel, copper, cadmium and arsenic. Based on field observations, microbial investigation, chemical analyses and geochemical modeling, the fate and transport of potentially deleterious elements at two natural acid drainage occurrences with slightly different settings are examined. The Macintosh Creek is a small, acidic stream （pH 2.98-3.40）, 2 km long, located in the Macmillan Pass area of east-central Yukon amidst known sedimentary exhalative massive sulfide mineralization but remains undisturbed by exploration activities. Its trace metal content is apparently derived from groundwater discharges, which gave as much as 5.0, 2.5, 0.7, 0.13 and 0.03 mg/L ofZn, Ni, Cu and As, respectively. Interaction and sorption reactions with algal mats, biofilms and iron oxyhydroxides appear to be the dominant mechanisms attenuating aqueous contaminant transport along the stream. Cryogenic precipitation further consolidates the ferricrete formation and reduces the mobility of the sorbed metals. The tributaries of the Engineering Creek along the Dempster Highway in northern Yukon drain through a series of dolomite, phyllite, argillite, limestone, black shale, sandstone and conglomerate with no known concentration of mineralization. In this area, the water chemistry fully reflects the local geology with acidic streams invariably associated with black shale occurrences. Groundwater seeps in the headwaters area of the km-180 Creek completely enclosed in black shale gave pH 3.0 and as much as 148, 39, 2.9 and 9.1 mg/L of Zn, Ni, Cu and As, respectively. Sorption with iron oxyhydroxide and organic matter appear to dominate the attenuation of contaminant transport along the stream. However, once entered into carbonate-dominated terrains, secondary carbonate minerals exercise additional geochemical control on the local water chemistry as a result of neutralization.  相似文献   

In situ time resolved synchrotron powder diffraction study of thaumasite     

Annalisa Martucci  Giuseppe Cruciani 《Physics and Chemistry of Minerals》2006,33(10):723-731

Structural changes during dehydration and subsequent decomposition in thaumasite Ca₃Si(SO₄)(CO₃)(OH)₆·12 H₂O were studied by in situ synchrotron powder diffraction between 303 and 1,098 K. Evolution of the crystal structure was observed through 28 structure refinements, by full profile Rietveld analysis performed in the P6₃ space group, between 300 and 417 K, whereupon the thaumasite structure was observed to breakdown. Within this temperature range, the cell parameters of thaumasite increased as a function of temperature in a nearly linear fashion up to about 393 K, at which temperature, a slight slope change was observed. Above 400 K, the thermogravimetric analysis revealed that the dehydration process proceeded very rapidly while the refined occupancy of water molecules dropped below a critical level, leading to instability in the thaumasite structure. At a same time, a remarkable change in the unit cell parameters occurring at about 417 K indicated that the crystal structure of thaumasite collapsed on losing the crystallization water and it turned amorphous. This result indicated that the dehydration/decomposition of thaumasite was induced by the departure of the crystallization water. At about 950 K, anhydrite and cristobalite crystallized from the thaumasite glass.  相似文献   

A Connectivity Index for Discrete Fracture Networks     

C. Xu  P. A. Dowd  K. V. Mardia  R. J. Fowell 《Mathematical Geology》2006,38(5):611-634

Connectivity is an important measure for assessing flow transport in rock, especially through fractures. In this paper, rock fracture systems are modelled by a discrete fracture model simulated by a marked point process. A connectivity index is then introduced to quantify the connectivity between any two points in space. Monte Carlo simulation is used to evaluate the connectivity index for stationary cases and relationships between the connectivity index and the parameters of the discrete fracture model are analysed. The average number of intersections per fracture, X_f, and the fracture intensity, P12 (P32), are calculated and the relationships between these parameters and the connectivity index are investigated, concluding that X_f is the more suitable parameter for the classification of rock mass flow properties. The relationships between the connectivity index and the percolation state of the fractured medium are also discussed. An edge correction is briefly discussed and a practical example is used to demonstrate the method of computing the connectivity index.  相似文献   

Influence of Cyclic Wetting Drying on Collapse Behaviour of Compacted Residual Soil     

Sudhakar M. Rao  K. Revanasiddappa 《Geotechnical and Geological Engineering》2006,24(3):725-734

The climatic zones where residual soils occur are often characterized by alternate wet and dry seasons. Laboratory studies of earlier workers have established that the alternate wetting and drying process affects the swell-shrink potentials, water content, void ratio and particle cementation of expansive soils. The influence of cyclic wetting and drying on the collapse behaviour of residual soils has not been examined. This paper examines the influence of alternate wetting and drying on the collapse behaviour of compacted residual soil specimens from Bangalore District. Results of such a study are useful in anticipating changes in collapse behaviour of compacted residual soil fills. Experimental results indicated that the cyclic wetting and drying process increased the degree of expansiveness of the residual soils and reduced their collapse tendency. Changes in the swell/collapse behaviour of compacted residual soil specimens from wetting drying effects are attributed to reduction in water content, void ratio and possible growth of cementation bonds.  相似文献   

云南元-磨公路某高堑坡灾害发生机制及防治对策     

齐明柱 《中国地质灾害与防治学报》2006,17(2):19-22

论文根据现场地质调查,应用地质力学分析方法,分析了元-磨公路K235 160~600段高堑坡地质条件、病害发生机制和诱发因素。堑坡所在区域位于红河深大断裂与哀牢山深大断裂所夹持的哀牢山褶皱带内,属强烈侵蚀切割的低中山区,河流下切严重,河流阶地不发育。南溪河及其支流小曼萨河、叉河依附于不同时期生成的构造发育而成,堑坡位于小曼萨河注入南溪河的交汇部位小曼萨河的左岸。小曼萨河及南溪河所夹持的山体,尤其是堑坡所在的部位,已严重破碎、松弛,岩石似大块石堆垒状,坡面上的树木均明显地向小曼萨河方向倾倒。经地质力学配套分析,堑坡所依附的山梁形成于红河深大断裂生成期(γ4),堑坡岩体受多期构造活动的作用,其中NW65/°SW64°及NW63/°SW35°两组倾向临空的构造面控制坡体的稳定。堑坡具备发生变形破坏的地质条件,分析认为由于组成坡体的岩土强度不足而引起既有构造面的大型坍塌。连续降雨及温差是诱发因素。基于目前国内边坡防治技术、施工能力,提出了以“治”或“避”为主的防治对策。  相似文献   

江西省宜春城区地面塌陷特征及防治建议   总被引：2，自引：0，他引：2  

刘细元  马振兴  杨永革  吕少俊  张永忠  陶木金 《中国地质灾害与防治学报》2006,17(2):89-94

宜春城区属岗阜低丘地形,分布石炭系-二叠系覆盖型及裸露型碳酸盐岩,占城区面积近70%。浅部岩溶发育,覆盖层厚度一般小于20m,土洞较多,基岩面起伏大,第四系岩性结构复杂,地下水埋藏浅。由于抽采地下水及建筑施工振动等人为因素影响,诱发地面塌陷12处,造成重大经济损失。在城市规划功能布局时应充分考虑地面塌陷的易发程度及场地建设适宜性;应限制诱发塌陷因素的强度,在易发区须严格控制地下水开采,严禁新建开采井;塌陷治理的主要方法有填堵、跨越、灌注、深基础控制抽排水强度、及其它综合治理或避让方法,同时做好灾害的监测预报工作。  相似文献   

江苏省矿山的主要生态环境问题及治理对策     

徐翠云 《中国地质灾害与防治学报》2006,17(2):160-163

江苏的经济发展较快,对矿产资源的需求量亦大。多年来的无序开采,对生态环境造成很大的破坏和影响,出现了山体植被遭受破坏、土地被占用、环境受污染、诱发地面沉降、地面塌陷等一系列问题,已影响到国民经济的发展。随着省人大和省政府关于限制开山采石和保护环境等政策、法规出台和落实,近几年乱采滥挖现象基本得到了有效的遏制。人们的环保意识得到了加强,不少矿山已逐步开始对环境治理,且初见成效。文章介绍了江苏生态环境现状、存在的主要问题和治理对策,以期引起各级政府和广大民众在对矿产资源开采的同时更要注重环境保护。  相似文献   

要十分重视另一类型地质灾害的防治     

蒋承菘 《中国地质灾害与防治学报》2006,17(3):96-97,102

文章提出另一类型地质灾害,即化学型地质灾害的定义及其分类。并认为化学型地质灾害不像物理型地质灾害那样发生瞬时灾害,而有一个延缓过程,但是一旦发生,难于挽救。化学型地质灾害体的主体是化学元素,开展地球化学调查,研究化学元素的赋存规律、土壤及沉积物承受各类元素的极限、各类元素活化的条件是揭示诱发化学型地质灾害机理的关键。因此要十分重视与加强化学型地质灾害的调查、研究、监测与治理工作。  相似文献   

遥控飞艇数字航空摄影系统     

曹立  潘然  田挚 《测绘与空间地理信息》2005,28(5):92-93

提出快速获得航空影像并及时制作DOM、DLG的一种手段.介绍遥控飞艇数字摄影系统的工作原理,探讨存在的问题.  相似文献