酸性矿山废水中生物成因次生高铁矿物的形成及环境工程意义   总被引：10，自引：1，他引：9  

周立祥 《地学前缘》2008,15(6)

酸性矿山废水(acid mine drainage,AMD)是一类pH低并含有大量有毒金属元素的废水。AMD及受其影响的环境中次生高铁矿物类型主要包括羟基硫酸高铁矿物(如黄铁矾和施威特曼石等)和一些含水氧化铁矿物(如针铁矿和水铁矿等),而且这些矿物在不同条件下会发生相转变,如施氏矿物向针铁矿或黄铁矾矿物相转化。基于酸性环境中生物成因次生矿物的形成会"自然钝化"或"清除"废水中铁和有毒金属这一现象所获得的启示,提出利用这些矿物作为环境吸附材料去除地下水中砷,不但吸附量大(如施氏矿物对As的吸附可高达120mg/g),而且可直接吸附As(III),还几乎不受地下水中其他元素影响。利用AMD环境中羟基硫酸高铁矿物形成的原理,可将其应用于AMD石灰中和主动处理系统中,构成"强化微生物氧化诱导成矿-石灰中和"的联合主动处理系统,以提高AMD处理效果和降低石灰用量。利用微生物强化氧化与次生矿物晶体不断生长的原理构筑生物渗透性反应墙(PRB)并和石灰石渗透沟渠耦联,形成新型的AMD联合被动处理系统,这将有助于大幅度增加处理系统的寿命和处理效率。此外,文中还探讨了上述生物成因矿物形成在AMD和地下水处理方面应用的优点以及今后需要继续研究的问题。  相似文献   

高位瓦斯抽放钻孔在降低综采工作面瓦斯浓度中的应用     

王永军  刘文兰 《中国煤炭地质》2008,(9):74-75

林南仓属于低瓦斯矿井,但存在高瓦斯区域。煤层和采空区是瓦斯的主要来源,尤以采空涌出量大,给煤矿生产和安全带来了极大隐患。通过在1129综采工作面风道施工高位瓦斯孔,把钻孔打到采空区一侧煤层顶板以上冒落裂隙带内,用钻孔进行瓦斯抽放,使采空内的瓦斯通过裂隙带沿钻孔抽出,有效降低综采工作面瓦斯浓度,保证综采工作面正常回采和安全生产。  相似文献   

基坑潜水疏干的简化计算在昊华水泥厂中的应用     

李务伦 《中国煤炭地质》2008,(9):28-31

以流线、流面、汇点的概念为基础,对稳定流双井干扰和直线隔水边界附近涌水量理论公式进行对比分析,提出了二个虚拟界面,其中虚拟界面Ⅰ,运用流线、流面的性质,流线方程等给出证明;虚拟界面Ⅱ则通过半无限条形降落漏斗的分析,应用元流和总流的能量方程得到流量为零,流线为零的平面。在同样条件下,条形无限涌水量是半无限潜含水层涌水量的二倍。应用总流能量方程对三种情况水头损失的分析,解释了这种关系存在的合理性,得出虚拟界面Ⅱ,并以此得出该界面内的最大残余水头计算公式。将基坑降水运用虚拟界面简化为扇形,条形半无限含水层,从而实现单井预测,该方法应用到昊华水泥厂基坑降水中,预测效果理想。  相似文献   

The Taconite Inlet Lakes Project: a systems approach to paleoclimatic reconstruction     

R. S. Bradley  M. J. Retelle  S. D. Ludlam  D. R. Hardy  B. Zolitschka  S. F. Lamoureux  M. S. V. Douglas 《Journal of Paleolimnology》1996,16(2):97-110

A comprehensive study of meteorological, hydrological, limnological and sedimentological conditions in the watersheds of density-stratified (meromictic) lakes around Taconite Inlet, Northern Ellesmere Island, N.W.T., Canada was carried out from 1990–1992. Lakes C1 and C2 contain seawater trapped by isostatic uplift as the former embayments became isolated from the sea. These lakes, and Lake C3, contain varved sediments which provide an annually resolvable paleoclimatic record. By studing the major systems influencing sedimentation in one of these lakes (Lake C2) a better understanding of the climatic controls on varve formation, and hence on the paleoclimatic signal in the varved sediment record, was obtained. The varves of Lake C2 provide a proxy record of summer temperature for the region.This is the first in a series of papers published in this issue on the Taconite Inlet Lakes Project. These papers were collected by Dr R. S. Bradley.  相似文献   

Attenuation of aqueous metal transport at two natural acid rock drainage occurrences in the Yukon Territory, Canada     

Y.T. John Kwong 《中国地球化学学报》2006,25(B08):229-230

Naturally acidic drainage associated with pyritic black shale has been observed in many locations in the Yukon Territory. While not necessarily linked to known mineral deposits, most of these natural acid rock drainage occurrences show elevated dissolved concentrations of trace elements, especially zinc, nickel, copper, cadmium and arsenic. Based on field observations, microbial investigation, chemical analyses and geochemical modeling, the fate and transport of potentially deleterious elements at two natural acid drainage occurrences with slightly different settings are examined. The Macintosh Creek is a small, acidic stream （pH 2.98-3.40）, 2 km long, located in the Macmillan Pass area of east-central Yukon amidst known sedimentary exhalative massive sulfide mineralization but remains undisturbed by exploration activities. Its trace metal content is apparently derived from groundwater discharges, which gave as much as 5.0, 2.5, 0.7, 0.13 and 0.03 mg/L ofZn, Ni, Cu and As, respectively. Interaction and sorption reactions with algal mats, biofilms and iron oxyhydroxides appear to be the dominant mechanisms attenuating aqueous contaminant transport along the stream. Cryogenic precipitation further consolidates the ferricrete formation and reduces the mobility of the sorbed metals. The tributaries of the Engineering Creek along the Dempster Highway in northern Yukon drain through a series of dolomite, phyllite, argillite, limestone, black shale, sandstone and conglomerate with no known concentration of mineralization. In this area, the water chemistry fully reflects the local geology with acidic streams invariably associated with black shale occurrences. Groundwater seeps in the headwaters area of the km-180 Creek completely enclosed in black shale gave pH 3.0 and as much as 148, 39, 2.9 and 9.1 mg/L of Zn, Ni, Cu and As, respectively. Sorption with iron oxyhydroxide and organic matter appear to dominate the attenuation of contaminant transport along the stream. However, once entered into carbonate-dominated terrains, secondary carbonate minerals exercise additional geochemical control on the local water chemistry as a result of neutralization.  相似文献   

Naturally acidic and metalliferous waters at unmined volcanogenic massive sulfide deposits in the Bonnifield mining district, Alaska Range, east-central Alaska     

Robert G. Eppinger Paul H. Briggs Cynthia Dusel-Bacon Stuart A. Giles Larry P. Gough Jane M.Hammarstrom Bernard E. Hubbard 《中国地球化学学报》2006,25(B08):232-232

The Bonnifield district hosts 26 tmmined volcanogenic massive sulfide （VMS） occurrences. Environmental geochemical samples of water and stream sediment were collected at several occurrences, concentrating on the two best-exposed and largest deposits, Red Mountain （RM） and Sheep Creek （SC）. Limited samples were also collected at the poorly exposed WTF deposit. The deposits are Late Devonian to Early Mississippian, and are hosted by felsic metavolcanic and carbonaceous schist members of the Totatlanika Schist or Keevy Peak Fm. Spring and stream waters at RM and SC have pH values commonly 〈3.5 （as low as 2.4 at RM and 2.5 at SC）, high conductivity （up to 11000 μS/cm）, and very high （Is to 100s mg/L） dissolved contents of Al, Cd, Co, Cu, Fe, Ni, and Pb. Waters at RM are characterized by extremely high REE contents （summed REE median 3200 μg/L, n=33）. At both RM and SC, pyrite oxidation and dissolution produce low pH waters that interact with and dissolve bedrock minerals, resulting in acidic, metal-laden, naturally degraded streams that are mostly devoid of aquatic life. Ferricrete is common. In contrast, WTF barely produces a surficial environmental footprint, mostly due to topography and relief. RM and SC are well exposed in the areas of relatively high relief, and both exhibit extensive areas of quartz-sericite-pyrite-alteration. While WTF shares many of the same deposit-and alteration characteristics, it is concealed by tundra in a large, nearly flat area. Surface water at WTF is absent and outcrops are sparse. Even though WTF is roughly the same size as Red Mountain （both around 3 million tonnes） and has similar base- and precious-metal grades, the surficial geochemical manifestation of WTF is minimal. However, exposure through mining of the altered, mineralized rock at WTF potentially could initiate the same processes of pyrite oxidation, acid generation, and mineral dissolution that are observed naturally at RM and SC.  相似文献   

Drainage spacing regularity on a fault-block: A case study from the eastern Ruahine Range     

Heather Purdie  Martin Brook 《New Zealand geographer》2006,62(2):97-104

Abstract:  Recent research has indicated river basin outlets draining linear sections of large, uplifting mountain belts often show a regularity of spacing, transverse to the main structural trend. A morphometric analysis of part of the Ruahine Range, on the North Island was undertaken to test whether drainage regularity may exist in smaller, younger mountain ranges. The ratio, R , of the half-width of the mountain belt, W , and the outlet spacing, S , was used to characterize drainage networks on the eastern side of the range. The spacing ratio for the range of 1.31 is lower than R results from studies of larger mountain belts ( R  = 1.91–2.23). We suggest the cause of this lower ratio is related to eastward migration of the Ruahine drainage divide.  相似文献   

The Removal of Dissolved Metals by Hydroxysulphate Precipitates during Oxidation and Neutralization of Acid Mine Waters, Iberian Pyrite Belt   总被引：4，自引：0，他引：4  

J. Sánchez España  E. López Pamo  E. Santofimia Pastor  J. Reyes Andrés  J. A. Martín Rubí 《Aquatic Geochemistry》2006,12(3):269-298

This study examines the removal of dissolved metals during the oxidation and neutralization of five acid mine drainage (AMD) waters from La Zarza, Lomero, Esperanza, Corta Atalaya and Poderosa mines (Iberian Pyrite Belt, Huelva, Spain). These waters were selected to cover the spectrum of pH (2.2–3.5) and chemical composition (e.g., 319–2,103 mg/L Fe; 2.85–33.3 g/L SO₄⁼) of the IPB mine waters. The experiments were conducted in the laboratory to simulate the geochemical evolution previously recognized in the field. This evolution includes two stages: (1) oxidation of dissolved Fe(II) followed by hydrolysis and precipitation of Fe(III), and (2) progressive pH increase during mixing with fresh waters. Fe(III) precipitates at pH < 3.5 (stages 1 and 2) in the form of schwertmannite, whereas Al precipitates during stage 2 at pH 5.0 in the form of several hydroxysulphates of variable composition (hydrobasaluminite, basaluminite, aluminite). During these stages, trace elements are totally or partially sorbed and/or coprecipitated at different rates depending basically on pH, as well as on the activity of the SO₄⁼ anion (which determines the speciation of metals). The general trend for the metals which are chiefly present as aqueous free cations (Pb²⁺, Zn²⁺, Cu²⁺, Cd²⁺, Mn²⁺, Co²⁺, Ni²⁺) is a progressive sorption at increasing pH. On the other hand, As and V (mainly present as anionic species) are completely scavenged during the oxidation stage at pH < 3.5. In waters with high activities (> 10⁻¹) of the SO ₄⁼ ion, some elements like Al, Zn, Cd, Pb and U can also form anionic bisulphate complexes and be significantly sorbed at pH < 5. The removal rates at pH 7.0 range from around 100% for As, V, Cu and U, and 60–80% for Pb, to less than 20% for Zn, Co, Ni and Mn. These processes of metal removal represent a significant mechanism of natural attenuation in the IPB.  相似文献   

PDC钻头在寺河煤矿瓦斯预抽放钻井中的应用   总被引：2，自引：1，他引：2  

吴小建  李新民 《中国煤田地质》2006,18(1):64-65,68

在寺河矿区一期瓦斯地面预抽放钻井施工中，使用传统的镶齿三牙轮钻头钻进，钻进速度低，仅为2.0m／h，且井斜不易控制、钻头寿命短、成本较高。通过对寺河煤矿地层特征的分析，在二期工程施工中，9#煤以上地层优选六翼内凹式PDC钻头钻进，采取一定技术措施并合理调整钻压、转速及泵量等钻进参数，钻速可达7．0m/h，井斜也得到有效控制，降低了钻井成本。  相似文献   

Monitoring of Over Cutting Area and Lubrication Distribution in a Large Slurry Pipe Jacking Operation   总被引：1，自引：0，他引：1  

Saeid Khazaei  Hideki Shimada  Takashi Kawai  Junichi Yotsumoto  Kikuo Matsui 《Geotechnical and Geological Engineering》2006,24(3):735-755

Slurry pipe jacking was firmly established as a special method for the non-disruptive construction of the underground pipelines of sewage systems. Pipe jacking, in its traditional form, has occasionally been used for short railways, roads, rivers, and other projects. Basically the system involves the pushing or thrusting of concrete pipes into the ground by a number of jacks. In slurry pipe jacking, during the pushing process, mud slurry and lubricant are injected into the face and the over cutting area that is between the concrete pipes and the surrounding soil. Next, the slurry fills voids and the soil stabilizes due to the created slurry cake around the pipes. Fillings also reduce the jacking force or thrust during operation. When the drivage and pushing processes are finished, a mortar injection into the over cutting area is carried out in order to maintain permanent stability of the surrounding soil and the over cutting area. Successful lubrication around the pipes is extremely important in a large diameter slurry pipe jacking operation. Control of lubrication and gaps between pipes and soil can prevent hazards such as surface settlement and increases in thrust. Also, to find voids around the pipes after the jacking process, in order to inject mortar for permanent stabilizing, an investigation around the pipes is necessary. To meet these aims, this paper is concerned with the utilization of known methods such as the GPR (Ground Penetrating Radar) system and borehole camera to maintain control of the over cutting area and lubricant distribution around the pipes during a site investigation. From this point of view, experiments were carried out during a tunnel construction using one of the largest cases of slurry pipe jacking in Fujisawa city, Japan. The advantages and disadvantages of each system were clarified during the tests.  相似文献