pH influence on sorption characteristics of heavy metal in the vadose zone   总被引：10，自引：0，他引：10  

M. Elzahabi  R. N. Yong 《Engineering Geology》2001,60(1-4):61-68

Sorption is an important process in the modelling and prediction of the movement of heavy metals in unsaturated clay barriers. This experimental study investigates the effect of pH changes in the acidic range on the sorption characteristics of heavy metals such as: lead, copper and zinc in an unsaturated soil. A series of one-dimensional coupled solute and moisture leaching column tests, using different heavy metal solutions, were conducted on an unsaturated illitic soil at varying pH values. Variations of volumetric water content (VWC) with distance were measured for different time durations, and concentrations of heavy metals in the liquid and solid phases were analysed. Partitioning coefficient profiles of contaminants along the soil column were determined for each individual layer in the soil.

Results from column leaching tests showed that the sorption characteristics of heavy metals are controlled by many factors which should be taken into consideration, i.e. the VWC, time of wetting, soil pH, and the influent heavy metal concentrations. Simplification of K_d as a constant and of the VWC as a linear function cannot be considered a good assumption and may lead to an improper evaluation of the sorption phenomena and also to serious errors in predicting contaminant transport through unsaturated soils.  相似文献   

南边界强迫的非线性临界层与副高的形成、维持和振荡   总被引：4，自引：0，他引：4  

陆维松  陶丽 《气象学报》1996,54(6):651-660

用非线性准地转正压涡度方程模式，在南边界取定常强迫波，采用４种方案模拟了非线性临界层及其上激发的Ｋｅｌｖｉｎ猫眼，以确定热带的定常强迫对副高的形成、维持和振荡的影响。结果表明，南边界定常强迫仍在非线性临界层内激发行星尺度的准定常反气旋的Ｋｅｌｖｉｎ猫眼流场，猫眼的移动、强度和形状变化与夏季副高比较相似．而北边界定常强迫所得结果与夏季副高差异较大。因此，南边界所激发的非线性临界层上的Ｋｅｌｖｉｎ猫眼可能是夏季副高形成、维持和振荡的一种更为重要的新物理机制。文中还提出准定常行星波穿越副热带的非线性临界层的物理机制。  相似文献   

Variations in heavy metals concentrations in Antarctic snows from 1940 to 1980   总被引：1，自引：0，他引：1  

U. Görlach  C. F. Boutron 《Journal of Atmospheric Chemistry》1992,14(1-4):205-222

Concentrations of Pb, Cd, Cu and Zn have been measured using improved ultraclean procedures in a succession of twenty six snow samples integrating a 40 yr time sequence from 1940 to 1980 which were collected from the walls of a 6 m deep pit at stake D 55 in Adelie Land, East Antarctica. Measured concentrations, which are among the lowest ones ever measured in Antarctic snows, are found not to have significantly increased during the investigated time period, with the possible exception of Pb for which there might have been a significant increase after the mid 1960's. For this last metal, measured concentrations in the 1940's are about 6-fold higher than in Antarctic Holocene ice several thousand years old, which indicates that a large fraction of the anthropogenic increase for Pb probably occurred before the 1940's.  相似文献   

Studies on Separation of Heavy Metals from Acidic Solutions by Foam Fractionation with Respect to an Application on Acidic Soil Extracts     

S. Wmmel  W. Calmano 《洁净——土壤、空气、水》1992,20(5):265-268

An experimental investigation is presented on the batch foam fractionation of the heavy metal cations Pb²⁺, Cd²⁺, Cu²⁺, Sb³⁺ and As⁵⁺ from diluted aqueous solutions with hexamethylenedithiocarbamate (HMDC) as complexing agent and sodiumdodecylsulfate (SDS) as surfactant. Among the considered pH-values of 2,4 and 7 the pH 2 experiments allow a direct application of foam fractionation on acidic extracts from heavy metal contaminated soil. The experiments at pH 2 and pH 4 show better results than those at neutral pH. Although a simple device was used, a maximum enrichment factor of 13.8 and a minimum removal factor of 0.01 have been measured. The flotation with weak organic acids like citric acid (CA) and acetic acid (AA) show about 50–70% smaller enrichment factors than those acidified with hydrochloric acid. The dissolution and mixing of the reacting components as well as the concentration of the detergent and the gaseous volume flow can be regarded as basic parameters of foam fractionation.  相似文献   

单个粘土体裂缝中水流规律的研究   总被引：2，自引：0，他引：2       下载免费PDF全文

葛中华  范炳恒 《地质学报》1993,67(2):159-167

通过模型实验,研究粘土体裂缝中的水流规律,提出了临界水位上升速度的概念。水位上升速度大于临界值时,裂缝中水流量增加,反之则减少。裂缝水流量与水位不呈正比关系。指出粘土裂缝中最大水流量要比相同条件下基岩裂缝水流量小30—40倍。随着水流运动的延续,水流量将逐渐变小。在水流作用下,粘土裂缝宽度将变窄3.0—4.0cm,裂缝深度也大幅度变浅到裂缝水深的50％以上。  相似文献   

NON-LINEAR CRITICAL LAYER IN EL NINO AND LA NINA YEARS AND FORMATION, MAINTENTENANCE AND OSCILLATION OF THE SUBTROPICAL HIGH     

陶丽  陆维松 《热带气象学报(英文版)》1999,5(2):113-122

Monthly mean zonal wind data from the European Center for Medium-range Weather Forecasting(ECMWF)for December 1982, April 1983, October 1984 and ApriI 1985 are used in numerical integration as thebasic flow in a non-linear critical-layer model. The subtropical high is extensive and limited in number if simulated with the basic now in December 1982 and April 1983. It consists of 2 to 3 cells that move westward at alloscillatory periods of 1～2 months. The subtropical high, simulated with the basic flow in October 1984 and April1 985. is weak and small in coverage, or distributed in strips that contain up to 4 cells. The high. merged or spillover a short time. is moving westward. The years 1982 ～1983 are a process of EI Niño while the years 1984-1985one of La Niña. lt is known from the chart of energy flux that it oscillates by a much larger amplitude and longerperiod in the EI Niño year than in the La Niña year. All the results above have indicated that the basic flow in the EI Niño year is enhancing the subtropical high lagging by about 4 months and that in the La Niña year is decay'ing it. It is consiStent with the well-known observational fact that the SSTA in the equatorial eastern Pacitlc ispositively correlated with the extent and intensity of the subtropical high in west Pacific lagging by 1～2 seasons.The result is also important for further study of the formation, maintenance and oscillation of the subtropicalhigh.  相似文献   

Trace metal composition of and accumulation rates of sediments in the Upper Gulf of Thailand     

Herbert L. Windom  Suchada Silpipat  Aurapin Chanpongsang  Ralph G. Smith  Manuwadi Hungspreugs 《Estuarine, Coastal and Shelf Science》1984,19(2):133-142

Sediment cores and grab samples were collected in the Upper Gulf of Thailand to determine sedimentation rates and to determine if metal concentrations reflect anthropogenic inputs.Accumulation rates of sediments in the Upper Gulf measured using the ²¹⁰Pb method, appear to vary from ca. 4 to 11 mm yr^?1. Sediment budgets suggest that little of the sediment delivered to the Upper Gulf by the major rivers is ultimately transported to the Lower Gulf. Metal concentrations in Upper Gulf sediments appear to be dominantly controlled by natural inputs.  相似文献   

The role of coarse colloids as a carrier phase for trace metals in riverine systems   总被引：2，自引：0，他引：2  

Davide Vignati  Janusz Dominik 《Aquatic Sciences - Research Across Boundaries》2003,65(2):129-142

  相似文献   

浙江省滑坡灾害预警预报的降雨阀值研究   总被引：28，自引：0，他引：28  

谢剑明  刘礼领  殷坤龙  杜惠良  钮学新 《地质科技情报》2003,22(4):101-105

根据浙江省降雨的特点,将降雨分为台风降雨和非台风降雨,采用统计方法研究了区域性滑坡灾害与台风区和非台风区降雨量及降雨强度的相关性,通过相关性分析确定了有效降雨量模型;得到了浙江省区域性滑坡发生的临界降雨量和降雨强度阀值,为实时时间预警提供了定量依据;将滑坡灾害的空间易发性与降雨量和降雨强度相结合确定了滑坡灾害的空间预警区划指标和等级;最后初步研究了滑坡发生的滞后时间。  相似文献   

泥沙起动判别标准探讨   总被引：3，自引：1，他引：2       下载免费PDF全文

何文社  方铎  曹叔尤  杨具瑞  刘兴年 《水科学进展》2003,14(2):143-146

分析了现有起动标准的不足之处。在制定起动标准时,不但要考虑水流条件,还必须考虑泥沙颗粒在床面的相对位置。对同一粒径的泥沙颗粒,其起动条件不是一个常量,而是位于一个区间,它随颗粒在床面的相对暴露度而变化。根据力学原理,推导了泥沙颗粒起动时的临界无量纲切应力公式,并对其系数取值进行了理论计算。计算结果表明,对同一粒径、在同一起动状态下,泥沙颗粒的起动临界条件并非一个常量。并从理论上分析得到了临界值的范围,对个别及少量起动,其无量纲临界切应力为0.021～0.042及0.041～0.062。  相似文献