Zircon M127 – A Homogeneous Reference Material for SIMS U–Pb Geochronology Combined with Hafnium,Oxygen and,Potentially, Lithium Isotope Analysis          下载免费PDF全文

Lutz Nasdala  Fernando Corfu  John W. Valley  Michael J. Spicuzza  Fu‐Yuan Wu  Qiu‐Li Li  Yue‐Heng Yang  Chris Fisher  Carsten Münker  Allen K. Kennedy  Peter W. Reiners  Andreas Kronz  Michael Wiedenbeck  Richard Wirth  Chutimun Chanmuang  Manuela Zeug  Tamás Váczi  Nicholas Norberg  Tobias Häger  Alfred Kröner  Wolfgang Hofmeister 《Geostandards and Geoanalytical Research》2016,40(4):457-475

In this article, we document a detailed analytical characterisation of zircon M127, a homogeneous 12.7 carat gemstone from Ratnapura, Sri Lanka. Zircon M127 has TIMS‐determined mean U–Pb radiogenic isotopic ratios of 0.084743 ± 0.000027 for ²⁰⁶Pb/²³⁸U and 0.67676 ± 0.00023 for ²⁰⁷Pb/²³⁵U (weighted means, 2s uncertainties). Its ²⁰⁶Pb/²³⁸U age of 524.36 ± 0.16 Ma (95% confidence uncertainty) is concordant within the uncertainties of decay constants. The δ¹⁸O value (determined by laser fluorination) is 8.26 ± 0.06‰ VSMOW (2s), and the mean ¹⁷⁶Hf/¹⁷⁷Hf ratio (determined by solution ICP‐MS) is 0.282396 ± 0.000004 (2s). The SIMS‐determined δ⁷Li value is ?0.6 ± 0.9‰ (2s), with a mean mass fraction of 1.0 ± 0.1 μg g^?1 Li (2s). Zircon M127 contains ~ 923 μg g^?1 U. The moderate degree of radiation damage corresponds well with the time‐integrated self‐irradiation dose of 1.82 × 10¹⁸ alpha events per gram. This observation, and the (U–Th)/He age of 426 ± 7 Ma (2s), which is typical of unheated Sri Lankan zircon, enable us to exclude any thermal treatment. Zircon M127 is proposed as a reference material for the determination of zircon U–Pb ages by means of SIMS in combination with hafnium and stable isotope (oxygen and potentially also lithium) determination.  相似文献   

Ablation Characteristic of Ilmenite using UV Nanosecond and Femtosecond Lasers: Implications for Non‐Matrix‐Matched Quantification          下载免费PDF全文

Zhen Li  Zhaochu Hu  Detlef Günther  Keqing Zong  Yongsheng Liu  Tao Luo  Wen Zhang  Shan Gao  Shenghong Hu 《Geostandards and Geoanalytical Research》2016,40(4):477-491

Ilmenite (FeTiO₃) is a common accessory mineral and has been used as a powerful petrogenetic indicator in many geological settings. Elemental fractionation and matrix effects in ilmenite (CRN63E‐K) and silicate glass (NIST SRM 610) were investigated using 193 nm ArF excimer nanosecond (ns) laser and 257 nm femtosecond (fs) laser ablation systems coupled to an inductively coupled plasma‐mass spectrometer. The concentration‐normalised ⁵⁷Fe and ⁴⁹Ti responses in ilmenite were higher than those in NIST SRM 610 by a factor of 1.8 using fs‐LA. Compared with the 193 nm excimer laser, smaller elemental fractionation was observed using the 257 nm fs laser. When using 193 nm excimer laser ablation, the selected range of the laser energy density had a significant effect on the elemental fractionation in ilmenite. Scanning electron microscopy images of ablation craters and the morphologies of the deposited aerosol materials showed more melting effects and an enlarged particle deposition area around the ablation site of the ns‐LA‐generated crater when compared with those using fs‐LA. The ejected material around the ns crater predominantly consisted of large droplets of resolidified molten material; however, the ejected material around the fs crater consisted of agglomerates of fine particles with ‘rough' shapes. These observations are a result of the different ablation mechanisms for ns‐ and fs‐LAs. Non‐matrix‐matched calibration was applied for the analysis of ilmenite samples using NIST SRM 610 as a reference material for both 193 nm excimer LA‐ICP‐MS and fs‐LA‐ICP‐MS. Similar analytical results for most elements in ilmenite samples were obtained using both 193 nm excimer LA‐ICP‐MS at a high laser energy density of 12.7 J cm^?2 and fs‐LA‐ICP‐MS.  相似文献   

The terrestrial fauna of the Late Triassic Pant-y-ffynnon Quarry fissures,South Wales,UK and a new species of Clevosaurus (Lepidosauria: Rhynchocephalia)     

Emily Keeble  David I. Whiteside  Michael J. Benton 《Proceedings of the Geologists' Association. Geologists' Association》2018,129(2):99-119

Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.  相似文献   

菲律宾迪纳加特岛30^#矿权区红土型镍矿床地质特征及成矿作用探讨          下载免费PDF全文

江胜国  王志刚  曹健 《地质找矿论丛》2018,33(2):299-305

30~#矿权区位于菲律宾迪纳加特岛北部,区内发育有红土型镍矿床。本次勘查圈定4处矿(化)体,其中以Ⅰ、Ⅱ、Ⅲ矿(化)体的矿化范围较大,厚度变化系数为45%~50%(相对稳定),经济价值较高。红土型镍矿体平面上呈地毯状展布于地表,厚度受地形控制,富镍矿体分布于矿权区东部的5、6、11、12小区;剖面上从地表向深部矿体为铁质红土层、松散红土层及高岭土化蛇纹石化橄榄岩层。30~#矿权区红土镍矿矿床的形成经历了从普通矿到富矿两个阶段,红土镍矿石属于酸性矿石。  相似文献   

Appropriate Spatial Sampling of Rainfall or Flow Simulation/Echantillonnage Spatial de la Pluie Approprié pour la Simulation D'écoulements     

《水文科学杂志》2013,58(2)

Abstract

The objective of this study is to find the appropriate number and location of raingauges for a river basin for flow simulation by using statistical analyses and hydrological modelling. First, a statistical method is used to identify the appropriate number of raingauges. Herein the effect of the number of raingauges on the cross-correlation coefficient between areally averaged rainfall and discharge is investigated. Second, a lumped HBV model is used to investigate the effect of the number of raingauges on hydrological modelling performance. The Qingjiang River basin with 26 raingauges in China is used for a case study. The results show that both cross-correlation coefficient and modelling performance increase hyperbolically, and level off after five raingauges (therefore identified to be the appropriate number of rain-gauges) for this basin. The geographical locations of raingauges which give the best and worst hydrological modelling performance are identified, which shows that there is a strong dependence on the local geographical and climatic patterns.  相似文献   

Fuzzy Optimization Neural Network Approach for Ice Forecast in the Inner Mongolia Reach of the Yellow River/Approche d'Optimisation Floue de Réseau de Neurones pour la Prévision de la Glace Dans le Tronçon de Mongolie Intérieure du Fleuve Jaune     

《水文科学杂志》2013,58(2)

Abstract

In ice forecasting, a key problem is the forecast of freeze-up and break-up dates. Ice-water mechanics and the principle of heat-exchange were mainly adopted in previous research. However, the mathematical models in these studies are complex and many parameters are required in relation to upstream and/or downstream gauging stations. Moreover, too many assumptions or simplifications for these parameters and constraints directly lead to low accuracy of the models and limitations as to their practical applications. This paper develops a fuzzy optimization neural network approach for the forecast of freeze-up date and break-up date. The Inner Mongolia reach lies in the top north of the Yellow River, China. Almost every year ice floods occur because of its special geographical location, hydrometeorological conditions and river course characteristics. Therefore, it is of particular importance for ice flood prevention to forecast freeze-up date and break-up date accurately. A case study in this region shows that the proposed methodology may allow obtaining useful results.  相似文献   

Are artificial neural network techniques relevant for the estimation of longitudinal dispersion coefficient in rivers? / Les techniques de réseaux de neurones artificiels sont-elles pertinentes pour estimer le coefficient de dispersion longitudinale en rivières?     

《水文科学杂志》2013,58(1)

Abstract

Abstract Accurate application of the longitudinal dispersion model requires that specially designed experimental studies are performed in the river reach under consideration. Such studies are usually very expensive, so in order to quantify the longitudinal dispersion coefficient, as an alternative approach, various researchers have proposed numerous empirical formulae based on hydraulic and morphometric characteristics. The results are presented of the application of artificial neural networks as a parameter estimation technique. Five different cases were considered with the network trained for different arrangements of input nodes, such as channel depth, channel width, cross-sectionally averaged water velocity, shear velocity and sinuosity index. In the case where the sinuosity index is included as an input node, the results turned out to be better than those presented by other authors.  相似文献   

Relations indices de Végétation–Pluie au Burkina Faso: Cas du Bassin Versant du Nakambé/Relationship between Rainfall and Vegetation Indexes in Burkina Faso: A Case Study of the Nakambé Basin     

《水文科学杂志》2013,58(2)

Abstract

This work deals with the problem of the use of remote sensing data derived from NOAA/AVHRR observations for monitoring the West African Sahel climatic variability. NDVI is widely used in hydrological and climatological research, and in the study of global climatic changes. The relationships between NDVI and climatic parameters are not well established yet and are the focus of many studies. The relationships between NDVI and rainfall were studied at a 10-day time step in the Nakambe River basin in Burkina Faso in the Sahelo-Sudanian area over the years 1982–1999. Good correlations were found in the annual evolution of these two variables. The statistical analysis shows a significant relationship between NDVI and the sum of the annual rainfall with determination coefficients greater than 0.80. At the spatial scale of 0.5° × 0.5°, the determination coefficient ranges from 0.91 to 0.96. It was also found that the NDVI is a good indicator of the determination of the beginning and the end of the rainy season. It gives reasonably good results in comparison with the other methods commonly used in the study region.  相似文献   

Trend detection in river flow series: 1. Annual maximum flow / Détection de tendance dans des séries de débit fluvial: 1. Débit maximum annuel     

《水文科学杂志》2013,58(5)

Abstract

Results of a study on change detection in hydrological time series of annual maximum river flow are presented. Out of more than a thousand long time series made available by the Global Runoff Data Centre (GRDC) in Koblenz, Germany, a worldwide data set consisting of 195 long series of daily mean flow records was selected, based on such criteria as length of series, currency, lack of gaps and missing values, adequate geographical distribution, and priority to smaller catchments. The analysis of annual maximum flows does not support the hypothesis of ubiquitous growth of high flows. Although 27 cases of strong, statistically significant increase were identified by the Mann-Kendall test, there are 31 decreases as well, and most (137) time series do not show any significant changes (at the 10% level). Caution is advised in interpreting these results as flooding is a complex phenomenon, caused by a number of factors that can be associated with local, regional, and hemispheric climatic processes. Moreover, river flow has strong natural variability and exhibits long-term persistence which can confound the results of trend and significance tests.  相似文献   

Influences of coupled wind–water processes on suspended sediment grain size: an example from tributaries of the Yellow River / Influences de processus couplés éoliens-hydriques sur la granulométrie des matières en suspension: exemple d'affluents du Fleuve Jaune     

《水文科学杂志》2013,58(5)

Abstract

Some unique coupled wind–water erosion processes exist in the desert-loess transitional zone in the middle Yellow River basin. Based on data from 40 stations on 29 rivers, a study was made on the influence of such processes on suspended sediment grain-size characteristics of the tributaries of the Yellow River. Results show that the percentage of >0.05-mm grain size decreases with the increased annual mean precipitation, but increases with the increase in the annual mean number of sand-dust storm days. The percentage of <0.01-mm grain size increases with the increase in the annual mean precipitation, but decreases with the increase in the annual number of sand-dust storm days. Based on annual mean data from 40 stations, multiple regression equations were established between the percentages of >0.05-mm grain size (r _>0.05) and <0.01-mm grain size (r _<0.01), annual mean precipitation (P _m) and annual mean number of sand-dust storm days (D _ss). On this basis, the relative contributions of the variations in D _ss and P _m to the variation in r _>0.05 and r _<0.01 were estimated. The results indicate that the variation in sand-dust storm frequency exerts greater influences on the variation in grain-size characteristics of suspended load than does the variation in annual mean precipitation. With the increase in the coupled wind–water processes index, expressed by P _m/D _ss, the percentage of >0.05-mm grain size in suspended sediment decreases and the percentage of <0.01-mm grain size increases. With the variation in P _m/D _ss, different combinations of r _>0.05 with r _<0.01 appear, which have some influence on the formation of hyperconcentrated flows. There exist some optimal ratios of coarse to fine fractions in suspended sediment that make sediment concentrations of hyperconcentrated flows the highest. The optimal r _>0.05/r _<0.01 value is related to some range of the index P _m/D _ss. When the P _m/D _ss index falls in this range, the optimum combination of relative coarse with fine sediments in the suspended load appears, and thus results in the peak values of sediment concentration.  相似文献