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81.
铅—试铁灵络合物吸附波及溴化十六烷基三甲基铵增敏效应的研究 总被引:1,自引:0,他引:1
在030mol/LHAc介质中,Pb(Ⅱ)与7_碘_8_羟基喹啉_5_磺酸(试铁灵,Feron)的络合物于-054V(vs.SCE)产生一尖锐的极谱波,加入溴化十六烷基三甲基铵(CTMAB)显著增敏,可使极谱波增高约4倍。峰电流与Pb(Ⅱ)浓度在96×10-9~48×10-6mol/L呈良好的线性关系,检出限为48×10-9mol/L。用多种电化学方法研究了该极谱波的性质及电极反应机理表明,络合物组成比为nPb(Ⅱ)∶nFeron=1∶1,极谱波为吸附波,峰电流由中心离子Pb(Ⅱ)还原产生,电子转移数为2。试验了多种离子对峰电流的影响,拟定的方法用于矿样分析,结果与原结果相符。 相似文献
82.
中国铬矿资源2010年保证程度与前景 总被引:2,自引:0,他引:2
至1993年底,我国已勘查的铬矿区有56处,累计探明铬矿石储量1305.3万t,主要分布于西藏,新疆,内蒙古等省区,贫矿与富矿(Cr2O3〉32%)大体各占一半,多为中小型矿床,矿床成因主要为岩浆晚期矿床。冶金工业生产不锈钢是铬矿石的最大消费领域,按不锈钢与钢产量比和我国铬矿生产能力测算,2010年只能满足国内铬矿石需求量的15%,其余要靠进口解决。西藏是国内找铬矿的最佳远景区。 相似文献
83.
我国现有锰矿资源状况,不能满足钢铁工业发展的需要。寻找低磷低铁低硅富锰矿,是解决锰矿资源短缺的重要途径。城口锰矿具有较大的找矿前景,锰矿层产出稳定,锰含量高,铁含量低,烧失量大。加强城口矿区勘查,扩大矿床规模,可望成为我国锰矿的重要生产基地。 相似文献
84.
Recent attention given to the concept of vertical integration and disintegration of production processes has identified the existence of a continuum, with small, flexibly specialized producers at one end and large, mass production units at the other end. Firms along the continuum constantly strive for the optimum combination of economies of scale and scope. This paper attempts to identify the organizational characteristics of high technology firms in one industrial complex of the U.S. Manufacturing Belt. A principal components analysis is performed on a number of theoretically relevant variables for a sample of high technology establishments in Northeast Ohio. The results indicate that the region contains a variety of organizational forms ranging from isolated workshops to large, vertically integrated assembly plants. These findings conform to expectations derived from recent conceptualizations in the literature. Additional empirical research will further enhance understanding of the processes that shape the organization of production in territorial complexes. 相似文献
85.
86.
Rapid Variscan exhumation and the role of magma in core complex formation: southern Brittany metamorphic belt, France 总被引:6,自引:0,他引:6
ABSTRACT The high-grade migmatitic core to the southern Brittany metamorphic belt has mineralogical and textural features that suggest high-temperature decompression. The chronology of this decompression and subsequent cooling history have been constrained with 40Ar/39 Ar ages determined for multigrain concentrates of hornblende and muscovite prepared from amphibolite and late-orogenic granite sheets within the migmatitic core, and from amphibolite of the structurally overlying unit. Three hornblende concentrates yield plateau isotope correlation ages of c. 303–298 Ma. Two muscovite concentrates record well-defined plateau ages of c. 306–305 Ma. These ages are geologically significant and date the last cooling through temperatures required for intracrystalline retention of radiogenic argon. The concordancy of the hornblende and muscovite ages suggest rapid post-metamorphic cooling. Extant geochronology and the new 40Ar/39Ar data suggest a minimum time-integrated average cooling rate between c. 725 °C and c. 125 °C of c. 14 ± 4°C Ma-1, although below 600 °C the data permit an infinitely fast rate of cooling. Mineral assemblages and reaction textures in diatexite migmatites suggest c. 4 kbar decompression at 800–750 °C. This must have pre-dated the rapid cooling. Emplacement of two-mica granites into the metamorphic belt occurred between 345 and 300 Ma. The youngest plutons were emplaced synkinematically along shallow-dipping normal faults interpreted to be reactivated Eo-Variscan thrusts. A penetrative, west-plunging stretching lineation developed in these granites suggests that extension was orogen-parallel. Extension was probably related to regional uplift and gravitational collapse of thermally weakened crust during constrictional (escape) tectonics in this narrow part of the Variscan orogen. This followed slab breakoff during the terminal stages of convergence between Gondwana and Laurasia; detachment may have been consequent upon a change in kinematics leading to dextral displacement within the orogen. Dextral ductile strike-slip displacement was concentrated in granites emplaced synkinematically along the South Armorican Shear Zone. Rapid cooling is interpreted to have resulted from tectonic unroofing with emplacement of granite along decollement surfaces. The high-grade migmatitic core of the southern Brittany metamorphic belt represents a type of metamorphic core complex formed during orogen-parallel extensional unroofing and regional-scale ductile flow. 相似文献
87.
在分析电磁系统自然谐振现象的基础上,简述了瞬变电磁场奇点展开法的物理基础、基本理论、极点提取方法,并考查了奇点展开法在地球物理中的应用可能性。 相似文献
88.
89.
Meihua Lu Albrecht W. Hofmann Maurizio Mazzucchelli Giorgio Rivalenti 《Chemical Geology》1997,140(3-4):207-222
Geochemical data are presented for the meta-igneous, mafic-ultramafic complex near Finero. This complex is in contact with a phlogopite-bearing mantle peridotite and is subdivided into the Internal Gabbro unit, the Amphibole Peridotite unit, and the External Gabbro unit. The Internal Gabbro and the Amphibole Peridotite units consist of coarse-grained, chemically heterogeneous cumulates, whereas the External Gabbro unit is generally massive, chemically more uniform and approximately representative of the residual melt with MgO contents between 6.6 and 9.1% and Mg numbers between 38 and 58. Both whole-rock and mineral contents of Ni and Cr are significantly higher (at similar Mg numbers) in the Amphibole Peridotite unit than in the Internal Gabbro unit. The most straightforward interpretation of this is that the Amphibole Peridotite unit accumulated after the influx of fresh mafic (or ultramafic) magma into the magma chamber. Major-element chemical trends are continuous from the Amphibole Peridotite unit to the External Gabbro unit and are consistent with closed-system fractionation with no further addition of magma or contamination by wall or roof rock assimilation. In the External Gabbro unit, total FeO and TiO2 contents are strongly correlated with each other (and with P2O5 and Zr) and reach values as high as 19 and 4%, respectively, indicating an advanced degree of crystal fractionation along a tholeftic trend. The External Gabbro samples have generally smooth normalized trace element patterns, which are consistent with being representative of a liquid composition. The residual nature of the External Gabbro magma is also indicated by negative Eu and Sr anomalies, clear evidence for prior feldspar fractionation. REE patterns are otherwise indistinguishable from N-type MORB, but Th and U are significantly more depleted than in MORB. This Th and U depletion is similar to that found in olivine basalts and picrites on Iceland and Hawaii; its origin is not well understood. No evidence is seen for any assimilation of crystal material, in sharp contrast with the situation of the igneous complex in Val Sesia near Balmuccia, where the magma composition is dominated by assimilation of crust. We suggest that the heat provided by at most two injections of magma near Finero was insufficient to induce crystal anatexis, in contrast with the excess heat supplied by multiple magma injections at Balmuccia. 相似文献
90.
水口山矿田花岗质潜火山杂岩的成因特征 总被引:5,自引:1,他引:5
水口山矿田内发育的花岗质岩石并非是互不联系的单体,而是一套由地下火山作用一潜火山作用在特定的构造条件和不同深度环境下,以不同方式形成的并规律结合的岩浆岩组合──花岗质潜火山杂岩。包括浅成(超浅成)侵入的花岗闪长质岩石、次火山侵入的英安份岩质岩石及其伴生的隐爆碎屑岩类。老鸦巢Ⅳ号角砾岩是英安玢岩质母岩浆在超浅成环境下隐蔽爆破而形成的隐爆角砾岩,它至少存在三条标志以区别于其它各类角砾岩。这套潜火山杂岩具过渡性地质地球化学特征。 相似文献