天然气水合物体系动态演化研究（I）：地质历史演变     

宋海斌 《地球物理学进展》2003,18(2):188-196

1995年Dickens对55．5Ma前古新世末增温事件进行了研究，提出天然气水合物作为全球环境变化重要因子的假说．认为古新世末增温事件溶解无机碳-2～-3‰的^13δC位移可以用水合物所含甲烷的释放与随后氧化成二氧化碳来解释．此后，地质历史演变中的天然气水合物演化研究蓬勃发展，本文总结古新世末增温事件、新元古代末期雪球事件、第四纪千年尺度事件等最新进展，为天然气水合物动态演化研究提供基础．开展天然气水合物-天然气体系动态演化过程数值模拟与特征分析，可望促进天然气水合物在全球变化与碳循环中作用的深入认识．  相似文献   

Fluid mixing as the mechanism of formation of the Dajing Cu-Sn-Ag-Pb-Zn ore deposit,Inner Mongolia ——Fluid inclusion and stable isotope evidence   总被引：2，自引：0，他引：2  

刘伟  李新俊  谭骏 《中国科学D辑(英文版)》2003,46(7)

Since the 1990s, interest in the magmatic fluids and their relation to mineralization has been re-aroused[1—6]. Studies on stable isotopes of low-sulfidation deposits commonly show the predominance of meteoric water[7]. Paradoxically, the evidence for me…  相似文献   

鄂尔多斯盆地苏里格庙与靖边天然气单体碳同位素特征及其成因   总被引：7，自引：1，他引：7  

付锁堂  冯乔  张文正 《沉积学报》2003,21(3):528-532,538

苏里格庙上古生界砂岩气藏天然气重烃含量高,干燥系数低,为湿气;靖边奥陶系风化壳气藏天然气重烃含量低,干燥系数高,属干气。苏里格庙天然气的正构烷烃碳同位素具有δ13 C₁<δ13 C₃ <δ13 C₂ <δ13 C4的规律,靖边天然气具有δ13 C₁<δ13 C₂ <δ13 C₃ 的规律。二者高碳数烷烃的同位素差别较大,尤其是苏里格庙的乙烷碳同位素比靖边平均重 3.6‰。根据天然气单体碳同位素及其含量变化,苏里格庙天然气属煤成气,靖边天然气属煤成气与油型气的混合气。苏里格庙和靖边天然气中均含少量CO₂ 气,其碳同位素表明苏里格庙除苏 5井为无机CO₂ 气外,均为有机CO₂ 气;靖边林 1、林 5井为无机CO₂ 气,陕参 1井为有机CO₂ 气。结合烷烃气和CO₂ 气,苏里格庙天然气可以分为含有机CO₂ 煤成气和含无机CO₂ 煤成气。碳同位素比值与Ro 关系分析认为,苏里格庙的天然气成熟度处于成熟到高成熟阶段,其相应气源岩的平均Ro 为 1.2 9%～ 1.39%,这一结果与该区二叠系煤岩的成熟度符合较好。  相似文献   

再论印度—亚洲大陆碰撞的启动时间   总被引：39，自引：6，他引：39       下载免费PDF全文

王成善  李祥辉等 《地质学报》2003,77(1):16-24

利用沉积响应来识别印度－亚洲大陆碰撞启动时间是最直接和有效的方法之一。西藏仲巴错江顶群被甄别为碰撞型三角洲沉积，曲下组可能代表了碰撞启动时期的建造，藏南定日的海相白垩－古近系沉积演化，锶和碳同位素变化也支持两大陆碰撞启动时间大约在K／T界线时期，对比喜马拉雅西段碰撞启动时间并考虑大印度北缘失掉的宽度，提出两大陆量可能的碰撞启动时间是65Ma左右。  相似文献   

辽宁宽甸新生代火山岩和地幔包体He-Ar同位素组成   总被引：8，自引：1，他引：8  

吴茂炳  王先彬  叶先仁  刘春燕 《地球化学》2003,32(5):401-405

宽甸新生代碱性玄武岩、地幔包体及辉石巨晶的稀有气体同位素组成和流体含量分析表明，不同岩性稀有气体含量的差异反映了岩浆作用过程中轻、重稀有气体的分馏特性，较轻的稀有气体(He、Ne)比较重的稀有气体(Kr、Xe)具有更高的活动性和不相容性；该地区上地幔源区具有典型的MORB型源区特征，以辉石巨晶为代表；地幔包体的3^He／^4He值较低，可能与地幔上隆过程中富集地幔流体的交代作用或地幔塑性变形作用丢失了部分原始He有关；大陆碱性玄武岩具有与大洋玄武岩截然不同的He同位素组成，反映了大陆区地幔岩浆上升过程中受到了陆壳物质混染。地幔源区^40Ar／^36Ar值为350左右，二辉橄榄岩和碱性火山岩的^40Ar／^36Ar值比大气略高，可能有大气组分的混入。部分样品中有^21Ne、^22Ne、^129Xe、^134Xe和^136Xe相对于大气的过剩现象。  相似文献   

Provenance analysis and tectonic setting of the Ordovician clastic deposits in the southern Puna Basin, NW Argentina   总被引：9，自引：0，他引：9  

Udo Zimmermann  Heinrich Bahlburg† 《Sedimentology》2003,50(6):1079-1104

Provenance studies on Early to Middle Ordovician clastic formations of the southern Puna basin in north-western Argentina indicate that the sedimentary detritus is generally composed of reworked crustal material. Tremadoc quartz-rich turbidites (Tolar Chico Formation, mean composition Q_t89 F7 L4) are followed by volcaniclastic rocks and greywackes (Tolillar Formation, mean Q_t33 F42 L25). These are in turn overlain by volcaniclastic deposits (mean Q_t24 F30 L46) of the Diablo Formation (late Arenig–early Llanvirn) that are intercalated by lava flows. All units were deformed in the Oclóyic Orogeny during the Middle and Late Ordovician. Sandstones of the Tolar Chico Formation are characterized by Th/Sc ratios > 1, La/Sc ratios ≈ 10, whereas associated fine-grained wackes show slightly lower values for both ratios. LREE (light rare earth elements) enrichment of the arenites is ≈ 50× chondrite, Eu/Eu* values are between 0·72 and 0·92, and flat HREE (heavy rare earth elements) patterns indicate a derivation from mostly felsic rocks of typical upper crustal composition. The ε_{Nd(t = sed)} values scatter around −11 to −9. The calculated Nd-T_DM residence ages vary between 1·8 and 2·0 Ga indicating contribution by a Palaeoproterozoic crustal component. The Th/Sc and La/Sc ratios of the Tolillar Formation are lower than those of the Tolar Chico Formation. Normalized REE (rare earth elements) patterns display a similar shape to PAAS (post-Archaean average Australian shale) but with higher abundances of HREEs. Eu/Eu* values range between 0·44 and 1·17, where the higher values reflect the abundance of plagioclase and feldspar-bearing volcanic lithoclasts. Average ε_{Nd(t = sed)} values are less negative at −5·1, and Nd-T_DM are lower at 1·6 Ga. This is consistent with characteristics of regional rocks of upper continental crust composition, which most probably represent the sources of the studied detritus. The rocks of the Diablo Formation have the lowest Th/Sc and La/Sc ratios, lower LREE abundances than the average continental crust and are slightly enriched in HREEs. Eu/Eu* values are between 0·63 and 1·17. The Nd isotopes (ε_{Nd(t = sed)} = −3 to −1; T_DM = 1·2 Ga) indicate that one source component was less fractionated than both the underlying Early Ordovician and the overlying Middle Ordovician units. Synsedimentary vulcanites in the Diablo Formation show the same isotopic composition. Our data indicate that the sedimentary detritus is generally composed of reworked crustal material, but that the Diablo Formation appears to contain ≈ 80% of a less fractionated component, derived from a contemporaneous continental volcanic arc. There are no data indicating an exotic detrital source or the accretion of an exotic block at this part of the Gondwana margin during the Ordovician.  相似文献   

Geology and Genesis of the Ta'ergou Skarn - Quartz Vein Tungsten Deposit in the North Qilian Caledonian Orogenic Belt, Northwest China     

Zuoheng Zhang    Jingwen Mao    Jianmin Yang    Zhiliang Wang  Zhaochong Zhang 《Resource Geology》2003,53(2):101-114

Abstract. The Ta'ergou tungsten deposit in Gansu province, northwestern China, is located in the western part of the North Qilian Caledonian orogen, and consists of scheelite skarn bodies and wolframite quartz veins. The tungsten‐bearing skarn developed by the replacement of carbonate layers intercalated in the Precambrian schist and amphibolite whereas wolframite‐quartz ore veins developed along a group of fractures that cut through horizontal skarns. The Ta'ergou tungsten deposit is genetically related to the Caledonian Yeniutan granodiorite intrusion and occurs ca. 500 m wide in the exo‐contact zone 300 ～ 500 m apart from the intrusion. The granodiorite displays a lower grade of differentiation, low content of SiO₂ and high contents of mafic components. There are three types of fluid inclusions in the wolframite‐quartz vein systems, i. e. aqueous, CO₂‐H₂O and CO₂‐rich. The homogenization temperature of aqueous inclusion ranges from 140 to 380d?C and their salinities from 6.4 to 17.4 equivalent wt% NaCl. Laser Raman spectroscopy shows that the inclusions contain a relatively high content of CO₂. The δ³⁴S values of skarn type sulfides range from +8.1 to +12.7 per mil and those of quartz vein sulfides from +9.3 to +14.9 per mil, similar to sulfides of the granodiorite with from +6.0 to +11.7 per mil. The δ¹⁸O values of quartz are between +10.5 and +13.3 per mil and those of wolframite between +3.4 and +5.1 per mil. The δ¹⁸O water values of ore forming fluids range from +0.6 to +6.4 per mil and suggest the mixture of magmatic fluids with meteoric water formed the ore‐forming fluids. It has been proved that Precambrian strata in the west sector of North Qilian region are enriched in tungsten. We propose the strata were remelted to be tungsten‐granitoid during subduction. The polymetallic tungsten was gradually accumulated into the roof pendants of the granite intrusion by fractional crystallization and then was deposited by hydrothermal fluids during metasomatism and infilling along fractures. On the other hand, the granite intrusion also acted as “heating machine” to make hydrothermal fluids leach out the metals from Precambrian strata and these metals joined the ore‐forming hydrothermal system.  相似文献   

Chemical, Isotopic, and Fluid Inclusion Evidence for the Hydrothermal Alteration of the Footwall Rocks of the BIF-Hosted Iron Ore Deposits in the Hamersley District, Western Australia     

Makoto Haruna    Takahiro Hanamuro    Kaoru Uyeda    Hirokazu Fujimaki  Hiroshi Ohmoto 《Resource Geology》2003,53(2):75-88

Abstract. The petrography, chemical, fluid inclusion and isotope analyses (O, Rb-Sr) were conducted for the shale samples of the Mount McRae Shale collected from the Tom Price, Newman, and Paraburdoo mines in the Hamersley Basin, Western Australia. The Mount McRae Shale at these mines occurs as a footwall unit of the secondary, hematite-rich iron ores derived from the Brockman Iron Formation, one of the largest banded iron formations (BIFs) in the world. Unusually low contents of Na, Ca, and Sr in the shales suggest that these elements were leached away from the shale after deposition. The δ¹⁸O (SMOW) values fall in the range of + 15.0 to +17.9 per mil and show the positive correlation with calculated quartz/sericite ratios of the shale samples. This suggests that the oxygen isotopic compositions of shale samples were homogenized and equilibrated by postdepositional event. The pyrite nodules hosted by shales are often rimmed by thin layers of silica of varying crystallinity. Fluid inclusions in quartz crystals rimming a pyrite nodule show homogenization temperatures ranging from 100 to 240C for 47 inclusions and salinities ranging from 0.4 to 12.3 wt% NaCl equivalent for 18 inclusions. These fluid inclusion data give direct evidence for the hydrothermal activity and are comparable to those of the vein quartz collected from the BIF-derived secondary iron ores (Taylor et al, 2001). The Rb-Sr age for the Mount McRae Shale is 1,952 ± 289 Ma and at least 200 million years younger than the depositional age of the Brockman Iron Formation of ∼ 2.5 Ga in age. All the data obtained in this study are consistent with the suggestion that high temperature hydrothermal fluids were responsible for both the secondary iron ore formation and the alteration of the Mount McRae Shale.  相似文献   

硫同位素混合总体筛分   总被引：4，自引：1，他引：4       下载免费PDF全文

崔彬  赵磊  詹朝阳  和志军 《地球学报》2003,24(6):494-496

现代矿床学研究表明，绝大多数矿床的形成具有多来源、多阶段、多成因的特点。定量研究S同位素来源可将形成一个矿床的过程看作是多个总体的混合或叠加，在数学上这种混合或叠加可以用混合总体筛分的数学模型来描述。笔者在长江中下游地区和湖南东坡矿田中成功地应用混合总体筛分的数学模型，定量研究了S同位素来源的问题，这一问题的解决对于研究成矿物质来源和成矿机理具有重要的意义。  相似文献   

高放废物处置系统地下水同位素特征   总被引：4，自引：1，他引：4  

郭永海  刘淑芬  吕川河 《地球学报》2003,24(6):525-528

在高放废物处置库场地特性评价中，对于深地质处置方案而言，最有可能使放射性核素进入生物圈的机制是地下水的迁移，因此，水文地质研究是场址预选和评价中的一个重要内容。本文以甘肃北山预选区旧井地段为例，根据地下水同位素数据，结合所获得的地质、水文数据和信息，分析研究了研究区基岩地下水的起源、形成、演化和循环特征。研究表明，北山预选区旧井地段，深部地下水和浅部地下水均源自大气降水的补给，弱含水、低渗透、低流速是该区的主要水文地质特征。  相似文献