Molecular modeling of the 10-Å phase at subduction zone conditions     

Jianwei Wang 《Earth and Planetary Science Letters》2004,222(2):517-527

Molecular dynamics (MD) modeling of the 10-Å phase, Mg₃Si₄O₁₀(OH)₂·xH₂O, with x=2/3, 1.0 and 2.0 shows complex structural changes with pressure, temperature and water content and provides new insight into the structures and stabilization of these phases under subduction zone conditions. The structure(s) of this phase and its role as a reservoir of water in the mantle have been controversial, and these calculations provide specific predictions that can be tested by in situ diffraction studies. At ambient conditions, the computed structures of talc (x=0) and the 10-Å phases with x=2/3 and 1.0 are stable over the 350-ps period of the MD simulations. Under these conditions, the 10-Å phases show phlogopite-like layer stacking in good agreement with previously published structures based on powder X-ray diffraction data for samples quenched from high-pressure and high-temperature experiments. The calculations show that the 10-Å phase with x=2.0 is unstable at ambient conditions. The computed structures at P=5.5 GPa and T=750 K, well within the known stability field of the 10-Å phase, change significantly with water content, reflecting changing H-bonding configurations. For x=2/3, the layer stacking is talc-like, and for x=1.0, it is phlogopite-like. The calculations show that transformation between these two stackings occurs readily, and that the talc-like stacking for the x=2/3 composition is unlikely to be quenchable to ambient conditions. For x=2.0, the layer stacking at P=5.5 GPa and T=750 K is different than any previously proposed structure for a 10-Å phase. In this structure, the neighboring basal oxygens of adjacent magnesium silicate layers are displaced by b/3 (about 3 Å) resulting in the Si atoms of one siloxane sheet being located above the center of the six-member ring across the interlayer. The water molecules are located 1.2 Å above the center of all six-member rings and accept H-bonds from the OH groups located below the rings. The b/3-displaced structure does not readily transform to either the talc-like or phlogopite-like structure, because neither of these stackings can accommodate two water molecules per formula unit. There is likely to be a compositional discontinuity and phase transition between the b/3-displaced phase and the phase with phlogopite-like stacking. The simulations reported here are the first to use the recently developed CLAYFF force field to calculate mineral structures at elevated pressures and temperatures.  相似文献   

The geomorphic dynamics and environmental history of an upper deltaic floodplain tract in the Sacramento–San Joaquin Delta,California, USA     

K. J. Brown  G. B. Pasternack 《地球表面变化过程与地形》2004,29(10):1235-1258

A multi‐proxy approach was used to examine the geomorphic dynamics and environmental history of an upper deltaic ?oodplain tract in the Sacramento–San Joaquin Delta, California. Three long cores were collected from the McCormack–Williamson Tract (MWT) and these cores were analyzed for bulk density, loss‐on‐ignition, ?ne (clay and silt) content, Al concentration, magnetic susceptibility, pollen, and charcoal. Radiocarbon dates obtained for the cores were converted into calendar years and an age–depth model was constructed. Long‐term vertical accretion and sedimentation rates were estimated from the age–depth model. Cross‐core relations show that coarse sediment generally accumulates more rapidly and has greater magnetic susceptibility compared to ?ne sediment. Percentage ?ne and LOI data show a strong linear relationship that indicates ?ooding is the primary mechanism for the deposition of particular organic matter on the ?oodplain and that landscape wash load has contributed a highly consistent fraction of persistent organic matter averaging 5·5 per cent to the site. Down‐core grain size pro?les show two hydrological domains in the cores, namely millennial ?ne–coarse ?uctuations superimposed on general up‐core ?ning. Coarse sediment is viewed as channel or near‐channel overbank deposits, whereas ?ne deposits are considered to be distal overbank ?ood deposits. The coarse–?ne ?uctuations are indicative of changing depositional settings as channels migrated laterally across MWT, whereas the upward ?ning trend re?ects a combination of self‐limiting overbank deposition as ?oodplain elevation increased and decreasing competence as sea‐level rise reduced ?ood‐pulse energy slopes. MWT has been cross‐cut and incised numerous times in the past, only to have the channels abandoned and subsequently ?lled by ?ne sediment. The channels around MWT attained their modern con?guration about 4000 years ago. MWT likely came under tidal in?uence at about 2500 cal BP. Wetlands have recently developed on MWT, but they are inorganic sediment dominated. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

安徽张八岭地区西冷岩组早期构造变形特征   总被引：3，自引：0，他引：3       下载免费PDF全文

鲁如魁高天山  张志树刘家云 吴海权 《中国地质》2004,31(2):131-138

安徽张八岭地区西冷岩组早期构造变形复杂，主要表现为褶皱以及与褶皱变形密切相关的韧性剪切变形。野外调查表明，该地层中至少发育3期褶皱变形，其中F1为北西向韧性剪切褶皱；F2为向南南西倾伏的纵弯褶皱；F3为近东西向的宽缓褶皱。F1与F：联合制约了西冷岩组岩层展布的总体格局。显微构造，特别是岩石的磁性组构特征证明了区内曾发生过多期构造变形，且有两期最为显著，即早期的水平剪切和随后发生的侧向挤压。本文重点阐述上述褶皱变形的几何学特征，并进行运动学和动力学分析。  相似文献   

On the effect of a low viscosity asthenosphere on the temporal change of the geoid—A challenge for future gravity missions     

Gabriele Marquart  Bernhard Steinberger  Karen Niehuus 《Journal of Geodynamics》2005,39(5):493

New satellite technology to measure changes in the Earth’s gravity field gives new possibilities to detect layers of low viscosity inside the Earth. We used density models for the Earth mantle based on slab history as well as on tomography and fitted the viscosity by comparison of predicted gravity to the new CHAMP gravity model. We first confirm that the fit to the observed geoid is insensitive to the presence of a low viscosity anomaly in the upper mantle as long as the layer is thin ( 200 km) and the viscosity reduction is less than two orders of magnitude. Then we investigated the temporal change in geoid by comparing two stages of slablet sinking based on subduction history or by advection of tomography derived densities and compared the spectra of the geoid change for cases with and without a low viscosity layer, but about equal fit to the observed geoid. The presence of a low viscosity layer causes relaxation at smaller wavelength and thus leads to a spectrum with relatively stronger power in higher modes and a peak around degrees 5 and 6. Comparing the spectra to the expected degree resolution for GRACE data for a 5 years mission duration shows a weak possibility to detect changes in the Earth’s gravity field due to large scale mantle circulation, provided that other causes of geoid changes can be taken into account with sufficient accuracy. A discrimination between the two viscosity cases, however, demands a new generation of gravity field observing satellites.  相似文献   

Hydrology, circulation and distribution of particulate matter in Thermaikos Gulf (NW Aegean Sea), during September 2001–October 2001 and February 2002     

V. Zervakis  A.P. Karageorgis  H. Kontoyiannis  V. Papadopoulos  V. Lykousis 《Continental Shelf Research》2005,25(19-20):2332

The hydrography, circulation and distribution of particulate matter in Thermaikos Gulf (NW Aegean Sea) are described, for September 2001 and October 2001 and February 2002. The observations were obtained to assess the impact of anthropogenic and natural resuspension processes on the coastal ecosystem. The first two periods represent highly stratified conditions and mild weather conditions; in September trawling is prohibited, whilst the October cruise took place following the commencement of the activity. The sampling in February was undertaken to record the contribution of natural resuspension to the system, in a stormy period.The water circulation was mainly baroclinic during autumn and barotropic in winter; this was due to vertical homogenisation of the water column, during the latter period. The distribution of the bottom nepheloid layer (BNL) was very different in the winter than in the autumn.Microstructure measurements were undertaken, which allowed the vertical eddy diffusivity to be estimated, together with the near-bed shear stresses. Computation of the diffusive flux of particulate matter (PM), from the BNL into the intermediate water column in response to turbulent motions, reveals that the PM flux was much higher in October than in September; this is despite the fact that the friction velocities were similar. This observation could explain partly the observed higher PM concentrations (PMC) in the intermediate layer, in October. Likewise suggest that the higher PMC in October could be attributed to trawling. The limited shear stress and friction velocity values obtained during the September and October cruises were always low; these were possibly capable of resuspending only recently deposited, “fluffy” material. Thus, the observed nepheloid layers are likely to be maintained by advection from the shallow water regions and trawled areas.  相似文献   

Intermittent chaos in nonlinear wave–wave interactions in space plasmas     

Rodrigo A. Miranda  Erico L. Rempel  Abraham C.-L. Chian  Felix A. Borotto 《Journal of Atmospheric and Solar》2005,67(17-18):1852

There is increasing observational evidence of nonlinear wave–wave interactions in space and astrophysical plasmas. We first review a number of theoretical models of nonlinear wave–wave interactions which our group has developed in the past years. We next describe a nonlinear three-mode truncated model of Alfvén waves, involving resonant interactions of one linearly unstable mode and two linearly damped modes. We construct a bifurcation diagram for this three-wave model and investigate the phenomenon of intermittent chaos. The theoretical results presented in this paper can improve our understanding of intermittent time series frequently observed in space and astrophysical plasmas.  相似文献   

On core surface flows inferred from satellite magnetic data     

Céline Eymin  Gauthier Hulot 《Physics of the Earth and Planetary Interiors》2005,152(3):200-220

Satellite-data allows the magnetic field produced by the dynamo within the Earth’s core to be imaged with much more accuracy than previously possible with only ground-based data. Changes in this magnetic field can in turn be used to make some inferences about the core surface flow responsible for them. In this paper, we investigate the improvement brought to core flow computation by new satellite-data based core magnetic field models. It is shown that the main limitation now encountered is no longer the (now high) accuracy of those models, but the “non-modelled secular variation” produced by interaction of the non-resolvable small scales of the core flow with the core field, and by interaction of the (partly) resolvable large scales of the core flow with the small scales of the core field unfortunately masked by the crustal field. We show how this non-modelled secular variation can be taken into account to recover the largest scales of the core flow in a consistent way. We also investigate the uncertainties this introduces in core flows computed with the help of the frozen-flux and tangentially geostrophic assumptions. It turns out that flows with much more medium and small scales than previously thought are needed to explain the satellite-data-based core magnetic field models. It also turns out that a significant fraction of this flow unfortunately happens to be non-recoverable (being either “non-resolvable” because too small-scale, or “invisible”, because in the kernel of the inverse method) even though it produces the detectable “non-modelled secular variation”. Applying this to the Magsat (1980) to Ørsted (2000) field changes leads us to conclude that a flow involving at least strong retrograde vortices below the Atlantic Hemisphere, some less-resolved prograde vortices below the Pacific Hemisphere, and some poorly resolved (and partly non-resolvable) polar vortices, is needed to explain the 1980-2000 satellite-era average secular variation. The characteristics of the fraction of the secular variation left unexplained by this flow are also discussed.  相似文献   

格尔木井水温异常特征及其与地震关系分析   总被引：1，自引：1，他引：1  

邱鹏程  刘学领  王永刚  白占孝  常振广 《地震地磁观测与研究》2005,(Z1)

简要介绍了格尔木井水温动态观测的环境与条件,在研究正常动态特征和影响因素的基础上,对水温异常的映震关系进行了分析,并成功地进行了一次短临地震趋势预测。探讨了水温异常的形成原因。  相似文献   

Dynamics of mule deer forage in the Sonoran Desert     

J.P. Marshal  P.R. Krausman  V.C. Bleich 《Journal of Arid Environments》2005,60(4):593-609

Forage availability for mule deer (Odocoileus hemionus) in the Sonoran Desert depends on plant biomass, which is influenced by rainfall. We determined how rainfall, temperature and plant characteristics affected biomass of deer forage. We measured forage biomass, rainfall and temperature every 3 months from April 2000 to December 2002. Quarterly rainfall ranged from <1 to 57 mm, and forage biomass in desert washes fluctuated between 6 and 34 g m⁻². There was a positive relationship between forage biomass and rainfall the previous six months (p<0.001), and a negative relationship between biomass and average temperature the previous 3 months (p<0.001). Quarterly forage growth was positively influenced by rainfall (p<0.001) and negatively influenced by forage biomass (p<0.001). The relationships between deer forage and environmental factors established here will be useful in understanding population ecology of mule deer as part of an interactive model of plant–herbivore dynamics in arid environments.  相似文献   

Shallow seismic trapping structure in the San Jacinto fault zone near Anza, California   总被引：3，自引：0，他引：3  

M. A. Lewis  Z. Peng †  Y. Ben-Zion  F. L. Vernon 《Geophysical Journal International》2005,162(3):867-881

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