Trace Element Analysis of NIST SRM 614 and 616 Glass Reference Materials by Laser Ablation Microprobe-Inductively Coupled Plasma-Mass Spectrometry   总被引：3，自引：0，他引：3  

Masanori Kurosawa  Simon E. Jackson  Shigeho Sueno 《Geostandards and Geoanalytical Research》2002,26(1):75-84

Fifty elements in NIST SRM 614 and 616 glass reference materials were determined by laser ablation microprobe-inductively coupled plasma-mass spectrometry (LAM-ICP-MS). The values determined for NIST SRM 614 agreed well with the NIST-certified and information values (mean relative difference ± 3.6%), except for B, Sc and Sb. The values determined for NIST SRM 616 agreed with the NIST-certified and information values within a mean relative difference of ± 1.5%, except for B, Sc and Ga. In addition, at an 80 μm sampling scale, NIST SRM 614 and 616 glass discs were homogeneous for trace elements within the observed precisions of 5 and 15% (mean), respectively. Detection limits were in the range 0.01 - 0.3 μg g⁻¹ for elements of lower mass numbers (amu < 80) and 1 - 10 ng g⁻¹ for heavy elements (amu > 80). Detection at the sub ng g⁻¹ level is possible for most of the heavy elements by using an ablation pit size larger than 10 0 μm.  相似文献   

G-Probe-1 - An International Proficiency Test for Microprobe Laboratories - Report on Round 1 : February 2002 (TB-1 Basaltic Glass)     

Philip J. Potts  Michael Thompson  Stephen Wilson 《Geostandards and Geoanalytical Research》2002,26(2):197-235

Results are presented for round one of a new international proficiency testing programme designed for microprobe laboratories involved in the routine analysis of silicate minerals. The sample used for this round was TB-1, a basaltic glass fused and prepared by the USGS. Thirty nine laboratories contributed data to this round, the majority of major element results being undertaken by EPMA and the majority of trace elements by LA-ICP-MS. Assigned values were derived from the median of results produced by nine selected laboratories that analysed powdered material by conventional ICP-MS, INAA and XRF techniques using bulk powders of the sample. Submitted microprobe results were evaluated using a target precision calculated using the Horwitz function, adopting the same criteria as those used for "applied" geochemistry laboratories in the companion GeoPT proficiency testing programme for laboratories involved in the routine bulk analysis of silicate rocks. An evaluation of results from participating microprobe laboratories indicated that overall, data were compatible with this precision function. A comparison between the performance of bulk and microprobe techniques used in the analysis of the basaltic glass showed remarkably good agreement, with significant bias only observed for the major oxide MgO.  相似文献   

Hydration and refractive indices of Holocene tephra glass in Hokkaido, Northern Japan     

Yugo Nakamura  Yoshinori Katayama  Kazuomi Hirakawa 《Journal of Volcanology and Geothermal Research》2002,114(3-4)

Refractive indices of incompletely hydrated tephra glasses vary widely. Thus, glass refractive index is not a practical indicator for identifying Holocene tephras. Hydration near the surface of tephra glass shards can be removed by either hydrofluoric acid treatment or annealing for 12 h at 400°C. The annealing procedure is a particularly reliable and simple way to dehydrate tephra glasses. Standard deviations (s) of refractive indices for glasses after 12 h annealing are small (s=0.0014–0.0018), in contrast with untreated glasses (s=0.0034–0.0405). The refractive indices of dehydrated tephra glasses are 0.006–0.014 lower than those of the untreated (hydrated) glasses. Using the 400°C 12-h annealing procedure, values for the refractive indices of eight Holocene tephras in Hokkaido were obtained. These refractive indices are useful indicators for identification and correlation of Holocene tephras.  相似文献   

The experimental studies on electrical con-ductivities and P-wave velocities of anortho-site at high pressure and high temperature   总被引：1，自引：0，他引：1  

白利平  杜建国  刘巍  周文戈 《地震学报(英文版)》2002,15(6):667-676

Introduction The measurements of the compressional wave velocity and electrical conductivity of minerals and rocks are of fundamental importance to look into the earths interior, including composition, geotherm, generation and distribution of fluids and melts. Hydrous minerals formed by metamatu-siom are abundant within the earth. Previous studies have been carried out on the dehydration effect on the electrical conductivity and wave velocity of rocks such as serpentine, amphibole, most of whi…  相似文献   

A finite‐element algorithm for electromagnetic induction in two‐dimensional anisotropic conductivity structures     

Yuguo Li 《Geophysical Journal International》2002,148(3):389-401

  相似文献   

Determining the magnetic field in the core–mantle boundary zone by non-harmonic downward continuation     

L. Ballani  H. Greiner-Mai  D. Stromeyer 《Geophysical Journal International》2002,149(2):374-389

  相似文献   

Controlled source apparent resistivity tensors and their relationship to the magnetotelluric impedance tensor   总被引：2，自引：0，他引：2  

T. Grant Caldwell  Hugh M. Bibby  Colin Brown 《Geophysical Journal International》2002,151(3):755-770

  相似文献   

Partial melt or aqueous fluid in the mid-crust of Southern Tibet? Constraints from INDEPTH magnetotelluric data   总被引：13，自引：0，他引：13  

Shenghui Li  Martyn J. Unsworth  John R. Booker  Wenbo Wei  Handong Tan  Alan G. Jones 《Geophysical Journal International》2003,153(2):289-304

  相似文献   

Resolution, stability and efficiency of resistivity tomography estimated from a generalized inverse approach   总被引：2，自引：0，他引：2  

Sven Friedel 《Geophysical Journal International》2003,153(2):305-316

  相似文献   

A high-resolution magnetotelluric survey of the Iapetus Suture Zone in southwest Scotland   总被引：1，自引：0，他引：1  

Sebastian Tauber  Roger Banks  Oliver Ritter  Ute Weckmann 《Geophysical Journal International》2003,153(3):548-568

  相似文献