Intercalation of kaolinite with acetamide     

R. L. Frost  J. Kristof  G. N. Paroz  J. T. Kloprogge 《Physics and Chemistry of Minerals》1999,26(3):257-263

Upon intercalation of both ordered (low defect) and disordered (high defect) kaolinites with acetamide, two types of interaction are observed. Firstly, hydrogen bonding between the NH₂ groups of the acetamide with the siloxane oxygens is formed, as evidenced by the formation of two new bands at 3400 and 3509 cm^–1. Secondly, the appearance of additional bands at ∼3600 cm^–1 in both the infrared and Raman spectra of the acetamide intercalates is attributed to a second type of hydrogen bonding by the interaction of the C=O group and the inner surface hydroxyls. Changes in the intensity of the hydroxyl deformation modes in the 895 to 940 cm^–1 region are attributed to the changes in the hydrogen bonding of the kaolinite surfaces. It is proposed that the hydrogen bonding between the adjacent kaolinite layers is replaced with hydrogen bonding between both kaolinite surfaces and the acetamide molecule. Changes in the molecular structure of acetamide are observed upon intercalation. The amide 1 band is lost and replaced with a well-defined NH₂ deformation vibration. The loss of the amide 1 band is attributed the hydrogen bond formation between the amide hydrogens and the siloxane surface. The bands of the C=O group at 1680 and 1740 cm^–1 become a single band at 1680 cm^–1. The amide 2 band remains unchanged. The lack of intensity of the 1740 cm^–1 band is attributed to the formation of hydrogen bonding between the inner surface hydroxyl groups and the carbonyl group. Received: 4 February 1998/ Revised, accepted: 30 June 1998  相似文献   

Structural and magnetic properties of Co2Al4Si5O18 and Mn2Al4Si5O18 cordierite     

K. Knorr  M. Meschke  B. Winkler 《Physics and Chemistry of Minerals》1999,26(6):521-529

The crystal structures, lattice dynamics and magnetic properties of synthetic Co-cordierite, Co₂Al₄Si₅O₁₈, and Mn-cordierite, Mn₂Al₄Si₅O₁₈ have been studied by neutron powder diffraction, infrared spectroscopy and magnetisation measurements. Due to different synthesis conditions, the Co-cordierite used here crystallised in the hexagonal α-cordierite structure with a disordered Si/Al distribution in the framework, while for the Mn-cordierite the orthorhombic β-structure has been determined. The experimentally determined paramagnetic moments, _exp (Mn) = 5.47(6) _B and _exp (Co) = 3.88(4) _B , are in good agreement with theoretical predictions for octahedrally coordinated Mn²⁺ and Co²⁺, respectively. In both compounds there is no magnetic long-range order down to at least 1.5 K. However, the onset of an anti-ferromagnetic short-range correlation of magnetic moments along [001] has been observed for Mn-cordierite by magnetisation and neutron diffraction measurements. This short-range magnetic correlation becomes evident from diffuse scattering observed at 2 K. The diffuse scattering has been interpreted in terms of a Blech-Averbach function. Received: 30 June 1998 / Revised, accepted: 3 March 1999  相似文献   

Temperature evolution between 50 K and 320 K of the thermal expansion tensor of gypsum derived from neutron powder diffraction data     

K. S. Knight  I. C. Stretton  P. F. Schofield 《Physics and Chemistry of Minerals》1999,26(6):477-483

The unit cell parameters, extracted from Rietveld analysis of neutron powder diffraction data collected between 4.2 K and 320 K, have been used to calculate the temperature evolution of the thermal expansion tensor for gypsum for 50 ≤ T ≤ 320 K. At 300 K the magnitudes of the principal axes are α ₁₁  = 1.2(6) × 10⁻⁶ K⁻¹, α ₂₂  = 36.82(1) × 10⁻⁶ K⁻¹ and α ₃₃  = 25.1(5) × 10⁻⁶ K⁻¹. The maximum axis, α ₂₂ , is parallel to b, and using Institution of Radio Engineers (IRE) convention for the tensor orthonormal basis, the axes α ₁₁ and α ₃₃ have directions equal to (−0.979, 0, 0.201) and (0.201, 0, 0.979) respectively. The orientation and temperature dependent behaviour of the thermal expansion tensor is related to the crystal structure in the I2/a setting. Received 12 February 1998 / Revised, accepted 19 October 1998  相似文献   

High temperature dehydroxylation of muscovite-2M1: a kinetic study by in situ XRPD     

E. Mazzucato  G. Artioli  A. Gualtieri 《Physics and Chemistry of Minerals》1999,26(5):375-381

Muscovite-2M₁ shows a major phase transition at about 800°C, which is generally attributed in the literature to the structural dehydroxylation process, although a number of structural models have been proposed for the dehydroxylated phase, and different transformation mechanisms have also been put forward. The observed first order transformation involves an increase in the cell volume, and it is not clear to date how the cell expansion is related to the loss of hydroxyl groups. The phase change has been re-investigated here by in situ high temperature powder diffraction, both in non-isothermal and isothermal modes, to combine for the first time the structural and the kinetic interpretation of the transformation. The results unequivocally confirm that the reaction taking place in the temperature range 700–1000°C is truly a dehydroxylation process, involving the nucleation and growth of the high temperature dehydroxylated phase, having Al in 5-fold coordination. Structural simulations of the basal peaks of the powder diffraction patterns indicate that the model originally proposed by Udagawa et al. (1974) for the dehydroxylated phase correctly describes the high temperature phase. The kinetic analysis of the isothermal data using an Avrami-type model yields values for the reaction order compatible with a reaction mechanism limited by a monodimensional diffusion step. Apparent activation energy of the process in vacuum is about 251 kJ/mol. Experiments carried out at temperatures much higher than the onset temperature of the reaction show that the dehydroxylation reaction overlaps with the reaction of formation of mullite, the final product in the reaction pathway. Received: 24 April 1998 / Revised, accepted: 12 October 1998  相似文献   

Nonlinear Effect of Wave Propagation in Shallow Water   总被引：7，自引：2，他引：5  

LI Ruijie  WANG Houjie Associate Professor  Ocean University of Qingdao  Qingdao  P. R. China. Graduate Student  Ocean University of Qingdao  Qingdao  P. R. China. 《中国海洋工程》1999,(1)

—In this paper,a nonlinear model is presented to describe wave transformation in shallow wat-er with the zero-vorticity equation of wave-number vector and energy conservation equation.Thenonlinear effect due to an empirical dispersion relation(by Hedges)is compared with that of Dalrymple＇sdispersion relation.The model is tested against the laboratory measurements for the case of a submergedelliptical shoal on a slope beach,where both refraction and diffraction are significant.The computation re-sults,compared with those obtained through linear dispersion relation.show that the nonlinear effect ofwave transformation in shallow water is important.And the empirical dispersion relation is suitable for re-searching the nonlinearity of wave in shallow water.  相似文献   

水下圆形浅滩附近波浪绕射的计算   总被引：2，自引：0，他引：2  

王亮  李瑞杰 《海岸工程》1999,18(3):1-4

采用波数矢量无旋和波能守恒方程对圆形浅滩附近水域波浪绕射进行了数值计算,计算模型中采用Ｂａｔｔｊｅｓ关系与波数矢量无旋,波能量守恒方程一起联合求解圆形浅滩附近水域波浪折射影响下的波浪要素。本文的数值计算模型对圆形浅滩水域波浪折射绕射现象的验证结果表明,计算所得结果与试验结果是吻合的,数学模型是可靠和合理的,具有实用价值。  相似文献   

Tracing sediment transport history using mineralogical fingerprinting in a river basin with dams utilizing sediment sluicing     

Kenichi Ito  Motohide Matsunaga  Tomoya Itakiyo  Hiroyuki Oishi  Kei Nukazawa  Mitsuteru Irie  Yoshihiro Suzuki 《国际泥沙研究》2023,38(3):469-480

Sediment causes a serious problem in relation to dam function. A cooperative sediment sluicing operation has been under way since 2017 to prevent sediment from accumulating in dams in the Mimi River,Miyazaki, Japan. To achieve a smooth and stable operation, it is very important to determine the sediment source and a sediment transport system to maintain the dam’s function. In the current study, the source and transport of sediment from the Mimi River basin have been analyzed with X-ray diffracti...  相似文献   

单晶高温合金X射线衍射斑点自动识别算法研究     

张哲  朱锦霞  庄凯  谢光  秦秀波  魏存峰 《CT理论与应用研究》2017,26(4):447-455

单晶高温合金展现出优越的抗疲劳性能和高温蠕变性能,广泛应用于航空发动机和燃气轮机的热端部件。但是,其制备过程中会产生晶体取向偏离、杂晶等缺陷。目前国际上已经普遍使用X射线劳埃衍射技术对单晶叶片的晶体缺陷进行无损检测,但是这种检测方法主要依赖人工识别,效率低,结果可重复性差,不适合批量化检测。本文结合工程需要,提出对劳埃衍射斑点进行自动识别的算法,主要包括衍射图样的预处理、轮廓检测、轮廓形态筛选及轮廓符合检测等。该算法能够自动检测出衍射图样上的衍射斑点,并最终给出斑点的位置坐标数据及其误差。根据衍射斑点的位置,通过衍射分析算法,计算出单晶叶片上的晶体取向,并最终对叶片的晶体缺陷给出综合评价。   相似文献   

层状半空间中周期分布凸起地形对平面SH波的散射   总被引：1，自引：0，他引：1       下载免费PDF全文

巴振宁  黄棣旸  梁建文  张艳菊 《地球物理学报》2017,60(3):1039-1052

提出了一种新的以层状半空间中周期分布斜线荷载动力格林函数为基本解的间接边界元方法,研究了周期分布凸起地形对平面SH波的散射问题.方法将散射波场分解为凸起内部散射波场和凸起外部散射波场.凸起内部散射波场通过在凸起闭合边界上施加虚拟斜线荷载产生的动力响应来模拟,而凸起外部散射波场则通过在凸起与半空间交界面上施加虚拟周期分布斜线荷载产生的动力响应来模拟.周期分布斜线荷载动力格林函数的引入,使得本文方法仅需针对一个凸起进行边界单元的离散和求解,便可完成问题的求解,避免了通过截断无限边界求解而引入的误差,方法具有较高精度的同时显著降低了求解自由度.文中通过与已有结果的比较,验证了方法的正确性,并以均匀半空间和基岩上单一土层中周期分布凸起为例进行了数值计算分析.研究表明,凸起间距对凸起地形间的动力相互作用有着显著的影响,同时层状半空间中周期分布凸起地形对SH波的散射与均匀半空间情况也有着显著的差别.  相似文献   

多方向不规则波传播变形数值模拟   总被引：2，自引：1，他引：1  

潘军宁左其华  王红川 《海洋工程》2004,22(3):14-19,29

在推广的缓坡方程数学模型基础上建立了多方向不规则波数学模型,综合考虑了波浪折射、绕射、反射、底摩擦和风能输入等因素。基于线性波浪理论,将波浪方向谱在频率和方向上按等能量分割法离散后,分别计算各组成波的传播变形,再计算合成波要素。缓坡方程数学模型采用改进的ADI法求解,计算效率高,稳定性好。采用椭圆形浅滩不规则波模型试验结果和单突堤不规则波绕射理论解对数学模型进行了验证,数值模拟结果和试验值及理论解符合良好。利用该模型进行了某港港内波浪折射、绕射和反射的联合数值模拟,给出了合理的港内波高分布。  相似文献