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111.
Bo PENG Shurong XIE Meilian XIAO Zhi SONG 《中国地球化学学报》2006,25(B08):85-86
The black shale formed under anoxic conditions usually contains high concentrations of many metals. Weathering of such black shale might cause the emission of many metals. Moreover, soils derived from black shale (SBS) are believed to be affected by black shale weathering. In recent years, many studies such as Lee et al. (2002), Woo et al. (2002), Fang et al. (2002), Pasava et al. (2003), and Peng et al. (2004) have approached the heavy metal contaminations of SBS, but systematical geochemical study is rare. Presently, the SBS and its corresponding black shales (CBS) were both sampled from central Hunan (China), and analyzed for a large number of elements, using an Elan6000 ICP-MS/AES machine at Guangzhou Institute of Geochemistry, CAS. In this paper, some preliminary results are reported. The analytical results show that the SBS in central Hunan contains very high concentrations of heavy metals such as Co, Cu, Hg, Mo, Pb, Zn, U, Th, Sb, T1, Cd, Cr, Sc, V, Sn, As, Se, and Ni. 相似文献
112.
YousifK. Kharaka Evangelos G. Kakouros James J. Thordsen David L. Naftz 《中国地球化学学报》2006,25(B08):100-101
Selenium (Se) is an essential micronutrient to biota, but can become a potent toxicant at elevated concentrations. The natural sources and chemical properties of Se species make the boundary between deficiency and toxicity narrow for some biota, with both phenomena common around the globe. Large areas of farmland in the Colorado River Basin (CRB) generate salinized drainage water with Se concentrations much higher than 5 μg/L, the U.S. Environmental Protection Agency chronic water-quality criterion for the protection of aquatic life. We have carried out detailed field and laboratory studies to investigate Se geochemistry and remediation in two of these areas: the Middle Green River Basin, Utah and the Salton Sea Basin, California, located respectively in the Upper and Lower CRB. Results from these and other studies show that approximately 90% of the dissolved Se in the Colorado River and its tributaries originally is derived from the Upper Cretaceous Mancos Shale and equivalent pyritic marine units that outcrop in the Upper CRB. Selenium is mobilized commonly by biogeochemical oxidation of this pyritic shale and is concentrated mainly as selenate (SeO4^2-) in soils and agricultural drainage water of dry climates by evaporation. Minor (0%-5%) amounts of Se are present as the selenite species (HSeO3^-) and (SEO3^2-), but these species and the more reduced species, elemental Se (SeO) and selenide (Se^2-), have much lower solubility and/or have high sorptive affinity towards organic matter, clay minerals and iron oxyhydroxides. The concentration of dissolved Se (-2.5 μg/L) and salinity in the Lower Colorado River water are among the highest of the world major rivers. Because of low precipitation (7 cm/a) and extreme evapotranspiration (-1.8 m/a) rates in the Salton Sea Basin, California, Se values in irrigation water imported from the Colorado River increase to 〉300 μg/L in drainage wastewater. Removal of Se from contaminated wastewater by nanofiltration membranes was demonstrated in laboratory and pilot-scale field experiments. 相似文献
113.
《中国地球化学学报》2006,25(B08):108-109
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116.
Jin-Soo Lee Kyung-Seok Ko Tong-Kwon Kim Jae Gon Kim Seong-Hyun Cho In-Suk Oh 《中国地球化学学报》2006,25(B08):152-152
The regional survey of groundwater used as a small water supply system was performed to know the effect of geology, soil properties and land use on groundwater quality at Nonsan City, Korea. A total of 126 groundwater samples were collected and analyzed at the study area. The multivariate statistical methods, principal components analysis and discriminant analysis, and GIS technique were used for the quantitative interpretation of groundwater quality. The study area is mainly composed of Precambrian gneiss, Jurassic granite, and Cretaceous volcanics, and metasedimentary rocks of the Ogcheon zone. The land use was grouped as paddy, upland, grassland, resident, point source, industrial area, and water system. The soil properties were classified as 4 major groups, Entisols, Alfisols, Inceptisols, and Ultisols, by the degree of development, and reclassified as 11 subgroups. The modified and simplified geologic map, soil map, and land use map were made by using ARCGIS soft-ware. The area of geology, soil property, and land use affecting the groundwater quality for each well were also calculated by ARCGIS soft-ware to acquire the quantitative parameters for multivariate statistical analysis. The monitoring results of groundwater in the study area showed that 13%-21% of the groundwater samples exceeded the portable water guideline and the main causes were turbidity, bacteria, arsenic and nitrate-N. The spatial distribution of each component showed the close relationship between groundwater quality and geology reflecting the topography, land use. 相似文献
117.
长白山北坡垂直植被带表土植硅体组合研究 总被引:3,自引:0,他引:3
长白山垂直分布的植被是欧亚大陆从温带到寒带植被水平地带性的缩影。对其北坡不同海拔高度植被带土壤中的植硅体进行初次研究,结果发现,该山北坡海拔700m到2630m的土壤中发育了形态和数量丰富的植硅体。不同植被带植硅体组合的含量各不相同,主要特征表现为随海拔升高示冷型的植硅体含量整体呈上升趋势,而示暖型的植硅体含量整体呈下降趋势。温泉附近土壤中的植硅体则表现出明显的与其上下相邻地点不同的特点。它对中国东北第四纪沉积物中植硅体组合的研究及第四纪古植被和古环境的重建可提供重要的基础性资料。 相似文献
118.
重庆金佛山表层岩溶生态系统土壤的CO2释放规律 总被引:2,自引:2,他引:2
采用碱溶液吸收法通过对重庆金佛山林地、裸地表层岩溶生态系统土壤CO2释放量进行野外监测,研究了影响土壤CO2释放量变化的主要因素,揭示土壤CO2释放变化规律。土壤CO2释放量的变化主要随着温度而变化,即气温降低,土壤CO2释放量减少,在昼夜时段,土壤CO2也随温度而变化,但相比温度变化有明显滞后性;降雨对土壤CO2释放有比较复杂的影响,但非简单的线性相关;同时植被也会影响到土壤CO2的释放,总体上,相比裸地而言,林地的土壤CO2的释放量大,但在不同时间段内土壤CO2释放强度与气温的关系有较大差异。一天时间段内林地土壤CO2释放强度与温度的关系较裸地灵敏,这是因为林地本身生物量大,对温度反应敏感,温度很小的变化就能引发土壤CO2释放量的大幅度地改变。而在以月为单位观测时间段时,裸地土壤CO2释放强度与气温的关系较林地灵敏,这可能是因为植被覆盖减缓气温对土温的影响,对土温有较强的调节作用。这种不同植被系统下,在不同时段土壤的CO2释放量动态差异在讨论岩溶作用与碳循环时应充分注意。 相似文献
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120.
大兴安岭火烧迹地土壤动物生态地理分析 总被引:20,自引:2,他引:20
不同恢复年份森林火烧迹地的土壤动物群落特征明显不同。火烧过后的前13年,大型土壤动物的种类和数量很少,特别是常见类群中的线蚓所占的比例很小,但运动能力较强的蜈蚣、蜘蛛等所占比例较高。火烧35年后,土壤中线蚓数量才逐渐增多并趋于稳定。中小型土壤动物中的原尾虫只出现在16年迹地和对比样地中,表明原尾虫确是稳定生境的指示动物。火烧过后,土壤环境中最先侵入的是运动能力较强的大型土壤动物,之后中小型土壤动物才逐渐得到恢复。火烧后67年是中小型土壤动物发展的盛期,随后土壤动物种类和数量开始减少并趋于稳定。火烧的强度对土壤动物群落的恢复有一定的影响,轻度火烧影响地区的土壤动物恢复较快,经过67年,土壤动物种类和数量能超过未受火烧影响的地区;而中、重度火烧地区,土壤动物恢复到正常水平则需要超过16年的更长的时间。 相似文献