晶体点阵参数最小二乘法计算程序     

陈蓉美 《湖南地质》1990,9(1):54-59

作者以最小二乘法理法导出了晶体点阵参数计算的公式,并顾及了X射线粉晶衍射图测定所引起的系统误差修正,从而得到点阵参数的最佳估值。以导出的公式为数学模型编制了PC-1500微机的扩展BASIC语言程序,可适用于各晶系点阵参数的计算,使用方便。  相似文献   

斜方辉石的反演畴结构对其衍射效应的影响   总被引：1，自引：0，他引：1  

徐洪武  薛纪越 《矿物岩石》1991,11(2):1-4

斜方辉石内部存在着众多的相邻间呈反演关系的(100)晶畴。这些晶畴的存在使斜方辉石的K为奇数的okl衍射之强度明显减弱,且参与衍射的晶畴的数目越多,其减弱的程度也就越大。这一现象在一定程度上掩盖了斜方辉石P2_(1ca)的真实对称性。与X射线衍射相比,利用电子衍射来研究斜方辉石的空间群类型具有明显的优越性。  相似文献   

黑硼锡镁矿孪晶的电子衍射分析     

赵文霞  杨光明  潘兆橹 《岩石矿物学杂志》1991,10(4):339-344

黑硼锡镁矿是1985年在我国发现的一种新矿物,微孪晶特别发育,其电子衍射斑点往往具规律的分裂现像。用选区电子衍射获得[010]、[141]和[121]定向带轴电子衍射斑点分裂图,经矩阵分析,确定两套斑点分裂是由其呈挛晶结构关系所致,孪晶面为(101),属于面律孪晶,这种孪晶的微形貌由明场像(BF)得到证实。根据不同取向的电子衍射图,确定该矿物属单斜晶系,a_0=10.7,b_0=3.01,c_0=5.39,β=94.5°。上述挛晶结构特征及其晶体学数据与X射线单晶研究结果有很好的可比性。  相似文献   

衍射指标h和k的互换问题     

张冠英 《矿物学报》1986,(2)

通过衍射线指标和面网指标的联系讨论了晶体的对称性对衍射指标h和k互换的影响。在下列情况下衍射指标h和k是不能互换的:在低级晶族;在四方晶系C_(4h)—4/m劳厄点群,六方品系C_(6h)—6/m劳厄点群和立方晶系T_h—m3劳厄点群对于hko和kkl型衍射;在三方晶系选取六方晶胞的情况下,在C_(3i)—3劳厄点群对于hol,okl,hko和hkl型衍射,在D_(3d)—3m劳厄点群对于holokl和hkl型衍射,以及在菱面体点阵除非h和k都是三的倍数。  相似文献   

合成斜方辉石系列的红外光谱研究     

彭文世  谢鸿森  张月明  薛承林  徐惠刚 《矿物学报》1986,(4)

在30kbar和900℃条件下,用等化学计量氧化物混合物合成了11个斜方辉石系列的样品,并对合成的样品进行了X射线粉晶分析和红外光谱分析。分析结果表明,晶胞参数和红外光谱随化学成分的改变而产生复杂的变化。不仅晶胞参数b和M而且频率ν_(670cm)-1和M之间存在很好的线性相关关系,通过用最小二乘法所拟合的相关方程可容易地测定斜方辉石的成分,但是α和c与M之间只有较差的线性关系,而ν_(450cm)-1和M以及ν_(380cm)-1和M之间并无简单的线性相关关系,这可归因于Fe~(2+)在M_1和M_2位置的有序分布。  相似文献   

Uniform half-plane elastodynamic problems by an approximate boundary element method     

Dionyssia-Pinelopi N. Kontoni  Dimitri E. Beskos 《Soil Dynamics and Earthquake Engineering》1987,6(4):227-238

In this paper the applicability of an approximate Boundary Element Method to uniform half-plane elastodynamic problems is investigated. This method employs the concept of images to construct approximate fundamental solutions for the half-plane and does not require any half-plane surface discretization. The method is formulated in the frequency domain for the case of harmonic disturbances or the Laplace transform domain for the case of transient disturbances. In the latter case a numerical inversion of the transformed solution is necessary to obtain the time domain response. The proposed method can be used as an alternative to boundary element methods that either utilize the infinite plane fundamental solution and thus require a half-plane surface discretization, or employ the exact half-plane fundamental solution, which even though leads to no surface discretization, is of a very lengthy and complicated form. Two characteristics numerical examples are used to illustrate the proposed method and study its advantages and disadvantages.  相似文献   

罕见的蓝色饵-纳透闪石研究     

廖尚宜  金萍 《矿物岩石地球化学通报》2001,20(3):190-193

尽管角闪石在地壳中大量存在 ,但是蓝色钾 钠透闪石却是角闪石中的稀有品种。本文采用X射粉晶线衍射和晶胞参数计算 ,确定该矿物为蓝色的钾 钠透闪石 ,用电子探针 (EMPA)精确分析了它的化学成分 ,确定为钾 钠透闪石 ,而不是蓝色软玉 (即不是透闪石或阳起石 )。  相似文献   

Parajamesonite revisited: background of the discreditation of an enigmatic mineral species     

Gábor Papp  Alan J. Criddle  Chris J. Stanley  László Kriston  Géza Nagy 《Swiss Journal of Geoscience》2007,100(3):495-502

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Investigation of NaCl deliquescence in porous substrates using RH-XRD     

Kirsten Linnow  Herbert Juling  Michael Steiger 《Environmental Geology》2007,52(2):317-327

We report on the use of X-ray diffractometry under controlled conditions of temperature and relative humidity (RH-XRD) for the investigation of NaCl deliquescence in the pore space of glass filter frits, which were used as model substrates. The study confirms that RH-XRD is an appropriate experimental technique for the in situ observation of phase transformation in porous materials. It is used for an investigation of both the deliquescence kinetics and the deliquescence humidity within pores of different median pore diameter. Several major influences affecting deliquescence rates in the pore space close to the surface of a porous material are discussed. It appears that quite short-term variation of ambient relative humidity, e.g., typical daily fluctuations, might induce damaging deliquescence–crystallization cycles within the pore space of building materials. In agreement with theoretical considerations it was found that confinement of NaCl crystals in pores with median diameters in the range 1.4–70 μm does not affect the deliquescence humidity of the salt.  相似文献   

X-ray diffraction investigation of native Si-Fe alloy minerals from Luobusha, Tibet     

Li Guowu  Shi Nicheng  Xiong Ming  Ma Zhesheng  Bai Wenji  Fang Qingsong 《Frontiers of Earth Science》2007,1(1):21-25

The origin of native Si-Fe alloy mineral is thought to be related with mantle and aerolite. The native Si-Fe alloy minerals from podiform chromites of the Luobusha ophiolite in the Yarlong Zangbo suture zone were examined by a new method for powder-like diffractograms of small single crystals, using an SMART APEX-CCD area-detector X-ray diffractometer. The powder diffraction pattern shows that the minerals are composed of FeSi, FeSi₂, β-FeSi₂ and native silicon. The association of these minerals suggests that the crystallization order of the mineral may be from early to late FeSi→FeSi₂→native silicon, accompanied by gradually increasing deoxidization. Translated from Acta Petrologica et Mineralogica, 2005, 24(5): 453–456 [译自: 岩石矿物学杂志]  相似文献