New Developments in Water Efficiency     

Tony T. Gregg Amanda Dewees Drema Gross Bill Hoffman Dan Strub Matt Watson 《中国海洋大学学报(英文版)》2006,5(4):375-380

1Water LossInitiativesUnaccounted-for water(or unbilled water)has beenreceiving newscrutiny at both the state and nationallevels.For years,water conservationeffortsin Europehave emphasized reduction in water loss to a muchgreater extent thaninthe United S…  相似文献   

The solubility of iron sulphides in synthetic and natural waters at ambient temperature   总被引：1，自引：1，他引：0  

W. Davison 《Aquatic Sciences - Research Across Boundaries》1991,53(4):309-329

A critical evaluation of literature values for the solubility products, K _sp ^NBS = [Fe²⁺][HS^–] Fe²⁺ HS^– (H _NBS ⁺ )^–1, of various iron sulphide phases results in consensus values for the pKs of 2.95 ± 0.1 for amorphous ferrous sulphide, 3.6 ± 0.2 for mackinawite, 4.4 ± 0.1 for greigite, 5.1 ± 0.1 for pyrrhotite, 5.25 ± 0.2 for troilite and 16.4 ± 1.2 for pyrite.Where the analogous ion activity products have been measured in anoxic freshwaters in which there is evidence for the presence of solid phase FeS, the values lie within the range of 2.6–3.22, indicating that amorphous iron sulphide is the controlling phase. The single value for a groundwater of 2.65 (2.98 considering carbonate complexation) agrees. In seawater four values range between 3.85 to 4.2, indicating that mackinawite or greigite may be the controlling phase. The single low value of 2.94 is in a situation where particularly high fluxes of Fe (II) and S (–II) may result in the preferential precipitation of amorphous iron sulphide. Formation of framboidal pyrite in these sulphidic environments may occur in micro-niches and does not appear to influence bulk concentrations. Calculations show that the formation of Fe₂S₂ species probably accounts for very little of the iron or sulphide in most natural waters. Previously reported stability constants for the formation of Fe (HS)₂ and (Fe (HS)₃)^– are shown to be suspect, and these species are also thought to be negligible in natural waters. In completely anoxic pore waters polysulphides also have a negligible effect on speciation, but in tidal sediments they may reach appreciable concentrations and lead to the direct formation of pyrite. Concentrations of iron and sulphide in pore waters can be controlled by the more soluble iron sulphide phase. The change in the IAP with depth within the sediment may reflect ageing of the solid phase or a greater flux of Fe (II) and S (–II) nearer the sediment surface. This possible kinetic influence on the value of IAPs has implications for their use in geochemical studies involving phase formation.  相似文献   

柿竹园矿床大理岩型锡矿石工艺矿物学研究   总被引：1，自引：0，他引：1  

谭延松 《湖南地质》1991,10(3):223-228

大理岩型锡矿石产于燕山早、中期千里山花岗岩与中、上泥盆统灰岩的外接触带。矿石呈细脉、网脉浸染状,锡矿物有:锡石、黄锡矿,富钛尼日利亚石、尼日利亚石和木锡矿,脉石矿物绿帘石、石榴石、电气石、萤石、方解石及磁黄铁矿等亦含锡,锡主要呈锡的浊立矿物存在,占总锡量的89.78％,其中锡石锡占总锡量的80.01％,其次有呈类质同象形式存在的锡,在绿帘石、石榴石、电气石等矿物中以Sn~(4+)取代Fe~(3+),这类锡占总量的8.33％。工艺矿物学研究表明,该类锡矿石以“贫”、“细”、“杂”为特征。锡不仅十分分散,而且品位偏低,矿石矿物组合及镶嵌关系复杂、相互包裹,紧密连生;锡矿物粒度微细,粒径一般为0.2～0.01mm,部分为<0.0l～0.002mm,是一种难选的锡矿石类型。通过锡的回收试验,采用选冶联合工艺流程,预测锡的最佳回收率可达50％以上。  相似文献   

Simultaneous transport of water and solutes under transient unsaturated flow conditions — A case study     

B. K. Purandara  N. Varadarajan  B. Venkatesh 《Journal of Earth System Science》2008,117(4):477-487

The imbalance between incoming and outgoing salt causes salinization of soils and sub-soils that result in increasing the salinity of stream-flows and agriculture land. This salinization is a serious environmental hazard particularly in semi-arid and arid lands. In order to estimate the magnitude of the hazard posed by salinity, it is important to understand and identify the processes that control salt movement from the soil surface through the root zone to the ground water and stream flows. In the present study, Malaprabha sub-basin (up to dam site) has been selected which has two distinct climatic zones, sub-humid (upstream of Khanapur) and semi-arid region (downstream of Khanapur). In the upstream, both surface and ground waters are used for irrigation, whereas in the downstream mostly groundwater is used. Both soils and ground waters are more saline in downstream parts of the study area. In this study we characterized the soil salinity and groundwater quality in both areas. An attempt is also made to model the distribution of potassium concentration in the soil profile in response to varying irrigation conditions using the SWIM (Soil-Water Infiltration and Movement) model. Fair agreement was obtained between predicted and measured results indicating the applicability of the model.  相似文献   

云南官房铜矿床矿石矿物特征及银的赋存状态   总被引：1，自引：0，他引：1  

刘德利  刘继顺  张彩华  韩海涛  周余国 《矿床地质》2008,27(6):695-704

通过显微镜鉴定、电子探针(EPMA)及扫描电镜能谱分析(SEM/EDS)等方法,首次对官房铜矿的矿物组合和银的赋存状态进行了研究。初步查明,矿石矿物为中-低温热液成因,并受火山机构及断裂构造的控制;银矿物主要为碲银矿和辉银矿。矿石中银与铜呈明显正相关关系,而方铅矿中不含银。银主要以类质同象的形式赋存于含铜矿物或黄铁矿中;银的独立矿物含量低,且多呈包裹体的形式存在于黄铜矿、斑铜矿及黄铁矿中,或以微细粒状赋存于矿物颗粒间和斑铜矿的表面。  相似文献   

Response of groundwater chemistry to water deliveries in the lower reaches of Tarim River,Northwest China   总被引：2，自引：0，他引：2  

Yongjin Chen  Kefa Zhou  Yaning Chen  Weihong Li  Jiazhen Liu  Tao Wang 《Environmental Geology》2008,53(6):1365-1373

In this paper, we analysed the monitored data from nine groundwater-monitoring transects in the lower reaches of Tarim River during the five times of stream water deliveries to the river transect where the stream flow ceased. The results showed that the groundwater depth in the lower reaches of Tarim River rose from −9.30 m before the conveyances to −8.17 and −6.50 m after the first and second conveyances, −5.81 and −6.00 m after the third and fourth the conveyance, and −4.73 m after the fifth. The horizontal extent of groundwater recharge was gradually enlarged along both sides of the channel of conveyance, i.e., from 250 m in width after the first conveyance to 1,050 m away from the channel after the fourth delivery. With the rising groundwater level, the concentrations of major anions Cl⁻, SO₄²⁻ and cations Ca²⁺, Mg²⁺, Na⁺, as well as total dissolved solids (TDS) in groundwater underwent a significant change. The spatial variations in groundwater chemistry indicated that the groundwater chemistry at the transect near Daxihaizi Reservoir changed earlier than that farther from it. In the same transect, the chemical variations were earlier in the monitoring well close to watercourse than that farther away from the stream. In general, the concentration of the major ions and TDS at each monitoring well increased remarkably when the water delivery started, and decreased with the continued water delivery, and then increased once again at the end of the study period. Hence, the whole study period may be divided into three stages: the initial stage, the intermediate stage and the later stage. According to the three stages of groundwater chemistry reaction to water delivery and the relationships between groundwater chemical properties and groundwater depths, we educe that under the situation of water delivery, the optimum groundwater depth in the lower reaches of the Tarim River should be −5 m.  相似文献   

A modified DRASTIC model for Siting Confined Animal Feeding Operations in Williams County,Ohio, USA   总被引：1，自引：0，他引：1  

Enrique Gomezdelcampo  J. Ryan Dickerson 《Environmental Geology》2008,55(8):1821-1832

Three of DRASTIC’s parameters (Depth to Water, Soil Media, and Topography) were modified and another parameter was added (land use/land cover) to the model to determine the potential impact on groundwater from Confined Animal Feeding Operations (CAFO) manure lagoon settings and manure application as fertilizer. Williams County is a mostly agricultural county located in northwest Ohio, USA. It currently has three CAFOs, all dairy, with the possibility of the construction of a multi-million chicken egg CAFO in the near future. A Geographic Information System (GIS) was utilized to modify the Ohio Department of Natural Resources (ODNR) DRASTIC map for the county to fully assess the county-wide pollution potential of CAFOs. The CAFO DRASTIC map indicates that almost half of Williams County has elevated groundwater pollution potential. The rest of the county, primarily the southeast corner, has lower CAFO groundwater pollution potential. Future CAFO development within the county should focus on the southeastern portion of the county where the groundwater table is deeper, and the aquifer is composed of shale substrate with low hydraulic conductivity. The CAFO DRASTIC results are intended to be used as a screening tool and are not to replace site-specific hydrogeologic investigations.  相似文献   

Potential for localized groundwater contamination in a porous pavement parking lot setting in Rhode Island     

Thomas B. Boving  Mark H. Stolt  Janelle Augenstern  Brian Brosnan 《Environmental Geology》2008,55(3):571-582

The control of polluted surface runoff and the assessment of possible impacts on groundwater is a concern at the local and regional scale. On this background, a study investigates possible impacts of organic and inorganic pollutants (including bacteria) originating from a permeable asphalt parking lot on the water quality immediately beneath it. The functioning of the permeable pavement, including clogging and restricted vertical percolation, was also evaluated. Four nested sample ports (shallow and deep) were installed below low- and high-traffic areas, including one port outside the parking lot. At least initially there was a good hydraulic connection between the parking surface and the shallow sample ports. The presence of a geotextile layer at the base of the parking lot structure, however, was identified in lab tests as one factor restricting vertical percolation to the deeper ports. Clogging of the permeable surface was most pronounced in heavy traffic areas and below snow pile storage areas. Corroborated by high electric conductivity and chloride measurements, sand brought in by cars during winter was the principal cause for clogging. No bacteria or BOD were found in percolating water. Polycyclic aromatic hydrocarbons (PAH) were present at concentrations near minimum detection limit. Nutrients (nitrate and phosphate) were being leached into the ground via the permeable parking lot surface at annual flux rates of 0.45–0.84 g/m²/year. A multi-species tracer test demonstrated a retention capacity of the permeable parking lot structure of >90% for metals and 27% for nutrients, respectively.  相似文献   

Dissolved trace elements and heavy metals in the Danjiangkou Reservoir,China   总被引：9，自引：0，他引：9  

Siyue Li  Zhifang Xu  Xiaoli Cheng  Quanfa Zhang 《Environmental Geology》2008,55(5):977-983

Concentrations of trace elements and heavy metals (Al, As, Ba, Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Sb, Se, Sr, V and Zn) in the Danjiangkou Reservoir, the water source area of the Middle Route of China’s interbasin South to North Water Transfer Project, were analyzed using an Inductively Coupled Plasma Atomic Emission Spectrometer (ICP-AES) and compared with the national and international standards for drinking water. The results indicated that concentrations of As, Pb, Sb and Se in the Reservoir exceeded the standards and they would pose health risk for residents in the region and the water receiving areas of the interbasin water transfer project. Spatial and temporal variability of the trace elements and heavy metals in the Reservoir implies their mixed sources of natural processing and anthropogenic activities in the upper drainage of the Reservoir. The research results would help develop water resource management and conservation strategy for the interbasin water transfer project.  相似文献   

Low-pressure,water-assisted anatexis of basic dykes in a contact metamorphic aureole,Fuerteventura (Canary Islands): oxygen isotope evidence for a meteoric fluid origin     

M. I. Holloway  F. Bussy  T. W. Vennemann 《Contributions to Mineralogy and Petrology》2008,155(1):111-121

Migmatites produced by low-pressure anatexis of basic dykes are found in a contact metamorphic aureole around a pyroxenite–gabbro intrusion (PX2), on Fuerteventura. Dykes outside and inside the aureole record interaction with meteoric water, with low or negative δ¹⁸O whole-rock values (+0.2 to −3.4‰), decreasing towards the contact. Recrystallised plagioclase, diopside, biotite and oxides, from within the aureole, show a similar evolution with lowest δ¹⁸O values (−2.8, −4.2, −4.4 and −7.6‰, respectively) in the migmatite zone, close to the intrusion. Relict clinopyroxene phenocrysts preserved in all dykes, retain typically magmatic δ¹⁸O values up to the anatectic zone, where the values are lower and more heterogeneous. Low δ¹⁸O values, decreasing towards the intrusion, can be ascribed to the advection of meteoric water during magma emplacement, with increasing fluid/rock ratios (higher dyke intensities towards the intrusion acting as fluid-pathways) and higher temperatures promoting increasing exchange during recrystallisation. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献