Atomistic calculations of structural and elastic properties of serpentine minerals: the case of lizardite   总被引：1，自引：0，他引：1  

A.-L. Auzende  R. J.-M. Pellenq  B. Devouard  A. Baronnet  O. Grauby 《Physics and Chemistry of Minerals》2006,33(4):266-275

The physical properties of the hydrous phyllosilicate lizardite have been investigated by atomistic simulation using the GULP code based on transferable semi-empirical interatomic potentials. Lizardite behavior was first investigated during structure relaxation at room temperature. The Helmholtz free energy is minimum for an equilibrium structure that is in agreement with experiment. The bulk, shear, and Young modulii for lizardite were calculated along with the Poisson ratio. From the shear and bulk modulii, we also calculated translational and longitudinal acoustic wave velocities that are important quantities for tectonophysics models. As expected, lizardite is stiffer in the a direction parallel to the layers than in the c perpendicular direction; the variation of the unit cell parameters with pressure is in good agreement with experiment. The cohesive energy between two successive layers along c direction was calculated at 0.33 eV (i.e., 0.11 eV per OH bond) in good agreement with recent ab initio calculations. Upon pressure and temperature variations, we evidenced that structural changes are mainly pressure induced; pressure being accommodated by a decrease of the c parameter up to 10 GPa. We also found that the change of slope in the derivative of the c cell parameter with respect to pressure occurring around 2 GPa originates from the bending of the interlayer hydroxyl groups with respect to the layer normal direction.  相似文献   

Secular variations of the upper crust composition: Implication of geochemical data on the Upper Precambrian shales from the Southern Urals western flank and Uchur-Maya region     

A. V. Maslov  V. N. Podkovyrov  Yu. L. Ronkin  M. T. Krupenin  E. Z. Gareev  V. M. Gorozhanin 《Stratigraphy and Geological Correlation》2006,14(2):126-149

In the mid-1980s, it was concluded based on geochemical study that Th, Sc, La concentrations and ratios Th/Sc, La/Sc and Eu/Eu* did not wary significantly in the post-Archean time. It was impossible to judge about compositional variations of upper crust during the Riphean and Vendian, because data of that time characterized a limited number of samples from the post-Archean basins of Australia, New Zealand, and Antarctic. Considered in this work are variations of Eu/Eu*, LREE/HREE, Th/Sc, and La/Sc ratios in Upper Precambrian fine-grained siliciclastic rock of the Southern Urals western flank (Bashkirian meganticlinorium) and Uchur-Maya region (Uchur-Maya plate and Yudoma-Maya belt). As is established, only the Eu anomaly in the studied siliciclastic rocks is practically identical to this parameter of the average post-Archean shale. Three other parameters plot on the Riphean-Vendian variation curves with positive and negative excursions of diverse magnitude, which do not coincide always in time. It is assumed that these excursions likely mark stages of local geodynamic activity, destruction of pre-Riphean cratons, and progressing recycling of sedimentary material during the Riphean.  相似文献   

The political geography of religion: historical state-church relations in Europe and recent challenges     

Hans Knippenberg 《GeoJournal》2006,67(4):253-265

Historical processes of state formation and nation building are crucial for an understanding of the geography of religions and churches in Europe. Each country has developed its own model of state-church relations, giving rise to a ‘bewildering variety’ as Grace Davie aptly remarks. The aim of this paper is to bring some order to this variety by developing a framework for the comparative study of church-state relations based on Stein Rokkan’s famous conceptual map and recent extensions of it to Central and Eastern Europe by John Madeley. According to that framework Europe has been divided into three mono-confessional (Roman Catholic, Lutheran, and Eastern Orthodox) blocs and two multi-confessional culture belts from Northwest to Southeast, and from Northeast to Southeast. This historical pattern has been challenged by secularisation, which started with the Enlightenment and the French Revolution (Western Europe) and the Russian Revolution (Eastern Europe until the velvet revolutions of 1989/1991) and then became widespread after the ‘cultural revolutions’ of the 1960s. A second challenge has to do with globalisation and its consequences, such as massive immigration and the rise of immigrant religions, and in general deterritorialisation, which means the disembeddedness of religion from its national territory. A third challenge concerns reterritorialisation at other (supranational, regional, transnational, and local) scales, of which the new territorial order of the European Union seems to be the most important. Finally, this paper serves as an introduction to the case studies on church-state relations in this special issue.  相似文献   

Assessment of Marine Clay Improvement Under Reclamation Fills by in-situ Testing Methods     

A. Arulrajah  H. Nikraz  M. W. Bo 《Geotechnical and Geological Engineering》2006,24(2):219-226

In ground improvement projects with prefabricated vertical drains, the duration of the preloading period is set in advance based on the predetermined time rate of consolidation of the compressible layer. If prediction is accurately done, the required degree of consolidation is met at the pre-determined preloading time. As such, there is a requirement for in-situ tests to be carried out just prior to the removal of surcharge to assess the degree of consolidation of the improved ground. In-situ tests were carried out after 23 months of surcharge loading at the In-Situ Test Site within the Changi East Reclamation Project in the Republic of Singapore. In-situ testing works in this research study comprises the use of field vane shear, piezocone, flat dilatometer and self-boring pressuremeter. The in-situ tests were carried out to determine the shear strength and degree of consolidation of the Singapore marine clay at Changi after 23 months of surcharge loading. The In-Situ Test Site consisted of a Vertical Drain Area as well as an untreated Control Area. Both areas were located adjacent to each other and were surcharged simultaneously to the same level and surcharge left in place for a period of 23 months. Comparison was made between the in-situ test results of the Vertical Drain Area and the untreated Control Area.  相似文献   

Experimental and numerical studies of rock salt strain hardening     

M. Hamami 《Geotechnical and Geological Engineering》2006,24(5):1271-1292

The work presented in this paper comes as part of a research program dealing with the thermomechanical behaviour of rock salt. It aims to study laboratory and in-situ long-term behaviour by means of creep tests with deviator and temperature changes. The laboratory results, using a triaxial multi-stages creep tests, highlighted the strain hardening character of rock salt. Furthermore, the in-situ results, using a borehole dilatometer multi-step creep test, have shown that the drilling is carried out in a weakly stressed pillar. The interpretation of the laboratory results, using the J.LEMAITRE law, did not indicate full agreement with all the test results. As a result a ‘double’ J.LEMAITRE model, which takes into account a double strain hardening variable, has been put forward. The validation of this model on the laboratory creep tests is very satisfactory. Furthermore, the activation energy seems satisfactory to represent the influence of the temperature. The in-situ behaviour modelling is clearly more complex than the modelization based on laboratory tests. In fact, it seems that if the rock salt behaviour is maintained by J.LEMAITRE law, it is necessary to vary with the stress, at least, one of the parameters assumed constant in the basic law.  相似文献   

Break out resistance of inclined anchors in sand     

Shubhra Goel  Shalini  Nihar Ranjan Patra 《Geotechnical and Geological Engineering》2006,24(6):1511-1525

Inclined anchors are widely used in a variety of civil engineering problems to resist oblique loads, most relevant being in transmission towers and in rocks and dams for structural strengthening. In the present study, the breakout resistance of the inclined anchors in sand has been worked out using limit equilibrium approach. The breakout resistance has been calculated for different soil friction angles with varying relative depth ratio and anchor inclination. The break out factor increases continuously with the inclination of the anchor. A comparison of predicted values of break out resistance of anchors by the proposed analysis with the experimental values as reported by the other researchers showed reasonably good agreement.  相似文献   

The log-normal distribution for hydraulic conductivity of compacted clays: Two or three parameters?     

Huaming Zhai  Craig H. Benson 《Geotechnical and Geological Engineering》2006,24(5):1149-1162

Risk and uncertainty assessments for waste containment systems employing clay barriers often include spatial variability in the hydraulic conductivity as part of the analysis. The two-parameter log-normal distribution is often used to describe the spatial variability, but for compacted clays the three-parameter form can be more appropriate. A statistical hypothesis test was developed that can be used to determine if the two- or three-parameter form of the log-normal distribution is more appropriate. The test is based on a likelihood ratio, comparing likelihood functions for the two- and three-parameter forms at their maximums. Likelihood functions are used assuming that a data set can be segregated into a set of distinct groups of hydraulic conductivities. A step-by-step calculation procedure is described and the test is applied to data collected from 45 sites.  相似文献   

R＆D投入的区位模式与区域经济发展   总被引：2，自引：1，他引：2  

姜怀宇  李铁立 《地理科学》2006,26(1):13-19

基于对中国R＆D投入的区位模式的实证检验，从投入一产出绩效的角度认为集中投入的区位模式具有较强的适宜性。利用聚类分析技术，按照R＆D的投入强度和及其对经济的带动效应、科技化效应、产业化效应将中国各省区划分为6类地区，具有代表性的是科技化模式和产业化模式。其中前者适合于技术存置较高的少数地区，而后者具有较强的借鉴意义。  相似文献   

长江口水域多光谱遥感水深反演模型研究   总被引：3，自引：0，他引：3  

徐升  张鹰 《地理与地理信息科学》2006,22(3):48-52

利用Landsat-7 ETM 遥感影像反射率和实测水深值之间的相关性可以探测水深。该文介绍单波段、双波段比值和多波段3种线性回归模型以及动量BP人工神经网络水深反演模型。选择长江口北港河道上段作为研究区,利用上述模型,分两种情况进行水深反演:一是以河道全部历史样本建模;二是将河道按自然水深划分为浅水区和深水区分别建模。结果表明:神经网络模型预测精度高于线性回归模型;水深分区后线性回归和神经网络模型预测误差均有所减小。  相似文献   

Regional disparity in the changes of agricultura land use intensity in China during 1980-2002     

LIU Chengwu LI Xiubin 《地理学报(英文版)》2006,16(3):286-292

Based on the cost-benefit data （1980-2002） of farm products and China Agriculture Yearbooks, this paper studies the regional disparity in the changes of the agricultural land use in China during the period 1980-2002 from three aspects such as the degree of intensity, the sown area and the abandoned farmland. The results show that： （1） The degree of intensity of land use in the westena region during 1980-2000 has a strong uptrend, but in the eastern and central regions the degree of intensity descends obviously and has shown a continuous downtrend since 1997. （2） The total sown area shrinks notably in the eastern region, while it enlarges constantly in the western region. （3） The sown area in the eastern, central and western regions has gone through a similar cyclic process： down （1980-1985）-up （1985-1991）-down （1991-1994）-up （1994-1999）-down （1999-2002）. However, there are obvious differences in amplitude variation and tendency among them. The sown area has shrunk in the eastern region and expanded in the central and western regions especially before 1999. （4） The most cases of abandoned farmland are reported in the central region, the second in the eastern region and the least in the western region. The abandonment phenomena chiefly occurred during 1992-1995 in the eastern region, and during 1998-2002 in the central region.  相似文献