罕见的蓝色饵-纳透闪石研究     

廖尚宜  金萍 《矿物岩石地球化学通报》2001,20(3):190-193

尽管角闪石在地壳中大量存在 ,但是蓝色钾 钠透闪石却是角闪石中的稀有品种。本文采用X射粉晶线衍射和晶胞参数计算 ,确定该矿物为蓝色的钾 钠透闪石 ,用电子探针 (EMPA)精确分析了它的化学成分 ,确定为钾 钠透闪石 ,而不是蓝色软玉 (即不是透闪石或阳起石 )。  相似文献   

Parajamesonite revisited: background of the discreditation of an enigmatic mineral species     

Gábor Papp  Alan J. Criddle  Chris J. Stanley  László Kriston  Géza Nagy 《Swiss Journal of Geoscience》2007,100(3):495-502

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Exfoliation of kaolinite by urea-intercalation precursor and microwave irradiation assistance process     

Pi Zhenbang  Liu Zhuoqin  Yang Chao  Tian Xike  Fei Jinbo  Zheng Jianhua 《Frontiers of Earth Science》2007,1(1):26-29

A type of exfoliated kaolinite was produced by urea-intercalation and original microwave irradiation assisted method. The product was investigated by Fourier transformation infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), scanning electronic microscopy (SEM), Brunauer-Emmett-Teller (BET) and laser particle analysis techniques. FT-IR spectra show that NHCO molecule exists in the intercalated kaolinite. XRD analyses indicate that the kaolinite sheet-like structure was disordered after microwave irradiation. The urea decomposition process and explosion effect between the sheet-like structures of kaolinite under microwave irradiation were discussed. The SEM and BET analyses reveal that the end product is exfoliated kaolinite with thin particles and increased surface area. Size and zeta potential analyses show that the particle size distribution is between 250 nm and 550 nm with normal distribution and the particle is negatively charged. In comparison with the conventional grind method, the process adopted appears to be economic and the exfoliated kaolinite end product may display a significantly enhanced performance in industrial applications.  相似文献   

煤中显微裂隙的成因类型及其研究意义   总被引：8，自引：0，他引：8  

张慧  王晓刚  员争荣  郝琦 《岩石矿物学杂志》2002,21(3):278-284

分析、归纳了大量的扫描电子显微镜观测结果，以煤岩学、构造地质学研究为基础，依据煤中显微裂隙的形态，大小、排列组合等发育特征，将内生裂隙进一步划分为失水裂隙，缩聚裂隙、静压裂隙，将外生裂隙进一步划分为张性裂隙，压性裂隙，剪性裂隙，松弛裂隙，描述了各类隙的发育特征，探讨了裂隙的演化，识别和影响裂隙发育的因素，裂隙成因类型的研究，有助于判断不同裂隙对煤储层渗透率的贡献。  相似文献   

绿柱石通道中配合物的振动光谱和辐照裂解   总被引：2，自引：1，他引：2  

亓利剑  叶松  向长金  裴景成  石国华 《地质科技情报》2001,20(3):59-64

以四川平武富碱型绿柱石为研究对象 ,采用 IR和 L RM测试方法 ,重点对通道中氢化物和多聚合离子的配位构型、辐照裂解及热致转型进行了较深入系统的研究。研究表明 ,在该区成矿作用条件下 ,绿柱石通道中的钠离子趋向与氢离子化合反应生成 Na H氢化物 ,并占据通道中的 C2 位。在垂直 c轴方向上 ,以 3165 cm-1,3114 cm-1及 30 31cm-1伸缩振动弱吸收谱带为特征。[Fe2 ( OH) 4 ] 2 多聚合离子占据通道中的 C1位 ,以 32 34 cm-1伸缩振动锐吸收谱带为特征 (∥ c轴 )。辐照作用导致上述多聚合离子的裂解 ,并形成不稳定的 [H0 ] i心和相对稳定的 [Fe3 ] OH心。与之对应的吸收谱带分别出现在 3110 cm-1(⊥ c轴 )和 335 5cm-1(∥c轴 )处。通道中 Na H和 [Fe2 ( OH) 4 ] 2 多聚合离子的存在 ,可视为该类型绿柱石的一个重要的成因标志。  相似文献   

辐照绿柱石的色心与赋色机制   总被引：4，自引：1，他引：4  

亓利剑  叶松  向长金  裴景成  罗永安 《地质科技情报》2001,20(4):68-72

在不同辐照剂量的带电粒子作用下，四川无色绿柱石因赋色而呈现浅蓝色，蓝绿色，黄绿色，浅黄色及橙黄色，紫外可见吸收光谱（UV－VIS）和阴极发光光谱（CLS）研究表明，辐照绿柱石中存在两组与赋色密切相关的色心组合，其一为相对稳定的[Fe^3 ]OH和[Fe^3 4]心，其二则为不稳定的[H^0]i心和F^ 心，二者对可见光的能量分别具有不同程度的选择性吸收和发射，由此产生特征的吸收与发射光谱。低温退火处理（210℃），有助于消除辐照绿柱石中不稳定的色心，使相对稳定的[Fe^3 ]OH心黉度再度聚集，并形成新的缺陷（二次缺陷），进而提高稳定色心的主波长和饱和度。研究证实，二次缺陷形成的初始温度，可近似代表辐照绿柱石的最佳热固色温度点，经辐照与热固色作用而形成的黄色，橙黄色绿柱石的颜色相对稳定，并不因长期日照或低温受热（＜280℃）而褪色。  相似文献   

绿柱石的辐照赋色与效应   总被引：4，自引：0，他引：4  

向长金  亓利剑  周开灿  罗永安 《地质科技情报》2001,20(4):73-76

利用电子加速器为辐照源，对四川，新疆等产的无色绿柱石进行了辐照改色处理。在改色实验中，对辐照源的输出功率，电子能量，扫描面积，扫描速度，辐照剂量等参数，及辐照后样品的辐照效应，环境适应性，时效考验等特性进行了较系统的实验研究，并拟定出一套适合不同成因的无色绿柱石辐照改色的优选方案，对绿柱石的辐照机制和应效进行了探讨。  相似文献   

The use of GPS arrays in detecting shock-acoustic waves generated during rocket launchings     

E. L. Afraimovich  E. A. Kosogorov  N. P. Perevalova  A. V. Plotnikov 《Journal of Atmospheric and Solar》2001,63(18)

This paper is concerned with the parameters of shock-acoustic waves (SAW) generated during rocket launchings. We have developed the interferometric method for determining SAW parameters (including angular characteristics of the wave vector, and the SAW phase velocity, as well as the direction towards the source) using GPS-arrays. Contrary to the conventional radio-probing techniques, the proposed method provides an estimate of SAW parameters without a priori information about the site and time of a rocket launching. The application of the method is illustrated by a case study of ionospheric effects from launchings of rockets PROTON, SOYUZ and SPACE SHUTTLE from Baikonur and Kennedy Space Center cosmodromes in 1998–2000. In spite of a difference of rocket characteristics, the ionospheric response for all launchings had the character of an N-wave corresponding to the form of a shock wave. The SAW period T is 270–360 s, and the amplitude exceeds the standard deviation of total electron content background fluctuations in this range of periods under quiet and moderate geomagnetic conditions by factors of 2–5 as a minimum. The angle of elevation of the SAW wave vector varies from 30° to 60°, and the SAW phase velocity (900–1200 m/s) approaches the sound velocity at heights of the ionospheric F-region maximum. The position of the SAW source, inferred by neglecting refraction corrections, corresponds to the segment of the rockets path at a distance no less than 200–900 km from the launch pad, and to the rocket flying altitude no less than 100 km. Our data are consistent with the existing view that SAW are generated during a nearly horizontal flight of the rocket with its engine in operation in the acceleration segment of the path at 100–130 km altitudes in the lower atmosphere.  相似文献   

Quantitative description of electron precipitation during auroral absorption events in the morning/noon local-time sector     

S. Kirkwood  A. Osepian  N. Smirnova 《Journal of Atmospheric and Solar》2001,63(18):1907

Flux-energy spectra of precipitating electrons are derived from electron density profiles measured by the EISCAT radar during auroral absorption events in the morning/noon local-time sector. The inversion technique uses effective recombination coefficient profiles computed on the basis of a previously validated theoretical model of the lower ionosphere. It is shown that flux-energy spectra for the energy range 30–200 keV are in reasonable agreement with those derived for the same events using trapped flux-energy spectra from geosynchronous satellite data and a model for diffusion of trapped electrons into the loss cone by scattering on whistler waves. During individual events, strongly varying precipitating fluxes are found to be due primarily to varying pitch-angle diffusion.  相似文献   

富钴结壳生长过程中铁锰氧化物矿物组合的变化   总被引：3，自引：0，他引：3  

武光海  周怀阳等 《矿物学报》2001,21(2):137-143

富钴结壳的矿物学研究是一个难点，本文运用电子探针微区分析结合X射线衍射和矿相显微镜观察的综合方法对富钴结壳中的铁锰氧化物矿物组合及其组分变化进行了研究，研究发现，富钴结壳是从与胶状粘土类混合共沉积开始生长的，结壳内部的韵律层和柱状构造也是始于粘土层终于粘土层的；铁锰团粒的核心一般是较纯的水羟凶国矿小核心，可能是在生物媒介作用下在水体中形成后沉降叠积的，FM、FPE海山结壳的中层存在一较纯水羟锰矿层，但该层中Co含量FM15比FPE06低得多，可能反映了FM15在该层形成时Co通量较低，而该层在FN12中不存在，反映了区域环境的较大差异，在FN12火焰状构造亚带存在Mn氧化物和Fe氧化物的极度分异现象，可能反映了结壳形成环境的重大变化。  相似文献