Treatment of high fluoride concentration wastewater by layered double hydroxides： Mechanism studies   总被引：1，自引：0，他引：1  

Liang LU Jing HE 《中国地球化学学报》2006,25(B08):160-161

An appropriate concentration of fluoride in drinking water is required to prevent dental cavities, but long-term ingestion of water that contains more than a suitable level of fluoride can cause bone disease and mottling of the teeth. Fluoride ions can be found in wastewater from the fluoride chemical industry, as well as the semiconductor, metal processing, fertilizer, and glass-manufacturing industries. The discharge standard for fluoride in industrial wastewater in China is 10 mg/L. Efficient treatment of fluoride-containing wastewater is therefore of major concern in China, following the rapid development of the fluoride chemical industry. Several methods have been used to remove fluoride from water, such as adsorption, chemical precipitation, electrodialysis, ion exchange and electrochemical processes. Layered double hydroxides （LDHs） are anionic clays with high anion exchange capacities which are effective adsorbents for removal of a variety of anionic pollutants. LDHs have been studied as potential adsorbents for removing toxic anionic species such as CrO4^2-, TcO4^-, SeO3^2-, pesticides, and anionic surfactants from aqueous systems. One of the main attractions of using LDHs for fluoride removal, is that unlike other chemical treatment methods, no chemical sludge should be produced. In the present study, an attempt was made to investigate the mechanism of fluoride removal by LDHs under different conditions using batch methods. In addition, the release of fluoride adsorbed on LDHs by treatment with an aqueous solution of Na2CO3 was studied. The residual fluoride was found to be 10 mg/L in a solution with an initial concentration of 1000 mg/L, which meets the discharge standard for fluoride in industrial wastewater in China.  相似文献   

我国地质找矿取心（样）钻探设备现状及提高效能的分析研究          下载免费PDF全文

张永勤 《探矿工程》2006,33(8):45-50

概述了我国地质找矿钻探市场现状及前景，分析研究了地质取样钻探传统的立轴钻机及全液压动力头钻机的优缺点及综合效能，针对国家提出加强地质工作的形势及中国的实际状况，提出了完善和改进我国现有钻探设备、提高我国地质找矿取样钻探效率、降低能耗及成本的观点及建议。  相似文献   

土钉墙与预应力锚杆联合支护技术          下载免费PDF全文

杨生彬 《探矿工程》2006,33(8):8-10,16

北京市深基坑工程中土钉墙支护技术应用比较广泛，对于边坡变形要求严格的基坑，采用土钉墙与预应力锚杆联合支护技术可有效控制变形，结合工程实例，介绍了该技术的设计思路及应用过程，说明了该技术的适用性，并就施工中遇到的问题进行分析，给出相应的处理措施。  相似文献   

复合土钉墙支护技术在某大型软土基坑围护中的应用          下载免费PDF全文

杜常春  章泽军  李飞  周喜锋 《探矿工程》2006,33(2):26-29

根据拟建建筑基坑的工程地质条件、周边环境条件、基坑开挖深度等特点综合考虑，对基坑分段采用超前微型桩支护加土钉墙、放坡加土钉墙2种复合支护方案。实践证明，该工程所采用的多种复合式支护实施方案，技术安全可靠，经济合理。  相似文献   

广州科学城保利林语山庄高边坡支护工程的实践          下载免费PDF全文

陈国勇  吴厚信  杨枫  杨年发  黄涛 《探矿工程》2006,33(5):33

主要介绍了广州科学城保利林语山庄高边坡支护设计方案与施工方法。支护方案综合采用了锚索、锚杆、抗滑桩、钢管桩、格构梁及挡土墙等多种支护方法，有效地提高了边坡的稳定性。应用有限元方法来验证设计方案的合理性，模拟结果与工程实践基本吻合。  相似文献   

Structural Evolvement of Heating Treatment of Mg/AI-LDH and Preparation of Mineral Mesoporous Materials     

CHEN Tianhu XU Huifang WANG Yifeng QING Chengsong FAN Mingde CHEN Gang 《《地质学报》英文版》2006,80(2):170-174

Although hydrotalcite, or layered double hydroxides （LDHs）, is not a common mineral, it is an important material that can be easily synthesized in laboratory. In this study, structural evolvement and BET surface area changes of heat treated Mg/AI-LDH is evaluated by XRD, TEM and N2-BET analyses. The results indicate that the magnesium-aluminum LDH with carbonate as interlayer anion, periclase-like oxides was formed at temperatures of 400-800℃. Meanwhile, 2-3 nanometer mesoporous were formed during decomposition of LDH. However, the heat treated samples still preserve the morphology of the original LDH plates. Periclase-like formed from LDH heat treatment may re-hydrolyze and recover the structure of LDH. However, crystallinity of the recovered LDH is lower than that of the original LDH. This heat treatment will result in formation of （Mg, Al）-oxide nano-crystals and nanopores among the nano-crystals. When heating temperature exceeds 1000, the periclase-like （Mg, Al）-oxide is transformed into a composite with periclase （MgO） and spinel phases. The periclase can be re-hydrolyzed and dissolved in HCl solution. After acid treatment, the sample with a high surface area is composed of spinel nano-crystals and nanopores among them. Our results will provide a new and economic way to synthesize mesoporous materials through pathways of phase transformation of precursor materials with different composition.  相似文献   

T形短肢剪力墙静力性能有限元仿真分析   总被引：4，自引：0，他引：4  

王建祥  苏枋  胡景龙  李青宁  于建军 《工程地质学报》2006,14(5):703-708

利用有限元分析软件ANSYS,首先采用其中三维实体单元SOLID65建立了T形短肢剪力墙有限元分析模型,从弹性到混凝土开裂直至破坏的全过程进行了仿真试验分析。分析了影响短肢剪力墙受力的几种因素:混凝土强度等级、配筋率、轴压比、墙肢截面高厚比对短肢剪力墙承载能力、变形能力及延性的影响,剖析了短肢剪力墙破坏过程及其原因。比较真实的反映了短肢剪力墙在轴压力和逐步加载侧向力共同作用下的响应。试验结果表明:增加混凝土等级和轴压比能提高试件的开裂、屈服和极限荷载,但应综合考虑其与变形能力、延性的关系。截面配筋率具有其特殊性,配筋率在1.4%1.6%之间时试件的承载能力、变形能力及延性较好。墙肢截面高厚比是不稳定因素但在高厚比为6.57.1时,延性及变形能力较强。  相似文献   

地下水中硝基苯污染的防控技术—泥浆回灌法构筑阻截墙     

李绪谦  马莉  蒋惠忠  宗芳  李爽  刘利 《吉林大学学报(地球科学版)》2006,(Z1)

硝基苯污染可使地下水环境质量急剧恶化。利用阻截墙控制地下水中的硝基苯污染范围的扩大,是控制地下水环境继续恶化的经济、有效方法之一。以粘土、沸石、铁粉、硫酸钙等与水调配成泥浆,利用压力向井中回灌,将泥浆注入到含水层中,可有效地阻截地下水中硝基苯的扩散。  相似文献   

惯性／双星组合导航系统的滤波与仿真   总被引：2，自引：0，他引：2  

蔺玉亭李洪涛  孙付平吴太旗 《测绘学院学报》2005,22(1):21-23

介绍了惯性导航系统和双星导航系统各自的运行方式和优缺点；详细推导了组合导航系统的误差方程和量测方程；介绍了Kalman滤波的整个过程并最后进行了仿真计算。仿真结果显示，惯性导航系统和双星导航系统的组合弥补了各自的不足，具有较好的精度和可靠性。  相似文献   

燕山水库坝基防渗墙优化设计   总被引：1，自引：0，他引：1  

张宜虎  尹红梅  杨裕云  王亮清 《岩土力学》2005,26(7):1161-1164

因现场资料不足或分析手段落后等原因,当前进行水库坝基防渗墙设计,往往存在过于保守的倾向。以河南省燕山水库为例,基于优化设计的思路,采用目前较为成熟的二维有限单元法,对不同防渗条件下的坝基渗流场分别进行了模拟,并将计算所得比降、流量与允许比降、允许流量做了对比,从定量的角度提出了既安全、又经济的防渗方案:防渗墙厚度取0.8m,深度取打入破碎带5m。  相似文献