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101.
Carbonyl products have been identified and their formation yields measured in experiments involving the gas phase reaction of ozone with 1,1-disubstituted alkenes at ambient T and p=1 atm. of air. Sufficient cyclohexane was added to scavenge the hydroxyl radical in order to minimize OH-alkene and OH-carbonyl reactions. Formation yields (carbonyl formed/ozone reacted) of primary carbonyls were close to the value of 1.0 that is consistent with the mechanism: O3+R1R2C=CH2 (HCHO+R1R2COO)+(1–)(R1COR2+H2COO) where formaldehyde and the ketone R1 COR2 are the primary carbonyls and R1R2COO and H2COO are the corresponding biradicals. Measured values of were 0.58–0.82 and indicate modest preferential formation of formaldehyde and the disubstituted biradical as compared to the ketone and the biradical H2COO. Carbonyls other than the primary carbonyls were identified. Their formation is discussed in terms of subsequent reactions of the disubstituted biradicals R1R2COO. Similarities and differences between disubstituted and monosubstituted biradicals are outlined. 相似文献
102.
L. G. Kodosky 《Environmental Geology》1994,23(1):65-72
Analysis of 153 residential air radon (Rn-222) screening measurements from southeast Michigan indicates that basements host Rn levels two to three times higher than upper-level rooms. Compared to unfinished basements, finished (e.g., paneled walls, tiled floors) basements apparently reduce indoor air Rn levels while partially finished basements may not. Factor analysis of residence questionnaire data explains 59 percent of the Rn data variance. The volume of pathways (e.g., foundation cracks/holes, uncapped sumps) allowing Rn seepage into the dwelling controls the largest portion, 23 percent, of the explained data variance. The residence water source explains 11 percent of the Rn data variance. Groundwater Rn levels contribute to the air Rn data variability, but the study data cannot quantitatively assess this contribution. Seven percent of the Rn data variance is likely controlled by house depressurization facilitated by residence structural properties. Residences with foundation cracks or poorly sealed joints and low-volume indoor-outdoor air exchange are more prone to this effect. Eighteen percent of the explained Rn data variance correlates with the residence's primary heat source. Evidently, operating combustion sources also induce house depressurization and allow Rn to be drawn into the house through entry paths. Twenty-four percent of the analyses equal or exceed 4 pCi/1 Rn. In residences occupied 5 years by the same individuals, 17 percent of the Rn data are 4 pCi/l; here the arithmetic mean air Rn level is 8.3 pCi/l and the average occupancy period 17.4 years. 相似文献
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Josef Vesely Heather Almquist-Jacobson Lisa M. Miller Stephen A. Norton Peter Appleby Aruna S. Dixit John P. Smol 《Journal of Paleolimnology》1993,8(3):211-231
This multi-disciplinary investigation documents the longterm effects of atmospheric pollution of metals and acids on a geologically sensitive catchment in the umava Mountains, southwestern Czech Republic, a region with a long history of human disturbance. A 30 cm long sediment core (I) from ertovo Lake was analyzed for natural and artifical radionuclides, metals, diatoms, chrysophytes, and pollen in sediments accumulated during the last 200 years. A second core (II), extending to 95 cm, included sediment judged to be free of atmospheric deposition of pollutants associated with the Industrial Revolution. Chronostratigraphic markers include several changes in the pollen assemblages corresponding to well-documented changes in land-use, and distinct distributions of 137Cs, 134Cs and 241Am from weapons testing and the 1986 nuclear accident at Chernobyl, Russia. These markers corroborate the 210Pb dating and, together, produce a reliable chronology extending back nearly to 1800 A.D.Stratigraphic profiles of Cu, Pb, and Zn in Core I are unlike any previously reported in the literature. Concentrations of Cu, Pb, and Zn remain generally above 100, 400, and 200 g g-1, respectively, for the 200 years represented by Core I. These values are unusually high for sediments from a watershed with no known heavy-metal ore bodies. Accumulation rates for Cu, Pb, and Zn, which include both atmospheric and watershed contributions, are also high (ca 1, > 1 and > 1 g cm-2 yr-1, respectively) for the same period, although the anthropogenic contribution of Zn rose from nearly zero at 1800 A.D. The Cu and Pb accumulation rates rose dramatically about 1640 A.D.Accumulation rates of anthropogenically-derived Be, a relatively abundant element in the soft coals of the region, are also elevated by about 0.01 g cm-2 yr-1 in sediments of this period. Vanadium accumulation rates increased only since 1980 A.D., presumably along with increased consumption of oil.Diatom assemblages illustrate that the lake was acidic (pH between 4.5 and 5) through at least the past 200 years. The pH declined significantly (from ca 5 to 4) between 1960 and 1985 with a slight increase to 4.5 in the last few years. Recent diatom and chrysophyte assemblages suggest high trace metal concentrations, consistent with the present lake-water chemistry. 相似文献
107.
目的:基于网络药理学与分子对接技术探讨青蛇方外用治疗湿疹的作用机制。方法:应用TCMSP和UniProt数据库平台查询青蛇方组方的有效活性成分及靶基因,与疾病靶基因取交集后构建蛋白质-蛋白质相互作用(PPI)网络;应用DAVID数据库,对潜在核心作用靶点基因进行基因本体(GO)功能、京都基因与基因组百科全书(KEGG)通路富集分析。利用分子对接原理论证青蛇方生物活性成分与核心靶点的分子结合能力。结果:筛选出青蛇方有效成分63种,作用靶点99个;主要有β-谷甾醇、2,4,7-三羟基-9,10-二氢菲、靛蓝素、豆甾醇、色氨酸等关键成分;转录因子AP-1(JUN)、肿瘤坏死因子(TNF)、原癌基因(RELA)、干扰素γ(IFNG)、转化生长因子-β1(TGF-β1)等核心基因。关键信号通路有癌症信号通路、恰加斯病通路、弓形体病通路、脂质和动脉粥样硬化通路等,分子对接结果显示活性成分与核心靶点基因结合能力较强。结论:青蛇方外用可以通过多种活性成分、多种通路有效抑制免疫炎症反应,促进免疫系统正常运行,从而达到治疗湿疹的目的。 相似文献
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Onthespatialcharacteristicoftheshort┐termandimminentanomaliesofundergroundwaterbehaviorsbeforestrongearthquakeXUE-BINDU(杜学彬)... 相似文献
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洛安江水库灌溉工程是贵州黔北万亩以上骨干工程之一,中华人民共和国成立初期建成。1991年"7.5F"洪灾,连续大暴雨,河水暴涨,倒灌暗河,产生高静、动水压力作用。岸坡岩体受不利结构面组合,发生顺层岩质滑坡,破坏干渠,严重影响灌溉。本文根据滑坡破坏情况,对滑坡产生的地质环境、滑坡特征、滑坡形成机理(滑坡形式和破坏机理,各种稳定性分析与评价),以及产生滑坡原因进行了初步分析。 相似文献